Low temperature solid oxide fuel cell (LT-SOFC) can be a source of power for vehicles, online grid, and at the same time reduce system cost, offer high reliability, and fast start-up. A huge amount ...of research work, as evident from the literature has been conducted for the enhancement of the ionic conductivity of LT electrolytes in the last few years. The basic conduction mechanisms, advantages and disadvantages of different LT oxide ion conducting electrolytes {BIMEVOX systems, bilayer systems including doped cerium oxide/stabilised bismuth oxide and YSZ/DCO}, mixed ion conducting electrolytes {doped cerium oxides/alkali metal carbonate composites}, and proton conducting electrolytes {doped and undoped BaCeO3, BaZrO3, etc.} are discussed here based on the recent research articles. Effect of various material aspects (composition, doping, layer thickness, etc.), fabrication methods (to achieve different microstructures and particle size), design related strategies (interlayer, sintering aid etc.), characterization temperature & environment on the conductivity of the electrolytes and performance of the fuel cells made from these electrolytes are shown in tabular form and discussed. The conductivity of the electrolytes and performance of the corresponding fuel cells are compared. Other applications of the electrolytes are mentioned. A few considerations regarding the future prospects are pointed.
•Basic theories, advantages and disadvantages of different classes LT-SOEs covered.•Effects of composition, fabrication methods, and other strategies discussed.•Conductivity of different classes LT-SOEs is presented and compared.•Performance of the fuel cells fabricated from the electrolytes have been discussed.•Applications of the LT-SOEs in different fields are covered.
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GEOZS, IJS, IMTLJ, KILJ, KISLJ, NUK, OILJ, PNG, SAZU, SBCE, SBJE, UL, UM, UPCLJ, UPUK, ZRSKP
For the development of rare-earth free permanent magnets with better performance to cost ratio, V and B dopings were employed to enhance the hard magnetic properties of Zr-Co-V-B alloys. The effect ...of V and B microalloying additions on the magnetic properties, phase stability and microstructure of the metastable Co5Zr phase have been investigated with experimental measurements together with first principles based on the DFT (Density Functional Theory) calculations. This study also investigates the effects of annealing at different temperatures on the intrinsic and extrinsic magnetic properties of Co82Zr12V6-xBx melt-spun ribbons. Rapidly solidified Co82Zr12V6-xBx (x = 1, 2, 3) alloy ribbons were produced by melt-spinning. For as-spun Co82Zr12V6-xBx (x = 1, 2, 3) ribbons, the coercivity Hc decreases from 2.34 kOe to 0.008 kOe with an increasing × value from 1 to 3. The amorphous alloy ribbons were annealed in a vacuum furnace at a series of temperatures of 600 °C, 650 °C, 700 °C and 750 °C each for 30 min. The XRD analysis showed the presence of two soft magnetic phases (fcc-Co and Co23Zr6), accompanied with a hard phase Co5Zr in ribbons thus leading to the desired hard/soft structure and the amount of both (hard and soft) phases increased with the annealing temperature. Coercivity was found to increase upon annealing treatment. The phase stabilities of the Co82Zr12V6-xBx ribbons were calculated from the total energy by the DFT calculations in this work. The calculated magnetic anisotropy energies have been compared to that of experimental coercivity values. Annealed sample Co82Zr12V5B1 showed the maximum coercivity value of 3.58 kOe due to the formation of a high volume fraction of hard magnetic phase (Co5Zr) and evenly distributed finer grains throughout the matrix. However, annealing under the same conditions resulted in lower coercivity of about 0.088 kOe and 1.61 kOe for Co82Zr12V3B3 and Co82Zr12V4B2 samples, respectively. Although sample Co82Zr12V4B2 exhibited higher remanence (42.80 emu/g) and maximum magnetization value with the applied field of 17 kOe (i.e. M17 = 77.70 emu/g) compared to Co82Zr12V3B3 sample.
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GEOZS, IJS, IMTLJ, KILJ, KISLJ, NLZOH, NUK, OILJ, PNG, SAZU, SBCE, SBJE, UILJ, UL, UM, UPCLJ, UPUK, ZAGLJ, ZRSKP
Abstract
We present experimental results of the trace argon impurity puffing in the ohmic plasmas of Aditya-U tokamak performed to study the argon transport behaviour. Argon line emissions in visible ...and Vacuum Ultra Violet (VUV) spectral ranges arising from the plasma edge and core respectively are measured simultaneously. During the experiments, space resolved brightness profile of Ar
1+
line emissions at 472.69 nm (3p
4
4s
2
P
3/2
–3p
4
4p
2
D
3/2
), 473.59 nm (3p
4
4s
4
P
5/2
–3p
4
4p
4
P
3/2
), 476.49 nm (3p
4
4s
2
P
1/2
–3p
4
4p
2
P
3/2
), 480.60 nm (3p
4
4s
4
P
5/2
–3p
4
4p
4
P
5/2
) are recorded using a high resolution visible spectrometer. Also, a VUV spectrometer has been used to simultaneously observe Ar
13+
line emission at 18.79 nm (2s
2
2p
2
P
3/2
–2s2p
2
2
P
3/2
) and Ar
14+
line emission at 22.11 nm (2s
2
1
S
0
–2s2p
1
P
1
). The diffusivity and convective velocity of Ar are obtained by comparing the measured radial emissivity profile of Ar
1+
emission and the line intensity ratio of Ar
13+
and Ar
14+
ions, with those simulated using the impurity transport code, STRAHL. Argon diffusivities ~ 12 m
2
/s and ~ 0.3 m
2
/s have been observed in the edge (ρ > 0.85) and core region of the Aditya-U, respectively. The diffusivity values both in the edge and core region are found to be higher than the neo-classical values suggesting that the argon impurity transport is mainly anomalous in the Aditya-U tokamak. Also, an inward pinch of ~ 10 m/s mainly driven by Ware pinch is required to match the measured and simulated data. The measured peaked profile of Ar density suggests impurity accumulation in these discharges.
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IZUM, KILJ, NUK, PILJ, PNG, SAZU, UL, UM, UPUK
This paper discussed the fundamentals of NiTi shape memory alloy and its applications in advanced scientific fields. Currently, the world is focusing on miniaturized systems for various industrial ...and functional applications. The thin-film shape memory NiTi alloy plays a crucial role in MEMS/NEMS industry in fabrication of microdevices. In this article, the NiTi phase diagram along with the shape memory effect and superelasticity has also been explained. Among several types of fabrication techniques for NiTi thin films, magnetron sputtering, which yields a better homogeneous film, has been discussed. Both the operational parameters (target type, Ar pressure, applied power, target–substrate distance, substrate rotation, substrate temperature, plasma stability, deposition rate) and the material’s parameters (deposition pattern, orientation of adatom, film thickness, film stress, crystal structure, grain size, intermetallic formation, oxide formation, phase transformation) have been correlated in this article. The utilization of shape memory behavior in various industrial applications has been discussed here, also the advantages and limitations of SMA have been briefly discussed.
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EMUNI, FIS, FZAB, GEOZS, GIS, IJS, IMTLJ, KILJ, KISLJ, MFDPS, NLZOH, NUK, OILJ, PNG, SAZU, SBCE, SBJE, SBMB, SBNM, UKNU, UL, UM, UPUK, VKSCE, ZAGLJ
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•Hf addition stabilizes the 1:7H phase.•Grain refinement is achieved by B addition.•The maximum coercivity (Hc) of the ribbons is achieved at Hf ≃ 3 at.%.•The remanent magnetization ...increases with increasing B content.•Experimental observations are in conformity with our theoretical calculations.
The effect of Hf and B additions on the phase stability, microstructure and magnetic properties of the metastable SmCo7 (1:7H) ribbons has been investigated with a combined approach of experimental measurements and first principle DFT (density functional theory) calculations. A series of (Sm0.12Co0.88)95Hf5−xBx (x = 0, 1, 2, 3, 4 and 5) alloys were arc-melted in a TIG (tungsten inert gas) arc melting furnace, followed by melt-spinning onto a copper roller at a wheel velocity of 40 m/s. Characterization based on X-ray diffraction indicates that the major phase is SmCo7 having meta-stable (TbCu7-type) structure. From the total energy calculations using DFT, the phase stability of (Sm0.12Co0.88)95Hf5−xBx ribbons have been confirmed. Moreover, Hf and B addition results in an effective grain refinement; average grain size being as low as ~ 80 nm. The reduction in grain size leads to significant changes (increase or decrease) in magnetic properties depending on the Hf/B ratio. The coercivity value (Hc) varies between 7 kOe and 12 kOe as x (at.% B) increases from 0 to 5 at.%. The experimental coercivity values have been compared with the computed anisotropy energies. The saturation magnetization (Ms) increases from ~ 54 emu/g to 77 emu/g with increasing B concentration (x).
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GEOZS, IJS, IMTLJ, KILJ, KISLJ, NLZOH, NUK, OILJ, PNG, SAZU, SBCE, SBJE, UILJ, UL, UM, UPCLJ, UPUK, ZAGLJ, ZRSKP
Pure nickel thin films were deposited on Si (100) substrates under different conditions of sputtering using direct current magnetron sputtering from a nickel metal target. The different deposition ...parameters employed for this study are target power, argon gas pressure, substrate temperature and substrate-bias voltage. The films exhibited high density of void boundaries with reduction in texture deposited under high argon gas pressures. At argon gas pressure of 5 mTorr and target power of 300 W, Ni deposition rate was ~40 nm/min. In addition, coalescence of grains accompanied with increase in the film texture was observed at high DC power. Ni films undergo morphological transition from continuous, dense void boundaries to microstructure free from voids as the substrate-bias voltage was increased from −10 to −90 V. Furthermore, as the substrate temperature was increased, the films revealed strong fiber texture accompanied with near-equiaxed grain structure. Ni films deposited at 770 K showed the layer-by-layer film formation which lead to dense, continuous microstructure with increase in the grain size.
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DOBA, EMUNI, FIS, FZAB, GEOZS, GIS, IJS, IMTLJ, IZUM, KILJ, KISLJ, MFDPS, NLZOH, NUK, OILJ, PILJ, PNG, SAZU, SBCE, SBJE, SBMB, SBNM, SIK, UILJ, UKNU, UL, UM, UPUK, VKSCE, ZAGLJ
Three mixed-phase TiO
2
powders, containing ∼80 volume % anatase and ∼20 volume % rutile, were prepared from amorphous titanium hydroxide and three different salt matrices-pure sodium chloride, pure ...Na
2
CO
3
, and pure disodium hydrogen phosphate (DSP). Amorphous titanium hydroxide and salt mixtures were heat treated at 875°C in a rapid thermal annealing system for different times, according to the time-temperature phase transformation graphs. Time-dependent UV degradation of aqueous solutions of methylene blue dye (15 ppm) in the presence of mixed-phase powders was used to monitor the activity of the catalysts. Microstructural study of the powders by scanning electron microscope and transmission electron microscope combined with phase analysis by XRD and optical absorbance by UV-absorption spectroscopy indicated that the higher photocatalytic activity of the powder obtained from pure DSP salt could be explained by its smaller rutile particle size and anatase-rutile interparticle bonding.
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BFBNIB, GIS, IJS, IZUM, KILJ, KISLJ, NUK, PILJ, PNG, SAZU, UL, UM, UPUK
•Co is substituting Mn in the alloy.•Twinning with branching is observed.•Compound twins and secondary twins are also present.•Curie temperature decreased with increase in Co content.
Cobalt-doped ...melt-spun ribbons of Ni50Mn25−xCoxGa25 were prepared to study the influence of cobalt on the magnetic properties of the NiMnGa based Heusler alloy. Bulk specimens were also prepared for a comparative study. The bulk specimens and the melt spun ribbons were annealed at 900 °C for 5 h followed by quenching. Microstructural studies revealed an extensively twinned structure which is beneficial for magnetic field induced strain. The magnetization measurements showed a reduction in the moment with an increase in the cobalt content from 78.4 emu/g to 52.7 emu/g for Co (x = 6) and Co (x = 10), respectively. A reduction was also observed in the TC when cobalt content was increased from Co (x = 6) (TC = 386 K) to Co (x = 10) (TC = 263 K).
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GEOZS, IJS, IMTLJ, KILJ, KISLJ, NLZOH, NUK, OILJ, PNG, SAZU, SBCE, SBJE, UILJ, UL, UM, UPCLJ, UPUK, ZAGLJ, ZRSKP
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