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Estimation of mineral content in forages by near-infrared reflectance spectroscopy = Ocenjevanje vsebnosti rudninskih snovi v voluminozni krmi z bližnjo infrardečo refleksijsko spektroskopijoLavrenčič, Andrej, 1965- ; Stefanon, Bruno ; Orešnik, Andrej, 1943-2016In 100 dried samples of forages, harvested three or four times during 1997 and 1999 in different morphological stages the macro- (Ca, P, Mg, K and Na) and trace- (Zn, Mn and Se) mineral contents were ... determined by chemical methods and by near infrared reflectance spectroscopy (NIRS). The accuracy calibration equations of NIRS for macrominerals Ca, P, Mg and K showed a high degree of accuracy, with an R2 of 0.963, 0.884, 0.892 and 0.939, respectively. These results suggest that these macrominerals are probably closely associated with the organic components, such as plant cell wall (Ca and Mg), chlorophyll (Mg), phytates, phospholipids, phosphoproteins and nucleic acids (P) and organic acids, such as malate (K). On the contrary, NIRS did not estimate Na content very accurately (R2 = 0.52; coefficient of variability of cross validation (CV[down]SECV) = 35.5%), suggesting that Na is not closely associated with organic functional groups or that the amount of the mineral is below the level of NIRS detection. Similar conlusions are also valid for trace minerals, where the R2 was 0.642 (SECV = 4.4) for Zn, 0.427 (SECV = 55.6) for Mg and only 0.186 (SECV = 6.5) for Se. The CVSECV for trace minerals always exceeded 20%. Despite the insensibilytz of NIRS to accurately determine Na and certain trace minerals, the NIRS technique may provide an acceptable prediction of macro mineral contents.Source: Zbornik Biotehniške fakultete Univerze v Ljubljani. Kmetijstvo. Zootehnika = Research reports [of the] Biotechnical Faculty University of Ljubljana. Agricultural issue. Zootechnica. - ISSN 1408-3434 (Letn. 80, št. 1, 2002, str. 41-49)Type of material - article, component partPublish date - 2002Language - englishCOBISS.SI-ID - 1323912
Author
Lavrenčič, Andrej, 1965- |
Stefanon, Bruno |
Orešnik, Andrej, 1943-2016
Topics
forages |
minerals |
macrominerals |
trace minerals |
analytical chemistry |
methods |
near infrared reflectance spectroscopy |
NIR |
voluminozna krma |
rudninske snovi |
makrorudninske snovi |
sledovni elementi |
makrorudninske snovi |
sledovni elementi |
analitska kemija |
metode |
bližnja infrardeča refleksijska spektroskopija |
NIRS
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Lavrenčič, Andrej, 1965- | 11889 |
Orešnik, Andrej, 1943-2016 | 00486 |
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