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Isotope effects in the crystal symmetry and nature of the phase transitions in ▫$NaH_3(SeO_3)_2$▫ and ▫$NaD_3(SeO_3)_2$▫
Blinc, Robert ...
Meritve NMR kažejo, da se triklinska feroelektrična faza, ki obstaja v ▫$NaH_3(SeO_3)_2$▫ med ▫$-79^\circ$▫C in ▫$-173^\circ$▫C, ne pojavi v ▫$NaD_3(SeO_3)_2$▫. Prehod ▫$2/m \to 1$▫ v ...▫$NaH_3(SeO_3)_2$▫ je zvezan s podvojitvijo dimenzij osnovne celice vzdolž osi ▫$a$▫ in ▫$b$▫, medtem ko je pri nizkotemperaturni fazi simetrije ▫$m$▫ v ▫$NaH_3(SeO_3)_2$▫ in ▫$NaD_3(SeO_3)_2$▫ osnovna celica podvojena samo v smeri osi ▫$b$▫. Prehodi pripadajo vrsti red-nered.
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