The Wet Chemistry Laboratory on the Phoenix Mars Lander performed aqueous chemical analyses of martian soil from the polygon-patterned northern plains of the Vastitas Borealis. The solutions ...contained approximately 10 mM of dissolved salts with 0.4 to 0.6% perchlorate (ClO₄) by mass leached from each sample. The remaining anions included small concentrations of chloride, bicarbonate, and possibly sulfate. Cations were dominated by Mg²⁺ and Na⁺, with small contributions from K⁺ and Ca²⁺. A moderately alkaline pH of 7.7 ± 0.5 was measured, consistent with a carbonate-buffered solution. Samples analyzed from the surface and the excavated boundary of the approximately 5-centimeter-deep ice table showed no significant difference in soluble chemistry.
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Carbonates are generally products of aqueous processes and may hold important clues about the history of liquid water on the surface of Mars. Calcium carbonate (approximately 3 to 5 weight percent) ...has been identified in the soils around the Phoenix landing site by scanning calorimetry showing an endothermic transition beginning around 725°C accompanied by evolution of carbon dioxide and by the ability of the soil to buffer pH against acid addition. Based on empirical kinetics, the amount of calcium carbonate is most consistent with formation in the past by the interaction of atmospheric carbon dioxide with liquid water films on particle surfaces.
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Hydrogen has been inferred to occur in enhanced concentrations within permanently shadowed regions and, hence, the coldest areas of the lunar poles. The Lunar Crater Observation and Sensing Satellite ...(LCROSS) mission was designed to detect hydrogen-bearing volatiles directly. Neutron flux measurements of the Moon's south polar region from the Lunar Exploration Neutron Detector (LEND) on the Lunar Reconnaissance Orbiter (LRO) spacecraft were used to select the optimal impact site for LCROSS. LEND data show several regions where the epithermal neutron flux from the surface is suppressed, which is indicative of enhanced hydrogen content. These regions are not spatially coincident with permanently shadowed regions of the Moon. The LCROSS impact site inside the Cabeus crater demonstrates the highest hydrogen concentration in the lunar south polar region, corresponding to an estimated content of 0.5 to 4.0% water ice by weight, depending on the thickness of any overlying dry regolith layer. The distribution of hydrogen across the region is consistent with buried water ice from cometary impacts, hydrogen implantation from the solar wind, and/or other as yet unknown sources.
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Global distributions of thermal, epithermal, and fast neutron fluxes have been mapped during late southern summer/northern winter using the Mars Odyssey Neutron Spectrometer. These fluxes are ...selectively sensitive to the vertical and lateral spatial distributions of H and CO2in the uppermost meter of the martian surface. Poleward of ±60° latitude is terrain rich in hydrogen, probably H2Oice buried beneath tens of centimeter-thick hydrogen-poor soil. The central portion of the north polar cap is covered by a thick CO2layer, as is the residual south polar cap. Portions of the low to middle latitudes indicate subsurface deposits of chemically and/or physically bound H2Oand/or OH.
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In May of 2011, NASA selected the
O
rigins,
S
pectral
I
nterpretation,
R
esource
I
dentification, and
S
ecurity–
R
egolith
Ex
plorer (OSIRIS-REx) asteroid sample return mission as the third mission ...in the New Frontiers program. The other two New Frontiers missions are
New Horizons
, which explored Pluto during a flyby in July 2015 and is on its way for a flyby of Kuiper Belt object 2014 MU69 on January 1, 2019, and
Juno
, an orbiting mission that is studying the origin, evolution, and internal structure of Jupiter. The spacecraft departed for near-Earth asteroid (101955) Bennu aboard an United Launch Alliance Atlas V 411 evolved expendable launch vehicle at 7:05 p.m. EDT on September 8, 2016, on a seven-year journey to return samples from Bennu. The spacecraft is on an outbound-cruise trajectory that will result in a rendezvous with Bennu in November 2018. The science instruments on the spacecraft will survey Bennu to measure its physical, geological, and chemical properties, and the team will use these data to select a site on the surface to collect at least 60 g of asteroid regolith. The team will also analyze the remote-sensing data to perform a detailed study of the sample site for context, assess Bennu’s resource potential, refine estimates of its impact probability with Earth, and provide ground-truth data for the extensive astronomical data set collected on this asteroid. The spacecraft will leave Bennu in 2021 and return the sample to the Utah Test and Training Range (UTTR) on September 24, 2023.
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DOBA, EMUNI, FIS, FZAB, GEOZS, GIS, IJS, IMTLJ, IZUM, KILJ, KISLJ, MFDPS, NLZOH, NUK, OBVAL, OILJ, PILJ, PNG, SAZU, SBCE, SBJE, SBMB, SBNM, UILJ, UKNU, UL, UM, UPUK, VKSCE, ZAGLJ
Using the Gamma-Ray Spectrometer on the Mars Odyssey, we have identified two regions near the poles that are enriched in hydrogen. The data indicate the presence of a subsurface layer enriched in ...hydrogen overlain by a hydrogen-poor layer. The thickness of the upper layer decreases with decreasing distance to the pole, ranging from a column density of about 150 grams per square centimeter at -42° latitude to about 40 grams per square centimeter at -77°. The hydrogen-rich regions correlate with regions of predicted ice stability. We suggest that the host of the hydrogen in the subsurface layer is ice, which constitutes 35 ± 15% of the layer by weight.
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•LEND/LRO instrument neutron counting data sets have been analyzed to create high resolution maps of epithermal neutron flux at polar regions of the Moon.•The conversion from epithermal neutron flux ...to the H/H2O abundances is presented based on the simple subsurface models.•The polar lunar maps (poleward 70S/70N) of homogeneous hydrogen distribution are derived and discussed.
We present a method of conversion of the lunar neutron counting rate measured by the Lunar Reconnaissance Orbiter (LRO) Lunar Exploration Neutron Detector (LEND) instrument collimated neutron detectors, to water equivalent hydrogen (WEH) in the top ∼1m layer of lunar regolith. Polar maps of the Moon's inferred hydrogen abundance are presented and discussed.
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GEOZS, IJS, IMTLJ, KILJ, KISLJ, NUK, OILJ, PNG, SAZU, SBCE, SBJE, UL, UM, UPCLJ, UPUK, ZRSKP
9.
Global distribution of near-surface hydrogen on Mars Feldman, W. C.; Prettyman, T. H.; Maurice, S. ...
Journal of Geophysical Research - Planets,
September 2004, Volume:
109, Issue:
E9
Journal Article, Conference Proceeding
Peer reviewed
Open access
Neutron data observed using the Neutron Spectrometer aboard 2001 Mars Odyssey provide a lower limit to the global inventory of Martian water‐equivalent hydrogen. Hydrogen‐rich deposits ranging ...between about 20% and 100% water‐equivalent by mass are found poleward of ±50° latitude, and less rich, but significant, deposits are found at near‐equatorial latitudes. The equatorial deposits between ±45° latitude range between 2% and 10% water‐equivalent hydrogen by mass and reach their maximum in two regions that straddle the 0‐km elevation contour. Higher water abundances, up to ∼11%, are required in subsurface regolith of some equatorial regions if the upper 10 g/cm2 of regolith is desiccated, as suggested on average by comparison of epithermal and fast neutron data. The hydrogen contents of surface soils in the latitude range between 50° and 80° north and south are equal within data uncertainties. A lower‐limit estimate of the global inventory of near surface hydrogen amounts to a global water layer about 14 cm thick if the reservoir sampled from orbit is assumed to be 1 m thick.
Chemical analyses of three Martian soil samples were performed using the Wet Chemistry Laboratories on the 2007 Phoenix Mars Scout Lander. One soil sample was obtained from the top ∼2 cm (Rosy Red) ...and two were obtained at ∼5 cm depth from the ice table interface (Sorceress 1 and Sorceress 2). When mixed with water in a ∼1:25 soil to solution ratio (by volume), a portion of the soil components solvated. Ion concentrations were measured using an array of ion selective electrodes and solution conductivity using a conductivity cell. The measured concentrations represent the minimum leachable ions in the soil and do not take into account species remaining in the soil. Described is the data processing and analysis for determining concentrations of seven ionic species directly measured in the soil/solution mixture. There were no significant differences in concentrations, pH, or conductivity, between the three samples. Using laboratory experiments, refinement of the surface calibrations, and modeling, we have determined a pH for the soil solution of 7.7(±0.3), under prevalent conditions, carbonate buffering, and PCO2 in the cell headspace. Perchlorate was the dominant anion in solution with a concentration for Rosy Red of 2.7(±1) mM. Equilibrium modeling indicates that measured Ca2+ at 0.56(±0.5) mM and Mg2+ at 2.9(±1.5) mM, are consistent with carbonate equilibrium for a saturated solution. The Na+ and K+ were 1.4(±0.6), and 0.36(±0.3) mM, respectively. Results indicate that the leached portion of soils at the Phoenix landing site are slightly alkaline and dominated by carbonate and perchlorate. However, it should be noted that there is a 5–15 mM discrepancy between measured ions and conductivity and another species may be present.
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