We estimate changes in forest cover (deforestation and forest regrowth) in the tropics for the two last decades (1990–2000 and 2000–2010) based on a sample of 4000 units of 10 ×10 km size. Forest ...cover is interpreted from satellite imagery at 30 × 30 m resolution. Forest cover changes are then combined with pan‐tropical biomass maps to estimate carbon losses. We show that there was a gross loss of tropical forests of 8.0 million ha yr⁻¹ in the 1990s and 7.6 million ha yr⁻¹ in the 2000s (0.49% annual rate), with no statistically significant difference. Humid forests account for 64% of the total forest cover in 2010 and 54% of the net forest loss during second study decade. Losses of forest cover and Other Wooded Land (OWL) cover result in estimates of carbon losses which are similar for 1990s and 2000s at 887 MtC yr⁻¹ (range: 646–1238) and 880 MtC yr⁻¹ (range: 602–1237) respectively, with humid regions contributing two‐thirds. The estimates of forest area changes have small statistical standard errors due to large sample size. We also reduce uncertainties of previous estimates of carbon losses and removals. Our estimates of forest area change are significantly lower as compared to national survey data. We reconcile recent low estimates of carbon emissions from tropical deforestation for early 2000s and show that carbon loss rates did not change between the two last decades. Carbon losses from deforestation represent circa 10% of Carbon emissions from fossil fuel combustion and cement production during the last decade (2000–2010). Our estimates of annual removals of carbon from forest regrowth at 115 MtC yr⁻¹ (range: 61–168) and 97 MtC yr⁻¹ (53–141) for the 1990s and 2000s respectively are five to fifteen times lower than earlier published estimates.
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The TREES-3 project of the Joint Research Centre aims at assessing tropical forest cover changes for the periods 1990–2000 and 2000–2010 using a sample-based approach. This paper refers to the ...1990–2000 assessment. Extracts of Landsat satellite imagery (20
km
×
20
km) are analyzed for these reference dates for more than 4000 sample sites distributed systematically across the tropical belt. For the processing and analysis of such a large amount of satellite imagery a robust methodological approach for forest mapping and change detection has been developed. This approach comprises two automated steps of multi-date image segmentation and object-based land cover classification (based on a supervised spectral library), followed by an intense phase of visual control and expert refinement. Image segmentation is done at two spatial scales, introducing the concept of a minimum mapping unit via the automated selection of a site-specific scale parameter. The automated segmentation of land cover polygons and the pre-classification of land cover types mainly aim at avoiding manual delineation and at reducing the efforts of visual interpretation of land cover to a reasonable level, making the analysis of 4000 sample sites feasible. The importance of visual control and correction can be perceived when comparing to the initial automatic classification result: about 20% of the polygon labels were changed through expert knowledge by visual interpretation. The component of visual refinement of the mapping results had also a notable impact on forest area and change estimates: for a set of sample sites in Southeast Asia (~
90% of all sites of SE-Asia) the rate of change in tree cover (deforestation) was assessed at 0.9% and 1.6% before and after visual control, respectively.
► Pan-tropical forest monitoring is feasible based on sampling and satellite imagery. ► Multi-date image segmentation provides a good basis for monitoring. ► Two-scale segmentation and automated classification are efficient for mapping. ► Quality control and correction by visual interpretation are essential.
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GEOZS, IJS, IMTLJ, KILJ, KISLJ, NUK, OILJ, PNG, SAZU, SBCE, SBJE, UL, UM, UPCLJ, UPUK
This paper outlines the methods and results for monitoring forest change and resulting carbon emissions for the 1990–2000 and 200–2005 periods carried out over tropical Central and South America. To ...produce our forest change estimates we used a systematic sample of medium resolution satellite data processed to forest change maps covering 1230 sites of 20 km by 20 km, each located at the degree confluence. Biomass data were spatially associated to each individual sample site so that annual carbon emissions could be estimated. For our study area we estimate that forest cover in the study area had fallen from 763 Mha (s.e. 10 Mha) in 1990 to 715 Mha (s.e. 10 Mha) in 2005. During the same period other wooded land (i.e., non-forest woody vegetation) had fallen from 191 Mha (s.e. 5.5 Mha) to 184 Mha (s.e. 5.5 Mha). This equates to an annual gross loss of 3.74 Mha∙y−1 of forests (0.50% annually) between 1990 and 2000, rising to 4.40 Mha∙y−1 in the early 2000s (0.61% annually), with Brazil accounting for 69% of the total losses. The annual carbon emissions from the combined loss of forests and other wooded land were calculated to be 482 MtC∙y−1 (s.e. 29 MtC∙y−1) for the 1990s, and 583 MtC∙y−1 (s.e. 48 MtC∙y−1) for the 2000 to 2005 period. Our maximum estimate of sinks from forest regrowth in tropical South America is 92 MtC∙y−1. These estimates of gross emissions correspond well with the national estimates reported by Brazil, however, they are less than half of those reported in a recent study based on the FAO country statistics, highlighting the need for continued research in this area.
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IZUM, KILJ, NUK, PILJ, PNG, SAZU, UL, UM, UPUK
Abstract Ocular tick attachment is a rare event; however, it carries a significant risk of tick-borne infections. Hereby, we describe a case of a 29-year-old female in the Amazon region who presented ...a tick attached to the left nasal bulbar conjunctiva with noticeable dilatation of conjunctival vessels. With no access to a medical center, the patient was guided to mechanically remove the tick by pulling it with sterile forceps. The conjunctiva was freely mobile, and the tick, later identified as Amblyomma spp., was completely removed from the eye. No ocular or systemic tick-transmitted diseases were observed within 6 months of follow-up. The prompt and secure removal of a tick attached to the conjunctiva should be undertaken as soon as possible to prevent the further transmission of pathogens, toxins, and allergens. The removal approach should be based on the tick’s location and the patient’s access to a medical facility.
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DOBA, IZUM, KILJ, NUK, PILJ, PNG, SAZU, UILJ, UKNU, UL, UM, UPUK
Maternal strategies reflect the trade-off between offspring needs and maternal ability to invest, a concept described by the evolutionary theory of parent–offspring conflict. In mammals this conflict ...has often been investigated by studying weaning, the transition from maternal milk consumption to dietary independence. An investigation of individual variation in weaning can provide information on the adaptive significance of maternal strategies in relation to social and biological variables. We analysed stable nitrogen isotopes of hair samples collected from 22 mother–infant dyads in a wild population of chacma baboons, Papio ursinus, in conjunction with behavioural data on suckling, to explore the temporal dynamics of weaning, as well as the extent and determinants of individual variation in these dynamics. The weaning pattern suggested by isotope values and behavioural data were congruent. The difference between infant and mother stable nitrogen isotope values decreased faster with age in infants of low-ranking mothers, which suggests a faster progression towards weaning, perhaps due to subordinate females experiencing lower resource availability and so being less able to bear the costs of lactation over prolonged periods. Additionally, within-infant variation in stable nitrogen isotope values showed an increase with age (which was not detectable between infants), potentially highlighting the nutritional costs that weaning imposes on offspring. Our combination of isotope analysis and behavioural data from a wild population provides insight into the evolution of maternal strategies. In particular, it suggests that the quantity of care a mother can provide is affected by her rank, with subordinate females possibly not able to lactate for as long and perhaps benefiting from weaning earlier.
•Time to weaning may depend on maternal and offspring characteristics•Stable isotope signatures can characterize the weaning process•In baboons, offspring of low-ranked mothers moved towards weaning more quickly•Stable isotope analysis may show signs of nutritional stress in weaning infants•Social environment can influence the weaning process and maternal strategies
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GEOZS, IJS, IMTLJ, KILJ, KISLJ, NLZOH, NUK, OILJ, PNG, SAZU, SBCE, SBJE, UILJ, UL, UM, UPCLJ, UPUK, ZAGLJ, ZRSKP
A series of novel (C∧N∧N) cyclometalated AuIII complexes of general formula Au(bipydmb-H)XPF6 (bipydmb-H = C∧N∧N cyclometalated 6-(1,1-dimethylbenzyl)-2,2′-bipyridine) were prepared with a range ...of anionic ligands X in the fourth coordination position, featuring C (alkynyl)-, N-, O-, or S-donor atoms. The X ligands are varied in nature and include three coumarins, 4-ethynylaniline, saccharine, and thio-β-d-glucose tetraacetate, the tripeptide glutathione (GSH), and a coumarin-substituted amide derived from 4-ethynylaniline. The gold(I) complex Au(C2ArNHCOQ)(PPh3) (HC2ArNHCOQ = N-(4-ethynylphenyl)-2-oxo-2H-chromene-3-carboxamide) was also prepared for comparison. The new compounds were fully characterized by means of analytical techniques, including NMR, absorption, and emission spectroscopy. The crystal structures of three cyclometalated AuIII complexes and of the AuI derivative were solved by single-crystal X-ray diffraction. The antiproliferative activity of the new AuIII cyclometalated derivatives was evaluated against cancer cells in vitro. According to the obtained results, only complexes 3-PF6 and 5-PF6, featuring coumarins as ancillary ligands and endowed with high redox stability in solution, display antiproliferative effects, with 5-PF6 being the most potent, while all of the others are scarcely active to nonactive in the selected cell lines. In order to study the reactivity of the compounds with biomolecules, the interaction of complexes 3-PF6 and 5-PF6 with the protein cytochrome c and the amino acids cysteine and histidine was analyzed by electrospray ionization mass spectrometry (ESI MS), showing adduct formation only with Cys after at least 1 h incubation. Furthermore, the parent hydroxo complex Au(bipydmb-H)(OH)PF6 (1OH-PF6) was investigated in a competitive assay to determine the protein vs oligonucleotide binding preferences by capillary zone electrophoresis (CZE) coupled to ESI-MS. Of note, the compound was found to selectively form adducts with the oligonucleotide over the protein upon ligand exchange with the hydroxido ligand. Adduct formation occurred within the first 10 min of incubation, demonstrating the preference of 1OH-PF6 for nucleotides in this setup. Overall, the obtained results point toward the possibility to selectively target DNA with gold(III) organometallics.
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The phloem limited bacterium 'Candidatus Liberibacter solanacearum' (Lso) is associated with disease in Solanaceous and Apiaceous crops. This bacterium has previously been found in the UK in Trioza ...anthrisci, but its impact on UK crops is unknown. Psyllid and Lso diversity and distribution among fields across the major carrot growing areas of Scotland were assessed using real-time PCR and DNA barcoding techniques. Four Lso haplotypes were found: C, U, and two novel haplotypes. Lso haplotype C was also found in a small percentage of asymptomatic carrot plants (9.34%, n = 139) from a field in Milnathort where known vectors of this haplotype were not found. This is the first report of Lso in cultivated carrot growing in the UK and raises concern for the carrot and potato growing industry regarding the potential spread of new and existing Lso haplotypes into crops. Trioza anthrisci was found present only in sites in Elgin, Moray with 100% of individuals harbouring Lso haplotype C. Lso haplotype U was found at all sites infecting Trioza urticae and at some sites infecting Urtica dioica with 77.55% and 24.37% average infection, respectively. The two novel haplotypes were found in Craspedolepta nebulosa and Craspedolepta subpunctata and named Cras1 and Cras2. This is the first report of Lso in psyllids from the Aphalaridae. These new haplotypes were most closely related to Lso haplotype H recently found in carrot and parsnip. Lso was also detected in several weed plants surrounding carrot and parsnip fields. These included two Apiaceous species Aegropodium podagraria (hap undetermined) and Anthriscus sylvestris (hap C); one Gallium sp. (Rubiaceae) (hap undetermined); and Chenopodium album (Amaranthaceae) (hap undetermined).
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IZUM, KILJ, NUK, PILJ, PNG, SAZU, UL, UM, UPUK
Variation in the concentration of antioxidants and hormones of maternal origin in the eggs of birds can have a profound influence on offspring phenotype both prenatally and postnatally. Egg maternal ...substances can have interacting effects, but experimental studies of the consequences of the combined variation in the egg concentration of such molecules are extremely rare, particularly as far as prenatal stages are concerned. We manipulated the yolk concentration of vitamin E and corticosterone, which are, respectively, the main antioxidant and the main glucocorticoid hormone in bird eggs, both independently and simultaneously, and we tested their separate and combined effects on growth and oxidative status in the liver and in the brain of yellow-legged gull (
) embryos. Egg supplementation of relatively large physiological doses of corticosterone depressed embryo growth (total body mass, tarsus length and liver mass), whereas administration of vitamin E in association with corticosterone restored normal growth. Vitamin E did not affect embryo growth when administered alone. We further analysed the independent and combined effects of vitamin E and corticosterone on liver and brain total antioxidant capacity, the concentration of reactive oxygen molecules and lipid peroxidation. Vitamin E significantly reduced liver total antioxidant capacity, while corticosterone depressed brain lipid peroxidation. Prenatal exposure to vitamin E and corticosterone appears to have antagonistic effects on body growth, although vitamin E is not limiting in yellow-legged gull eggs. In combination with the results of previous experiments on the same species applying smaller experimental doses or focusing on the postnatal rather than prenatal life stages, our findings indicate that the effects of a physiological increase in the egg concentration of these substances can be life stage and dose specific, implying that generalizing prenatal effects of egg compounds may not be feasible.
In this work, mild Lewis acids and low environmental impact solvents were investigated for Nenitzescu synthesis. Cyclopentyl methyl ether can be used at room temperature in substitution of ...halogenated solvents with zinc, iron and magnesium salts as homogeneous catalysts to give 5‐hydroxyindoles in fair to good yields. The reaction features a straightforward workup and excellent solvent recycle.
In cyclopentyl methyl ether (CPME), the Nenitzescu reaction of enamines and quinones can be catalyzed with ZnCl2, ZnI2, Mg(CF3SO3)2 or FeCl3 at room temperature to give 5‐hydroxyindoles as crystalline solids, which can be isolated by simple filtration from the reaction mixture. CPME can be efficiently recycled and reused.
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BFBNIB, FZAB, GIS, IJS, KILJ, NLZOH, NUK, OILJ, SAZU, SBCE, SBMB, UL, UM, UPUK
Reaction of glycerol with aldehydes and ketones is a strategy widely studied in literature to valorize this bioproduct. A Brønsted or Lewis acid is normally used to activate the carbonyl function and ...various strategies adopted to drive the equilibrium to the products. In this study ammonium salts as catalysts, and removal of water by azeotropic distillation of cyclopentyl methyl ether, permit the conversion of glycerol into acetals obtained as mixture of dioxanes and dioxolanes determined by 1H‐NMR. Under the optimized conditions, the products could be obtained in excellent yield without using excess of reactants and the solvent was recycled efficiently.
Acetalization of glycerol can be efficiently carried out under azeotropic water removal substituting aromatic solvents with cyclopentyl methyl ether. Ammonium salts are a cheap and efficient alternative to stronger and more polluting acids, high conversions and isolated yields are realized with electron‐rich aromatic aldehydes in presence of the mild NH4Br.
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