Sediments represent a critical compartment of marine coastal ecosystems due to the toxic and long-lasting effects of the contaminants buried therein. Here, we investigated the properties of surficial ...sediments in front of the Southern Marche Region coast (Central Adriatic Sea, Italy). The grain size of the surficial sediments was determined by X-ray sedigraphy. TN and OC contents were determined by elemental analysis. The concentrations of Al, Fe, Mg, K, S, Ca, Ti, P, Na, Mn, Mg, Li, As, Ba, Ga, Pb, Sr, and Zn were determined by ICP-OES to evaluate their spatial patterns and temporal trends. A Q-mode Factor Analyses was applied and resulted in the identification of three compositional facies (Padanic, Coastal, and Residual) characterized by common biogeochemical, mineralogical, sedimentological properties, transport pathway, and source. Some pollution indicators, such as the enrichment factor, the geoaccumulation index, and the pollution load index were calculated to assess the deviation from the natural background levels. The results showed a pollution by As and Ba due to the human activities in the 20th century. Furthermore, a general decreasing of Al, Ti, P, Co, Cr, Cu, Ga, Ni, Pb, Sc, V, and Y concentrations from the background levels suggested a change in the sedimentation processes during the last decades.
The geological, biological and geochemical features of a particular field of hydrothermal vents, discovered in the Panarea Volcanic Complex during a research survey carried out in 2015, are described ...for the first time. The site, located at 70-80 m depth off the South-western coast of the islet of Basiluzzo, was named Smoking Land for the presence of a large number of wide and high active chimneys and was characterized in terms of dissolved benthic fluxes, associated macrofauna and megafauna communities and preliminary mineralogy and geochemistry of chimney structures. On the whole field, a total of 39 chimneys, different in size and shape, were closely observed and described; 14 of them showed emission of low temperature hydrothermal fluids of marine origin characterized by acidified chemical conditions. The CTD and benthic chamber measurements highlighted that the Smoking Land is able to form a sea water bottom layer characterized by variable acidity and high DIC and trace elements concentrations; these characteristics weaken moving away from the chimney mouths. The SEM-EDS analysis of the collected solid samples revealed a chimney structure principally composed by amorphous and low crystalline Fe-oxyhydroxides of hydrothermal origins. The ROV explorations revealed a wide coverage of red algae (Peyssonnelia spp.) colonized by the green algae Flabiella petiolata and by suspension feeders, mainly sponges, but also bryozoans, and tubicolous polychaetes. Although novent-exclusive species were identified, the benthic communities found in association to the chimneys included more taxa than those observed in the surrounding no-vent rocky areas. These first findings evidence a submarine dynamic habitat where geological, chemical and biological processes are intimately connected, making the Smoking Land an important site in terms of marine heritage that should be safeguarded and protected.
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DOBA, IZUM, KILJ, NUK, PILJ, PNG, SAZU, SIK, UILJ, UKNU, UL, UM, UPUK
The recent expansion of Atlantic waters into the Arctic Ocean represents undisputable evidence of the rapid changes occurring in this region. Understanding the past variability of this ...“Atlantification” is thus crucial in providing a longer perspective on the modern Arctic changes. Here, we reconstruct the history of Atlantification along the eastern Fram Strait during the past 800 years using precisely dated paleoceanographic records based on organic biomarkers and benthic foraminiferal data. Our results show rapid changes in water mass properties that commenced in the early 20th century—several decades before the documented Atlantification by instrumental records. Comparison with regional records suggests a poleward expansion of subtropical waters since the end of the Little Ice Age in response to a rapid hydrographic reorganization in the North Atlantic. Understanding of this mechanism will require further investigations using climate model simulations.
We investigated the living (stained) and dead benthic foraminiferal assemblages collected in surface sediment samples (0–1 cm) from two different areas (JOIDES Basin and Mawson Bank) of the Ross Sea ...(Antarctica). Samples were collected during the BEDROSE oceanographic cruise from January to February 2017. Four living and dead benthic foraminiferal fauna assemblages have been distinguished based on cluster analysis. The differences observed in the living and dead foraminiferal content from the two investigated areas are the result of taphonomic processes induced by the different oceanographic settings and environmental conditions. In the JOIDES Basin, agglutinated taxa
Rhabdamminella cylindrica, Lagenammina difflugiformis, Adercotryma glomeratum, Recurvoides contortus, Reophax subfusiformis
with high percentages of
Trochammina
group and
Reophax spiculifer
associated with the calcareous species
Nonionella bradii
and
Astrononion echolsi
characterize the living assemblages. The comparison between living and dead benthic foraminifera reveals considerable similarities in terms of the presence/absence of agglutinated species and differences in relative abundance of calcareous taxa. However, the major influencing factor in foraminiferal preservation appears to be the carbonate dissolution. Results from Mawson Bank show an almost exclusive presence of calcareous taxa with high percentages of
Globocassidulina
group in both living and dead assemblages. The dead fauna assemblage differs from the corresponding living assemblage by being more diverse documenting high-energy current influence on marine sedimentation.
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EMUNI, FIS, FZAB, GEOZS, GIS, IJS, IMTLJ, KILJ, KISLJ, MFDPS, NLZOH, NUK, OBVAL, OILJ, PNG, SAZU, SBCE, SBJE, SBMB, SBNM, UKNU, UL, UM, UPUK, VKSCE, ZAGLJ
High-definition bathymetry mapping, combined with the measurement of dissolved benthic fluxes and water column biogeochemical properties, allows for a description of new biogeochemical processes ...around the Panarea Volcanic island. Investigations focused on the CO2 releases from the bottom sea on the east of the Panarea volcanic complex provided insights into the geological setup of the marine area east and south of the Panarea Island. Between the Panarea Island and the Basiluzzo Islet lies a SW-NE-stretching graben structure where a central depression, the Smoking Land Valley, is bounded by extensional faults. Abundant acidic fluids rich in dissolved inorganic Carbon are released on the edges of the graben, along the extensional faults, either diffusely from the seafloor, from hydrothermal chimneys, or at the center of craters of different sizes. The precipitation of iron dissolved in the acidic fluids forms Fe-oxyhydroxides bottom sea crusts that act as a plug, thus preventing the release of the underlying gases until their mounting pressure generates a bursting release. This process is cyclic and results in intermittent gas release from the bottom, leaving extinct craters and quiescent chimneys. The measurement of dissolved benthic fluxes allowed us to estimate the volcanic DIC venting at 15 Mt of CO2 over the past 10,000 years. The fluxes are not distributed homogeneously but rather concentrate along fractures and fault planes, which facilitate their rise to the seafloor. The acidic fluids released affect the chemical properties and structure of the water column through the formation of layers with a lower pH under the pycnocline, which can limit volcanic CO2 release to the atmosphere. Further and continuous monitoring and investigation of the area are needed in order to complete a thorough picture of the variations in fluid releases through time and space. The importance of such monitoring lies in the development of a new method for detecting and quantifying the diffusive dissolved benthic fluxes on a volcanic sea bottom affected by hydrothermal seeps.
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IZUM, KILJ, NUK, PILJ, PNG, SAZU, UL, UM, UPUK
This work presents the results of long-term deep-water observations carried out in the southwestern Adriatic margin. Hydrodynamics and thermohaline measurements were carried out in the last 100 m of ...the water column using two long-term moorings placed at two different locations along the western sector of the Adriatic continental margin (open slope vs. submarine canyon). The observations, carried out over a period of almost 10 years, made it possible to define the intra- and interannual deep-water dynamics, which are mainly influenced by the passage of cold, dense water. The hydrodynamic field is influenced by seasonal behavior and varies from year to year, with no clear temporal trend or periodicity. Thermohaline properties follow hydrodynamics but also show a climatological trend toward higher temperatures and salinity. The combination and variability of preconditioning factors explains the interannual variability in dense water passage at the mooring sites triggering the formation of dense water in the northern Adriatic. The impulsive nature of the dense water flow, which is difficult to capture with sporadic oceanographic surveys, and its linkage with the large-scale atmospheric circulation make continuous monitoring essential to answer open questions about cascading processes and deep-water dynamics under a global change scenario.
This study focused on the geochemical and sedimentological characterization of recent sediments from two marine sites (S1 and E1) located in the North Adriatic Sea, between the Po River prodelta and ...the Rimini coast. Major and trace metal concentrations reflect the drainage area of the Po River and its tributaries, considered one of the most polluted areas in Europe. Sediment geochemistry of the two investigated sites denote distinct catchment areas. High values of Cr, Ni, Pb and Zn detected in sediments collected in the Po River prodelta (S1 site) suggest the Po River supply, while lower levels of these elements characterize sediments collected in front of the Rimini coast (E1 site), an indication of Northern Apennines provenance. Historical trends of Pb and Zn reconstructed from the sedimentary record around the E1 site document several changes that can be correlated with the industrialization subsequent to World War II, the implementation of the environmental policy in 1976 and the effects of the Comacchio dumping at the end of 1980. At the S1 site, the down core distributions of trace elements indicate a reduction of contaminants due to the introduction of the Italian Law 319/76 and the implementation of anti-pollution policies on automotive Pb (unleaded fuels) in the second half of the 1980s.
We present the results of the tephrochronology study of a 14.49 m long marine sediment core (TR 17–08) collected in the Edisto Inlet, Ross Sea (Antarctica). The core contains four cryptotephra layers ...at 55–56, 512–513, 517–518, and 524–525 cm of depth, which have been characterised by a detailed description of the texture, mineral assemblage, and single glass shards major and trace element geochemistry. The age model of the investigated sedimentary sequence, based on radiocarbon dating, indicates that the topmost cryptotephra correlates with the widespread 1254 CE tephra erupted by a historical eruption (696 ± 2 cal yrs BP) of Mount Rittmann, in northern Victoria Land. Deeper cryptotephra layers were derived from previously unknown explosive eruptions of Mount Melbourne volcano and were emplaced between 1615 cal yrs BP and 1677 cal yrs BP, e.g. between the 3rd and 4th centuries CE. This discovery demonstrates that the Mount Melbourne volcanic complex has been highly active in historical times allowing significant progress in the current understanding of regional eruptive history. Moreover, from a tephrochronological point of view, the detected cryptotephra provide new regional isochron markers to facilitate high-precision correlations and help stratigraphically constrain changes in environmental and climatic conditions that are identified by multidisciplinary studies.
•Four cryptotephra were discovered in a piston core collected in the Edisto Inlet, Ross Sea (Antarctica).•The topmost cryptotephra is associated with the 1254 CE tephra marker from Mt. Rittmann volcano.•Mt. Melbourne volcano is the source of the lowermost tephra.•The tephra document historical eruptions of Mt. Melbourne that occurred between the 3rd and 4th centuries CE.•Excellent tephrostratigraphic markers for the Ross Sea and proxies for the paleo wind circulation of northern Victoria Land.
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GEOZS, IJS, IMTLJ, KILJ, KISLJ, NLZOH, NUK, OILJ, PNG, SAZU, SBCE, SBJE, UILJ, UL, UM, UPCLJ, UPUK, ZAGLJ, ZRSKP
Cdc7 serine/threonine kinase is a key regulator of DNA synthesis in eukaryotic organisms. Cdc7 inhibition through siRNA or prototype small molecules causes p53 independent apoptosis in tumor cells ...while reversibly arresting cell cycle progression in primary fibroblasts. This implies that Cdc7 kinase could be considered a potential target for anticancer therapy. We previously reported that pyrrolopyridinones (e.g., 1) are potent and selective inhibitors of Cdc7 kinase, with good cellular potency and in vitro ADME properties but with suboptimal pharmacokinetic profiles. Here we report on a new chemical class of 5-heteroaryl-3-carboxamido-2-substituted pyrroles (1A) that offers advantages of chemistry diversification and synthetic simplification. This work led to the identification of compound 18, with biochemical data and ADME profile similar to those of compound 1 but characterized by superior efficacy in an in vivo model. Derivative 18 represents a new lead compound worthy of further investigation toward the ultimate goal of identifying a clinical candidate.
The paper is a dialogue with Gregory Bateson and Alvin Toffler, prophetic thinkers that in the middle of the 20th century envisaged, and called for, the education of the future. We owe to Bateson the ...idea of “learning to learn”, on which he began to reflect in the 1940’s and kept thinking throughout his life. The idea was later taken up by Toffler in Future Shock (1970), where he wrote that “the illiterate of the 21st century will not be those who cannot read and write, but those who cannot learn, unlearn, and relearn.” The idea of learning to learn – as well as of metacognition – is widespread today, to the point of being considered one of the key competences needed in our time; however, it is still poorly understood and far from being applied as a guiding principle of educational practice in schools. The historical moment we are experiencing with the COVID-19 pandemic brings the urgent need for change in education, shifting from a paradigm based on merit to a paradigm based on competences. Urgency is an occasion but also a risk: the conditions of students with learning difficulties or in state of poverty might worsen and, overall, inequality might increase. A different, equal and deeply human scenario for the education of the future finds connections with ideas sown in the 20th century and ready to germinate. Facing a future world of which we only know how different it will be from the present world, metacognition and learning to learn appear as the solid ground on which to build the future of education.
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