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Shedding light on an ultra-bright photoluminescent lamellar gold thiolate coordination polymer [Au(p-SPhCO [sub] 2Me)] [sub] n
Lavenn, Christophe ...
The first structure elucidation of a lamellar gold thiolate coordination polymer is described. [Au(p-SPhCO2Me)]n is obtained from the simultaneous esterification of mercaptobenzoic acid and reduction ...of the Au(III) precursor. Despite the presence of aurophilic interactions, the intense phosphorescence (QY - 70%) originates from intra-ligand and metal-to-ligand transitions.
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