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Termodinamika disociacije cikloheksilsulfaminske kisline v vodni raztopini : magistrsko delo = Thermodynamics of dissociation of cyclohexylsulphamic acid in aqueous solution : master of science thesis
Luci, Marko
Cikloheksilsulfaminska kislina v obliki njene natrijeve in kalcijeve soli ima pomembno vlogo kot umetno sladilo v hrani, pijačah in farmacevtskih izdelkih. Vodnim raztopinam cikloheksilsulfaminske ...kisline smo izmerili elektrolitsko prevodnost pri koncentracijah do 0.14 mol dm-3, v temperaturnem območju od 298.15 K do 333.15 K, v intervalih po 5.0 K. Izračunali smo ekvivalentno prevodnost pri neskončnem razredčenju in konstante disociacije. Iz temperaturnih odvisnosti konstant disociacije smo izračunali standardne termodinamske funkcije procesov disociacije, t.j. Gibbsovo prosto energijo, entalpijo, entropijo in specifično toploto. Standardne termodinamske funkcije disociacije smo pojasnili s solvatacijskimi procesi. Limitno prevodnost cikloheksilsulfamatnega iona smo ovrednotili in interpretirali na osnovi Eyringove teorije.
Type of material - master's thesis
; adult, serious
Publication and manufacture - Ljubljana : [M. Luci], 1998
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