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Odvisnost dinamike tvorbe in razpada nekovalentnih vezi večatomskih ligandov od njihove strukture
Miklavc, Adolf ; Kocjan, Darko
Sistematične eksperimentalne raziskave disociacijskih časov ligandov na receptorskem vezavnem mestu so razkrile močno odvisnost teh časov od strukture ligandov. Na podlagi rezultatov študija prenosa ...energije med molekulami je bilo mogoče razložiti presenetljivo strukturno odvisnost eksperimentalno določenih disociacijskih časov skupine opiatov. Odločilnega pomena je prenos vibracijske energije v interne rotacije liganda. Model, ki jebil razvit na opiatih, je na splošno mogoče uporabiti za grobe ocene relativnih velikosti asociacijskih in disociacijskih hitrosti pri vezavi strukturno sličnih ligandov.
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