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Regulacija naboja in robni pogoji v elektrostatiki [Elektronski vir]
Koncilja, Maks
Nekatere makromolekule so sposobne titriranja, saj lahko oddajo in prejmejo kislinske in bazične skupine. Regulacija naboja, ki je odvisna od vrednosti pH in lokalnega potenciala, vpliva na nekatere ...naravne procese kot na primer potovanje DNA skozi nanopore. Ravno tako se regulacijo naboja izkorišča v industriji, med drugim za oblikovanje materialov iz polielektrolitov. V članku je regulacija naboja vpeljana s pomočjo “kemijske” fenomenološke interpretacije in s “fizikalnim” statistično mehanskim pristopom. Sledi opis makromolekul z reguliranim nabojem v raztopini ionov, na primeru dveh makromolekul z regulariziranim nabojem. Nadaljujemo z večdelčnim problemom makromolekul v raztopini, ki ga lahko glede na fizikalne razmere opišemo bodisi z uporabo celičnega modela, za statične raztopine, bodisi s kolektivnim opisom gibljivih makromolekul.
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