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Crystal chemistry and physics of ▫$UCd_{11}$▫
Zaremba, Nazar ...
In the phase diagram U-Cd, only one compound has been identified so far─UCd11 (space group Pm3̅m). Since the discovery of this material, the physical properties of UCd11 have attracted a considerable ...amount of attention. In particular, its complex magnetic phase diagram─as a result of tuning with magnetic field or pressure─is not well-understood. From a chemical perspective, a range of lattice parameter values have been reported, suggesting a possibility of a considerable homogeneity range, i.e., UCd11–x. In this work, we perform a simultaneous study of crystallographic features coupled with measurements of physical properties. This work sheds light on the delicate relationship between the intrinsic crystal chemistry and magnetic properties of UCd11.
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