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Self-assembly of tert-butyl silanetriol in solution and aggregation with tetrahydrofuran
Spirk, Stefan ...
tert-Butyl silanetriol behaves like a surfactant and self-assembles in aqueousand tetrahydrofuran (THF) solutions. Micelle formation was studied withpulsed field gradient stimulated spin echo ...(PFG-SSE) NMR, while multilayerlamellar vesicles can be concluded from small/wide angle X-ray scattering measurements in concentrated solutions at elevated temperature. The significant interaction between tert-butyl silanetriol and THF is further highlighted by a crystal structure featuring a 3:1 adduct of silanetriol and THF.
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