Summary
The Orchidaceae is a diverse and ecologically important plant family. Approximately 69% of all orchid species are epiphytes, which provide diverse microhabitats for many small animals and ...fungi in the canopy of tropical rainforests. Moreover, many orchids are of economic importance as food flavourings or ornamental plants. Phalaenopsis aphrodite, an epiphytic orchid, is a major breeding parent of many commercial orchid hybrids. We provide a high‐quality chromosome‐scale assembly of the P. aphrodite genome. The total length of all scaffolds is 1025.1 Mb, with N50 scaffold size of 19.7 Mb. A total of 28 902 protein‐coding genes were identified. We constructed an orchid genetic linkage map, and then anchored and ordered the genomic scaffolds along the linkage groups. We also established a high‐resolution pachytene karyotype of P. aphrodite and completed the assignment of linkage groups to the 19 chromosomes using fluorescence in situ hybridization. We identified an expansion in the epiphytic orchid lineage of FRS5‐like subclade associated with adaptations to the life in the canopy. Phylogenetic analysis further provides new insights into the orchid lineage‐specific duplications of MADS‐box genes, which might have contributed to the variation in labellum and pollinium morphology and its accessory structure. To our knowledge, this is the first orchid genome to be integrated with a SNP‐based genetic linkage map and validated by physical mapping. The genome and genetic map not only offer unprecedented resources for increasing breeding efficiency in horticultural orchids but also provide an important foundation for future studies in adaptation genomics of epiphytes.
Full text
Available for:
BFBNIB, DOBA, FZAB, GIS, IJS, IZUM, KILJ, NLZOH, NUK, OILJ, PILJ, PNG, SAZU, SBCE, SBMB, UILJ, UKNU, UL, UM, UPUK
Artificial intelligence (AI)-based methods have emerged as powerful tools to transform medical care. Although machine learning classifiers (MLCs) have already demonstrated strong performance in ...image-based diagnoses, analysis of diverse and massive electronic health record (EHR) data remains challenging. Here, we show that MLCs can query EHRs in a manner similar to the hypothetico-deductive reasoning used by physicians and unearth associations that previous statistical methods have not found. Our model applies an automated natural language processing system using deep learning techniques to extract clinically relevant information from EHRs. In total, 101.6 million data points from 1,362,559 pediatric patient visits presenting to a major referral center were analyzed to train and validate the framework. Our model demonstrates high diagnostic accuracy across multiple organ systems and is comparable to experienced pediatricians in diagnosing common childhood diseases. Our study provides a proof of concept for implementing an AI-based system as a means to aid physicians in tackling large amounts of data, augmenting diagnostic evaluations, and to provide clinical decision support in cases of diagnostic uncertainty or complexity. Although this impact may be most evident in areas where healthcare providers are in relative shortage, the benefits of such an AI system are likely to be universal.
Full text
Available for:
EMUNI, FIS, FZAB, GEOZS, GIS, IJS, IMTLJ, KILJ, KISLJ, MFDPS, NLZOH, NUK, OILJ, PNG, SAZU, SBCE, SBJE, SBMB, SBNM, UKNU, UL, UM, UPUK, VKSCE, ZAGLJ
Development of advanced supercapacitors which provide greater energy density while retaining high power density can revolutionize energy storage solutions for both civilian and military applications. ...Herein, we present fabrication and characterization of nanostructured supercapacitor electrodes using manganese dioxide and carbon nanotubes (MnO
2
/CNTs) on flexible graphite foil substrate for integration into a supercapacitor prototype cell, without any additives or binders. Low-cost, thermal chemical vapor deposition process in a tube furnace was used to synthesize CNTs, acting as the current conductors, directly on both sides of the flexible, conducting graphite foil current collector. Thin-film MnO
2
deposition on the CNTs was achieved by electrochemical technique using in situ reduction of potassium permanganate (KMnO
4
), without any supporting electrolyte, which provides excellent bonding between the two for enhanced stability. Eight electrodes were assembled in a stack with polypropylene separators and packaged in a pouch cell with organic electrolyte (1 M tetraethylammonium tetrafluoroborate in acetonitrile) yielding a total capacitance of nearly 2.8 F at 2.5 V and a corresponding specific capacitance of 388 F g
−1
was calculated for MnO
2
. High cell capacitance and a low DC resistance yield a maximum specific power value of 36.1 kW kg
−1
and a maximum specific energy of 48.5 Wh kg
−1
at 2.5 V when considering the total mass including that of CNTs and MnO
2
. Cycling data showed nearly 100% capacitance retention over 3000 charge discharge cycles. To the best of our knowledge, a supercapacitor prototype cell in this configuration has not been fabricated and/or reported previously.
Graphical Abstract
Schematic representation of the prototype supercapacitor cell consisting of a stack of eight electrodes with polypropylene separators. On the right is a blow-up representation of a double side electrode with MnO
2
/CNT on both sides of the graphite foil substrate. The equivalent circuit diagram can be seen on the left, consisting of seven capacitors in parallel
Full text
Available for:
DOBA, EMUNI, FIS, FZAB, GEOZS, GIS, IJS, IMTLJ, IZUM, KILJ, KISLJ, MFDPS, NLZOH, NUK, OBVAL, OILJ, PILJ, PNG, SAZU, SBCE, SBJE, SBMB, SBNM, UILJ, UKNU, UL, UM, UPUK, VKSCE, ZAGLJ
Graphene and its composites are widely investigated as supercapacitor electrodes due to their large specific surface area. However, the severe aggregation and disordered alignment of graphene sheets ...hamper the maximum utilization of its surface area. Here we report an optimized structure for supercapacitor electrode, i.e., the vertical graphene sheets, which have a vertical structure and open architecture for ion transport pathway. The effect of morphology and orientation of vertical graphene on the performance of supercapacitor is examined using a combination of model calculation and experimental study. Both results consistently demonstrate that the vertical graphene electrode has a much superior performance than that of lateral graphene electrode. Typically, the areal capacitances of a vertical graphene electrode reach 8.4 mF/cm2 at scan rate of 100 mV/s; this is about 38% higher than that of a lateral graphene electrode and about 6 times higher than that of graphite paper. To further improve its performance, a MnO2 nanoflake layer is coated on the surface of graphene to provide a high pseudocapacitive contribution to the overall areal capacitance which increases to 500 mF/cm2 at scan rate of 5 mV/s. The reasons for these significant improvements are studied in detail and are attributed to the fast ion diffusion and enhanced charge storage capacity. The microscopic manipulation of graphene electrode configuration could greatly improve its specific capacitance, and furthermore, boost the energy density of supercapacitor. Our results demonstrate that the vertical graphene electrode is more efficient and practical for the high performance energy storage device with high power and energy densities.
Full text
Available for:
IJS, KILJ, NUK, PNG, UL, UM
Abstract
Background
Sudden cardiac arrest (SCA) is a critical complication of acute myocardial infarction, especially ST-segment elevation myocardial infarction (STEMI). This study identified the ...risk factors for SCA in patients with STEMI before receiving catheterization.
Methods
We retrospectively analyzed the data of patients with STEMI and cardiac arrest who presented to a tertiary care center in Taiwan between January 1, 2016, and December 31, 2019. Only patients with coronary artery disease (CAD) confirmed by coronary angiography were included in this study. We collected the patients’ demographic and clinical data, such as age, sex, medical history, estimated glomerular filtration rate (eGFR), and coronary angiographic findings. The primary outcome of this study was SCA in patients with STEMI. Continuous and nominal variables were compared using the two-sample Student's
t
-test and chi-squared test, respectively. The results of logistic regression were subjected to multivariate analysis with adjustment for possible confounders.
Results
A total of 920 patients with STEMI and coronary angiography–documented CAD and 108 patients with SCA who presented between January 1, 2016, and December 31, 2019, were included. The bivariate logistic regression analysis of patients’ demographic data revealed that patients with STEMI and SCA were slightly younger, were more likely to have diabetes mellitus, and had a lower eGFR than did the patients without SCA. The coronary angiographic findings indicated a higher prevalence of left main CAD and three-vessel disease in patients with SCA than in patients without SCA. Multivariate logistic regression revealed that left main CAD (odds ratio OR: 3.77; 95% confidence interval CI, 1.84 to 7.72), a lower eGFR (OR: 0.97; 95% CI, 0.96 to 0.98), and younger age (OR: 0.98; 95% CI, 0.96 to 0.99) were the risk factors for SCA in patients with STEMI.
Conclusions
Left main CAD, lower eGFR, and younger age are the risk factors for cardiac arrest in patients with acute myocardial infarction.
Full text
Available for:
IZUM, KILJ, NUK, PILJ, PNG, SAZU, UL, UM, UPUK
This study develops the first heteropentametal extended metal atom chain (EMAC) in which a string of nickel cores is incorporated with a diruthenium unit to tune the molecular properties. ...Spectroscopic, crystallographic, and magnetic characterizations show the formation of a fully delocalized Ru25+ unit. This Ru2‐containing EMAC exhibits single‐molecule conductance four‐fold superior to that of the pentanickel complex and results in features of negative differential resistance (NDR), which are unobserved in analogues of pentanickel and pentaruthenium EMACs. A plausible mechanism for the NDR behavior is proposed for this diruthenium‐modulated EMAC.
Strings attached: The first pentametal heteronuclear string, Ni+Ru25+Ni2+Ni2+, is prepared and the electronic structure is assigned by magnetic properties, DFT simulation, UV/Vis, and XPS spectra. This molecule is four‐fold more conductive than that of its pentanickel analogue and exhibits characteristics of negative differential resistance (NDR; see figure).
Full text
Available for:
BFBNIB, FZAB, GIS, IJS, KILJ, NLZOH, NUK, OILJ, SAZU, SBCE, SBMB, UL, UM, UPUK
Display omitted
•Vertically aligned CNTs successfully grown on aluminum substrates.•Catalyst assisted CVD process developed in a hot-filament chamber.•Conventional microfabrication process used to ...create an array layout.•3D micropatterned CNT array provides >10× area for incorporating cathode material.
Attempts to grow carbon nanotubes directly on to aluminum (Al) substrates have had limited success, primarily due to its relatively low melting point of 660°C. In this work, we have successfully synthesized vertically aligned CNTs (VACNTs) in a planar configuration (48µm tall) as well as, for the first time, a micropatterned array with 36µm tall CNTs on Al substrates. This was achieved by combining conventional microfabrication steps for patterning an array and a catalyst-assisted hot-filament CVD process with methane as carbon source gas for CNT synthesis. Such substrates can provide highly conductive and high specific surface area host materials for cathodes in lithium ion batteries and supercapacitors. We have demonstrated a >10× increase in surface area available for coating cathode nanoparticles in the 3D micropatterned CNT array, as compared to the planar configuration.
Full text
Available for:
GEOZS, IJS, IMTLJ, KILJ, KISLJ, NUK, OILJ, PNG, SAZU, SBCE, SBJE, UL, UM, UPCLJ, UPUK, ZRSKP
The surrounding waters of Taiwan are evaluated as a moderate risk environment by Casualty Return, Lloyd’s Registry of Shipping. Among all types of maritime accidents, ship collisions occur most ...often, which has severe consequences, including ship damage, sinking and death of crews, and destruction of marine environments. It is, therefore, imperative to mitigate the risk of ship collision by exploring the risk factors and then providing preventive measures. This study invited domain experts to form a decision-making group, which helped with the risk assessment. The initial set of risk factors was selected from the literature. The expert group then identified seven representative risk factors using rough set theory (RST). The researchers worked with the experts to delineate the diagram of a bow-tie analysis (BTA), which provided the causes, consequences, and preventive and mitigation measures for ship collision incidents. The results show an integrated research framework for the risk assessment of ship collision that can effectively identify key factors and associated managerial strategies to improve navigation safety, leading to a sound marine environment.
In this study, a 3 × 3 blue micro-LED array with a pixel size of 10 × 10 μm
2
and a pitch of 15 μm was fabricated on an epilayer grown on a sapphire substrate using metalorganic chemical vapor ...deposition technology. The fabrication process involved photolithography, wet and dry etching, E-beam evaporation, and ion implantation technology. Arsenic multi-energy implantation was utilized to replace the mesa etching for electrical isolation, where the implantation depth increased with the average energy. Different ion depth profiles had varying effects on electrical properties, such as forward current and leakage currents, potentially causing damage to the n-GaN layer and increasing the series resistance of the LEDs. As the implantation depth increased, the light output power and peak external quantum efficiency of the LEDs also increased, improving from 5.33 to 9.82%. However, the efficiency droop also increased from 46.3 to 48.6%.
The conventional lithium-ion battery fabrication process involves mixing of the active cathode material with additives and tape casting on metallic current collectors. The thickness of this layer ...limits the performance of the cathode. In this work, a novel cathode platform is presented consisting of a micropatterned array of vertically aligned carbon nanotubes (CNTs) on aluminum (Al) foil that serves as host for active cathode powders. This highly conductive three-dimensional structure provides a high specific surface area to support greater mass loading capable of achieving high energy and power densities. The feasibility of this structure was demonstrated by using commercially available lithium iron phosphate (LFP) powder which was processed and dispersed using two different techniques—vibration-assisted drip-coating and electrophoretic deposition. A high specific capacity of 143 mAh/g at 3.4 V was achieved at C/20 rate for the novel cathode fabricated using electrophoretic deposition, which seemed superior to vibration-assisted drip coating with its easier application, more uniform particle coating, stronger particle attachment to the CNTs, and better electrochemical performance. In addition, CNT array on Al has been demonstrated to be a viable candidate for fabricating cathodes for energy storage applications without the need for any additives and/or binders.
Full text
Available for:
EMUNI, FIS, FZAB, GEOZS, GIS, IJS, IMTLJ, KILJ, KISLJ, MFDPS, NLZOH, NUK, OBVAL, OILJ, PNG, SAZU, SBCE, SBJE, SBMB, SBNM, UKNU, UL, UM, UPUK, VKSCE, ZAGLJ
PDF
