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Polymerised forms in the zirconium conversion coatings on cold-rolled steel : proof of conceptKraš, Ana ...This study validates the proposed polymerised structure, including tetrameric polynuclear species, of solid amorphous oxyhydroxide zirconium conversion coatings on cold-rolled steel using ToF-SIMS. ... Tetramers are formed at pH near 4 (and possibly higher), with thickness increasing over extended conversion times. EIS in simulated acid rain further demonstrates that optimal coating formation requires a pH of at least 4 and a sufficient conversion time for adequate thickness, confirmed by the high-frequency EIS loop. Tetramer forms were not observed when the coatings were prepared at lower pH or shorter conversion time, proving that the polymerisation step is crucial for obtaining the coatings offering adequate corrosion protectionSource: npj Materials degradation. - ISSN 2397-2106 (Vol. 8, Art. 65, 2024, 6 str.)Type of material - e-articlePublish date - 2024Language - englishCOBISS.SI-ID - 199397379
Author
Kraš, Ana |
Milošev, Ingrid |
Seyeux, Antoine |
Marcus, Philippe, 1953-
Topics
fizikalna kemija |
polimeri |
jeklo
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Database name | Field | Year |
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Links to authors' personal bibliographies | Links to information on researchers in the SICRIS system |
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Kraš, Ana | 53542 |
Milošev, Ingrid | 01290 |
Seyeux, Antoine | ![]() |
Marcus, Philippe, 1953- | ![]() |
Source: Personal bibliographies
and: SICRIS
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