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'Living' free radical graft copolymers, II: structureHuskić, Miroslav ...Poly(vinyl) chloride)-n-propyl xanthate (PVC-nPX) macroinitiators with 3 to 14 bonded xanthate groups per molecule were synthesized using PVC and potassium n-propyl xanthate. The reaction took place ... rapidly between 30 and 40C. Ultraviolet (UV) and nuclear magnetic resonance studies confirmed the presence of xanthyl groups on these macroinitiators. The PVC-nPX macroinitiators were grafted by methyl methacrylate under UV irradiationof 254, 302 and 336 nm producing with increasing conversation, which is consistent with a `living` polymerisation process. The active species in these polymerisation are believed to be macroradicals and xanthyl radicals.Source: Polymer international. - ISSN 0959-8103 (Vol. 40, no. 3, 1996, str. 227-233)Type of material - article, component partPublish date - 1996Language - englishCOBISS.SI-ID - 726042
Author
Huskić, Miroslav |
Roha, Max |
Harwood, James H. |
Šebenik, Anton, 1941-
Topics
cepljenje |
PVC |
živa polimerizacija |
ksantat |
graft polymerization |
PVC |
living polymerization |
xanthate
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Database name | Field | Year |
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Links to authors' personal bibliographies | Links to information on researchers in the SICRIS system |
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Huskić, Miroslav | 10692 |
Šebenik, Anton, 1941- | 05018 |
Source: Personal bibliographies
and: SICRIS
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