Bulk equiatomic (Hf-Ta-Zr-Ti)C and (Hf-Ta-Zr-Nb)C high entropy Ultra-High Temperature Ceramic (UHTC) carbide compositions were fabricated by ball milling and Spark Plasma Sintering (SPS). It was ...found that the lattice parameter mismatch of the component monocarbides is a key factor for predicting single phase solid solution formation. The processing route was further optimised for the (Hf-Ta-Zr-Nb)C composition to produce a high purity, single phase, homogeneous, bulk high entropy material (99% density); revealing a vast new compositional space for the exploration of new UHTCs. One sample was observed to chemically decompose; indicating the presence of a miscibility gap. While this suggests the system is not thermodynamically stable to room temperature, it does reveal further potential for the development of new in situ formed UHTC nanocomposites. The optimised material was subjected to nanoindentation testing and directly compared to the constituent mono/binary carbides, revealing a significantly enhanced hardness (36.1 ± 1.6 GPa,) compared to the hardest monocarbide (HfC, 31.5 ± 1.3 GPa) and the binary (Hf-Ta)C (32.9 ± 1.8 GPa).
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IZUM, KILJ, NUK, PILJ, PNG, SAZU, UL, UM, UPUK
The electric current activated/assisted sintering (ECAS) is an ever growing class of versatile techniques for sintering particulate materials. Despite the tremendous advances over the last two ...decades in ECASed materials and products there is a lack of comprehensive reviews on ECAS apparatuses and methods. This paper fills the gap by tracing the progress of ECAS technology from 1906 to 2008 and surveys 642 ECAS patents published over more than a century. It is found that the ECAS technology was pioneered by Bloxam (1906 GB Patent No. 9020) who developed the first resistive sintering apparatus. The patents were searched by keywords or by cross-links and were withdrawn from the Japanese Patent Office (342 patents), the United States Patent and Trademark Office (175 patents), the Chinese State Intellectual Property Office of P.R.C. (69 patents) and the World Intellectual Property Organization (12 patents). A subset of 119 (out of 642) ECAS patents on methods and apparatuses was selected and described in detail with respect to their fundamental concepts, physical principles and importance in either present ECAS apparatuses or future ECAS technologies for enhancing efficiency, reliability, repeatability, controllability and productivity. The paper is divided into two parts, the first deals with the basic concepts, features and definitions of basic ECAS and the second analyzes the auxiliary devices/peripherals. The basic ECAS is classified with reference to discharge time (fast and ultrafast ECAS). The fundamental principles and definitions of ECAS are outlined in accordance with the scientific and patent literature.
Extreme heating and cooling rates, approaching 104 °C min−1 represent a paradigm shift in materials manufacturing. In the past two decades, new techniques like Ultrafast High-temperature Sintering ...(UHS), and Flash sintering (FS) have emerged. Compared to conventional sintering, consolidation times are shortened by at least a thousand folds. Densification and chemical reactions proceed in a far from equilibrium condition. Readily recognized advantages of rapid sintering are suppressed grain growth, reduced loss of volatile elements (Li, Na, K), and limited interdiffusion in multi-layered devices. The accelerated kinetics opens up new opportunities to prepare ceramics with properties not attainable using slow heating rates. In the context of the current global environmental crisis, rapid sintering also holds the promise to decarbonize the sector while reducing the emissions of toxic gases associated with the firing step. This review tracks advances in rapid sintering over the past century. It examines the impact of extreme heating rates on the sintering mechanisms, and microstructural evolution throughout the three stages of sintering.
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GEOZS, IJS, IMTLJ, KILJ, KISLJ, NLZOH, NUK, OILJ, PNG, SAZU, SBCE, SBJE, UILJ, UL, UM, UPCLJ, UPUK, ZAGLJ, ZRSKP
High entropy metal diborides (HEBs) represent a radically new approach to extend the chemical composition window of ultra-high temperature ceramics (UHTCs). In this work, arc-melting was used to ...produce dense HEBs starting from UHTC powders. In order to understand the influence of each individual diboride within the quinary system (HfB2, ZrB2, TiB2, TaB2 and CrB2), we investigated five quaternary equimolar solid solutions e.g. Hf-Zr-Ti-Ta, Hf-Zr-Ti-Cr, Hf-Zr-Ta-Cr, Hf-Ti-Ta-Cr, Zr-Ti-Ta-Cr and the overall quinary equimolar combination. Arc-melting allowed a rapid screening of favorable and unfavorable combinations. The produced HEBs were free from undesired oxides and characterized by linear variation of lattice parameters typical of diborides and binary solid solutions. Because of evaporation during arc melting, CrB2 was hardly found in the solid solution, suggesting that vapor pressure should be taken into account when designing HEB compositions especially for operating temperatures exceeding 2000 °C. Finally, Vickers microhardness ranged between the typical values of starting diborides.
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GEOZS, IJS, IMTLJ, KILJ, KISLJ, NLZOH, NUK, OILJ, PNG, SAZU, SBCE, SBJE, UILJ, UL, UM, UPCLJ, UPUK, ZAGLJ, ZRSKP
This paper reports the electrochemical, optical and thermal effects occurring during flash sintering of 8 mol % yttria-stabilized zirconia (8YSZ). In-situ observations of polycrystalline and single ...crystal specimens revealed electrochemical blackening/darkening during an incubation period prior to flash sintering. The phenomenon is induced by cathodic partial reduction under DC fields. When using a low frequency AC field (0.1⁻10 Hz) the blackening is reversible, following the imposed polarity switching. Thermal imaging combined with sample colour changes and electrical conductivity mapping give a complete picture of the multi-physical phenomena occurring during each stage of the flash sintering event. The partial reduction at the cathode causes a modification of the electrical properties in the sample and the blackened regions, which are close to the cathode, are more conductive than the remainder of the sample. The asymmetrical nature of the electrochemical reactions follows the field polarity and causes an asymmetry in the temperature between the anode and cathode, with the positive electrode tending to overheat. It is also observed that the phenomena are influenced by the quality of the electrical contacts and by the atmosphere used.
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IZUM, KILJ, NUK, PILJ, PNG, SAZU, UL, UM, UPUK
Guided by the theoretical prediction, a new MAX phase V
2
SnC was synthesized experimentally for the first time by reaction of V, Sn, and C mixtures at 1000 °C. The chemical composition and crystal ...structure of this new compound were identified by the cross-check combination of first-principles calculations, X-ray diffraction (XRD), energy dispersive X-ray spectroscopy (EDS), and high resolution scanning transmission electron microscopy (HR-STEM). The stacking sequence of V
2
C and Sn layers results in a crystal structure of space group P6
3
/mmc. The
a
- and
c
-lattice parameters, which were determined by the Rietveld analysis of powder XRD pattern, are 0.2981(0) nm and 1.3470(6) nm, respectively. The atomic positions are V at 4f (1/3, 2/3, 0.0776(5)), Sn at 2d (2/3, 1/3, 1/4), and C at 2a (0, 0, 0). A new set of XRD data of V
2
SnC was also obtained. Theoretical calculations suggest that this new compound is stable with negative formation energy and formation enthalpy, satisfied Born-Huang criteria of mechanical stability, and positive phonon branches over the Brillouin zone. It also has low shear deformation resistance
c
44
(second-order elastic constant,
c
ij
) and shear modulus (
G
), positive Cauchy pressure, and low Pugh’s ratio (
G/B
= 0.500 < 0.571), which is regarded as a quasi-ductile MAX phase. The mechanism underpinning the quasi-ductility is associated with the presence of a metallic bond.
Biomarkers can be used to detect the presence of endothelial and/or alveolar epithelial injuries in case of ARDS. Angiopoietin-2 (Ang-2), soluble intercellular adhesion molecule-1 (ICAM-1), vascular ...cell adhesion protein-1 (VCAM-1), P-selectin and E-selectin are biomarkers of endothelial injury, whereas the receptor for advanced glycation end-products (RAGE) reflects alveolar epithelial injury. The aims of this study were to evaluate whether the plasma concentration of the above-mentioned biomarkers was different 1) in survivors and non-survivors of COVID-19-related ARDS and 2) in COVID-19-related and classical ARDS.
This prospective study was performed in two COVID-19-dedicated Intensive Care Units (ICU) and one non-COVID-19 ICU at Ferrara University Hospital. A cohort of 31 mechanically ventilated patients with COVID-19 ARDS and a cohort of 11 patients with classical ARDS were enrolled. Ang-2, ICAM-1, VCAM-1, P-selectin, E-selectin and RAGE were determined with a bead-based multiplex immunoassay at three time points: inclusion in the study (T1), after 7 ± 2 days (T2) and 14 ± 2 days (T3). The primary outcome was to evaluate the plasma trend of the biomarker levels in survivors and non-survivors. The secondary outcome was to evaluate the differences in respiratory mechanics variables and gas exchanges between survivors and non-survivors. Furthermore, we compared the plasma levels of the biomarkers at T1 in patients with COVID-19-related ARDS and classical ARDS.
In COVID-19-related ARDS, the plasma levels of Ang-2 and ICAM-1 at T1 were statistically higher in non-survivors than survivors, (p = 0.04 and p = 0.03, respectively), whereas those of P-selectin, E-selectin and RAGE did not differ. Ang-2 and ICAM-1 at T1 were predictors of mortality (AUROC 0.650 and 0.717, respectively). At T1, RAGE and P-selectin levels were higher in classical ARDS than in COVID-19-related ARDS. Ang-2, ICAM-1 and E-selectin were lower in classical ARDS than in COVID-19-related ARDS (all p < 0.001).
COVID-19 ARDS is characterized by an early pulmonary endothelial injury, as detected by Ang-2 and ICAM-1. COVID-19 ARDS and classical ARDS exhibited a different expression of biomarkers, suggesting different pathological pathways. Trial registration NCT04343053 , Date of registration: April 13, 2020.
The physiological effects of high-flow nasal cannula O
therapy (HFNC) have been evaluated mainly in patients with hypoxemic respiratory failure. In this study, we compared the effects of HFNC and ...conventional low-flow O
therapy on the neuroventilatory drive and work of breathing postextubation in patients with a background of chronic obstructive pulmonary disease (COPD) who had received mechanical ventilation for hypercapnic respiratory failure.
This was a single center, unblinded, cross-over study on 14 postextubation COPD patients who were recovering from an episode of acute hypercapnic respiratory failure of various etiologies. After extubation, each patient received two 1-h periods of HFNC (HFNC1 and HFNC2) alternated with 1 h of conventional low-flow O
therapy via a face mask. The inspiratory fraction of oxygen was titrated to achieve an arterial O
saturation target of 88-92%. Gas exchange, breathing pattern, neuroventilatory drive (electrical diaphragmatic activity (EAdi)) and work of breathing (inspiratory trans-diaphragmatic pressure-time product per minute (PTP
)) were recorded.
EAdi peak increased from a mean (±SD) of 15.4 ± 6.4 to 23.6 ± 10.5 μV switching from HFNC1 to conventional O
, and then returned to 15.2 ± 6.4 μV during HFNC2 (conventional O
: p < 0.05 versus HFNC1 and HFNC2). Similarly, the PTP
increased from 135 ± 60 to 211 ± 70 cmH
O/s/min, and then decreased again during HFNC2 to 132 ± 56 (conventional O
: p < 0.05 versus HFNC1 and HFNC2).
In patients with COPD, the application of HFNC postextubation significantly decreased the neuroventilatory drive and work of breathing compared with conventional O
therapy.
Needle and plate like single MoAlB crystals were synthesized by reacting MoB and Al powders. The growth of MoAlB single crystals was promoted by either increasing dwell temperature or by adding ...excess of Al. When raising the temperature from 1100 to 1300 °C, the shape of MoAlB single crystals transformed from needle to plate like. The single crystals exhibited anisotropic oxidation resistance where the (0l0) plane showed a better oxidation resistance compared to (l00) and (00l) planes. The oxidization weight gain tested at 1100 °C and weight loss at 1300 °C suggests the beneficial role of a dense Al2O3 scale formed on the plate-like single crystals.
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GEOZS, IJS, IMTLJ, KILJ, KISLJ, NLZOH, NUK, OILJ, PNG, SAZU, SBCE, SBJE, UILJ, UL, UM, UPCLJ, UPUK, ZAGLJ, ZRSKP
The synthesis, microstructure, and properties of high purity dense bulk Mo
2
TiAlC
2
ceramics were studied. High purity Mo
2
TiAlC
2
powder was synthesized at 1873 K starting from Mo, Ti, Al, and ...graphite powders with a molar ratio of 2:1:1.25:2. The synthesis mechanism of Mo
2
TiAlC
2
was explored by analyzing the compositions of samples sintered at different temperatures. It was found that the Mo
2
TiAlC
2
phase was formed from the reaction among Mo
3
Al
2
C, Mo
2
C, TiC, and C. Dense Mo
2
TiAlC
2
bulk sample was prepared by spark plasma sintering (SPS) at 1673 K under a pressure of 40 MPa. The relative density of the dense sample was 98.3%. The mean grain size was 3.5 μm in length and 1.5 μm in width. The typical layered structure could be clearly observed. The electrical conductivity of Mo
2
TiAlC
2
ceramic measured at the temperature range of 2–300 K decreased from 0.95 × 10
6
to 0.77 × 10
6
Ω–1·m–1. Thermal conductivity measured at the temperature range of 300–1273 K decreased from 8.0 to 6.4 W·(m·K)
–1
. The thermal expansion coefficient (TEC) of Mo
2
TiAlC
2
measured at the temperature of 350–1100 K was calculated as 9.0 × 10
–6
K
–1
. Additionally, the layered structure and fine grain size benefited for excellent mechanical properties of low intrinsic Vickers hardness of 5.2 GPa, high flexural strength of 407.9 MPa, high fracture toughness of 6.5 MPa·m
1/2
, and high compressive strength of 1079 MPa. Even at the indentation load of 300 N, the residual flexural strength could hold 84% of the value of undamaged one, indicating remarkable damage tolerance. Furthermore, it was confirmed that Mo
2
TiAlC
2
ceramic had a good oxidation resistance below 1200 K in the air.
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