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13.
Sinteza benzopiran-2-iminov in študij njihove reaktivnosti [Elektronski vir]
Volmajer Valh, Julija ; Toplak Časar, Renata ; Majcen Le Marechal, Alenka
V prispevku je predstavljena sinteza benzopiran-2-iminov, ki smo jih pripravili s Knoevenaglovo reakcijo. Na sintetiziranih benzopiran-2-iminih smoprou č evali reaktivnost iminske skupine tako z ...nukleofilnimi kot tudi z elektrofilnimi reagenti. Pri reakcijah benzopiran-2-iminov z N-nukleofili so vocetni kislini ob prisotnosti amonijevega acetata nastali 2-N-substituirani benzopiran-2-imini. Z natrijevim hipokloritom (I) pa smo izolirali serijo N-klorobenzopiran-2-iminov.
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