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Electron ionization induced fragmentation of fused nonbornene analogues containing ▫$SiMe_2$▫ or ▫$GeMe_2$▫ and oxygen bridges. Migration of ▫$SiMe_2$▫ and ▫$GeMe_2$▫ groups
Eckert Maksić, Mirjana ...
The main electron ionisation induced fragmentation processes of fused norbornene analogues containing SiMe2 or GeMe2 and oxygen bridges, as well as their dependence on substitution, wereinvestigated ...using mass (MS) and tandem mass (MS/MS) spectrometric analysis. Formation of the rearrangementions of m/z 176 in the mass spectra of fused norbornene analogues containing SiMe2 and m/z 222 in the massspectrum of norbornene analogues containing GeMe2 provides firm evidence for the migration of a SiMe2and GeMe2 bridge, respectively
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