Instability in mixed‐halide perovskites (MHPs) is a key issue limiting perovskite solar cells and light‐emitting diodes (LEDs). One form of instability arises during the processing of MHP quantum ...dots using an antisolvent to precipitate and purify the dots forming surface traps that lead to decreased luminescence, compromised colloidal stability, and emission broadening. Here, the introduction of inorganic ligands in the antisolvents used in dot purification is reported in order to overcome this problem. MHPs that are colloidally stable for over 1 year at 25 °C and 40% humidity are demonstrated and films that are stable under 100 W cm−2 photoirradiation, 4× longer than the best previously reported MHPs, are reported. In LEDs, the materials enable an EQE of 24.4% (average 22.5 ± 1.3%) and narrow emission (full‐width at half maximum of 30 nm). Sixfold‐enhanced operating stability relative to the most stable prior red perovskite LEDs having external quantum efficiency >20% is reported.
Bandgap‐stable and efficient CsPbBrxI3−x perovskite light‐emitting diodes (PLEDs) are demonstrated by adopting an in situ inorganic ligand exchange. This strategy enables bandgap‐stable mixed‐halide perovskites with nanocrystal colloidal stability exceeding 1 year at ambient conditions. The PLEDs exhibit an external quantum efficiency (EQE) of 24.4% and sixfold‐enhanced operating stability relative to the most stable prior red perovskite LEDs having EQEs >20%.
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BFBNIB, FZAB, GIS, IJS, KILJ, NLZOH, NUK, OILJ, SBCE, SBMB, UL, UM, UPUK
The all‐inorganic nature of CsPbI3 perovskites allows to enhance stability in perovskite devices. Research efforts have led to improved stability of the black phase in CsPbI3 films; however, these ...strategies—including strain and doping—are based on organic‐ligand‐capped perovskites, which prevent perovskites from forming the close‐packed quantum dot (QD) solids necessary to achieve high charge and thermal transport. We developed an inorganic ligand exchange that leads to CsPbI3 QD films with superior phase stability and increased thermal transport. The atomic‐ligand‐exchanged QD films, once mechanically coupled, exhibit improved phase stability, and we link this to distributing strain across the film. Operando measurements of the temperature of the LEDs indicate that KI‐exchanged QD films exhibit increased thermal transport compared to controls that rely on organic ligands. The LEDs exhibit a maximum EQE of 23 % with an electroluminescence emission centered at 640 nm (FWHM: ≈31 nm). These red LEDs provide an operating half‐lifetime of 10 h (luminance of 200 cd m−2) and an operating stability that is 6× higher than that of control devices.
Stable and efficient CsPbI3 perovskite light‐emitting diodes (PLEDs) are demonstrated by resurfacing perovskite with the aid of inorganic ligands (KI). The resurfaced perovskites show a 7× higher phase stability and higher thermal conductivity than in films with organic ligands. The PLEDs exhibit a record‐high external quantum efficiency (EQE) of ≈23 % and a 100‐fold improvement in the operating stability compared to previous EQE devices.
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BFBNIB, FZAB, GIS, IJS, KILJ, NLZOH, NUK, OILJ, SBCE, SBMB, UL, UM, UPUK
In this paper, the distributed adaptive event-triggered fault-tolerant consensus of general linear multiagent systems (MASs) is considered. First, in order to deal with multiplicative fault, a ...distributed event-triggered consensus protocol is designed. Using distributed adaptive online updating strategies, the computation of the minimum eigenvalue of Laplacian matrix is avoided. Second, some adaptive parameters are introduced in trigger function to improve the self-regulation ability of event-triggered mechanism. The new trigger threshold is both state-dependent and time-dependent, which is independent of the number of agents. Then sufficient conditions are derived to guarantee the leaderless and leader-following consensus. On the basis of this, the results are extended to the case of actuator saturation. It is proved the Zeno-behavior of considered event-triggered mechanism is avoided. At last, the effectiveness of the proposed methods are demonstrated by three simulation examples.
Dopamine (DA), as one of the central neurotransmitters, plays an important role in many physiological and pathological processes. Detection of DA is critical to diagnose and monitor some neurological ...diseases. In this work, a novel on-off ratiometric electrochemical sensor with molecularly imprinted polymers (MIPs) as target molecule recognizer has been developed for selective and accurate detection of DA. Nanoporous gold (NPG) was electrodeposited on bare gold electrode, which not only benefited the output signal amplification, but also provided enlarged surface for immobilization of polythionine (pThi) and MIPs. Oxidation of DA and pThi served as response signal and internal reference signal, respectively. The oxidation peak currents of DA at +0.12 V increased with increasing the concentration of DA, while the peak currents of pThi at −0.2 V decreased simultaneously. Due to the specificity from MIPs and the built-in correction from pThi, the fabricated sensor showed excellent performance in view of selectivity and reproducibility. It's worth to mention that even if the surface area and morphology of working electrode underwent huge variation deliberately, the assay deviation among these ratiometric sensors was largely reduced around 10 times. The proposed sensor demonstrated a broad dynamic range of 0.3–100 μM, as well as a low detection limit of 0.1 μM (S/N = 3). Moreover, superior anti-interfering ability toward DA detection was obtained despite the presence of interferents at high concentration in artificial cerebrospinal fluid (aCSF). Therefore, this work is expected to provide an alternative pathway for constructing ratiometric electrochemical sensor and offer reliable determination of small molecules with high selectivity and stability.
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•A ratiometric electrochemical dopamine sensor was designed to improve the reproducibility and robustness.•Molecularly imprinted polymer was served as dopamine molecule recognizer with enhanced specificity.•Measurement error was controlled effectively even though sensors with diverse areas and morphologies were adopted.•The sensors showed excellent DA sensing performance in artificial cerebrospinal fluid (aCSF).
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GEOZS, IJS, IMTLJ, KILJ, KISLJ, NLZOH, NUK, OILJ, PNG, SAZU, SBCE, SBJE, UILJ, UL, UM, UPCLJ, UPUK, ZAGLJ, ZRSKP
Protein lysine deacetylases have a pivotal role in numerous biological processes and can be divided into the Rpd3/Hda1 and sirtuin families, each having members in diverse organisms including ...prokaryotes. In vertebrates, the Rpd3/Hda1 family contains 11 members, traditionally referred to as histone deacetylases (HDAC) 1-11, which are further grouped into classes I, II and IV. Whereas most class I HDACs are subunits of multiprotein nuclear complexes that are crucial for transcriptional repression and epigenetic landscaping, class II members regulate cytoplasmic processes or function as signal transducers that shuttle between the cytoplasm and the nucleus. Little is known about class IV HDAC11, although its evolutionary conservation implies a fundamental role in various organisms.
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DOBA, IJS, IZUM, KILJ, NUK, PILJ, PNG, SAZU, UILJ, UKNU, UL, UM, UPUK
In this work, a green, simple, economical method was developed in the synthesis of fluorescent carbon dots using pork as carbon source. The as-prepared carbon dots exhibit exceptional advantages ...including high fluorescent quantum yield (17.3%) and satisfactory chemical stability. The fluorescence of carbon dots based nanosensor can be selectively and efficiently quenched by uric acid. This phenomenon was used to develop a fluorescent method for facile detection of uric acid within a linear range of 0.1–100μM and 100–500μM, with a detection limit of 0.05μM (S/N=3). Finally, the proposed method was successfully applied in the determination of uric acid in human serum and urine samples with satisfactory recoveries, which suggested that the new nanosensors have great prospect toward the detection of uric acid in human fluids.
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•Fluorescent carbon dots (CDs) were synthesized using pork.•The as-prepared CDs show high long-term stability.•Uric acid (UA) can quench the fluorescence of CDs owing to static quenching.•The CDs were used for the sensitive and selective detection of UA in human fluid.
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GEOZS, IJS, IMTLJ, KILJ, KISLJ, NLZOH, NUK, OILJ, PNG, SAZU, SBCE, SBJE, UL, UM, UPCLJ, UPUK, ZRSKP
This paper proposes a new modulation scheme for the three-level active neutral-point-clamped (ANPC) converter. This scheme yields new commutation loops for the three-level ANPC phase leg, which ...contain paralleled switching devices during commutation. The new commutation loops have better switching performance with smaller switching stress for some devices. There are also more evenly distributed loss and stress for each switching device on the phase leg. Moreover, the switching states of the new modulation scheme also reduce the conduction loss of the neutral current. In addition, the proposed modulation scheme needs less pulsewidth modulation (PWM) comparators per phase compared with the conventional scheme. The simple gate signal logic can be applied to any sinusoidal PWM or space vector modulation strategies. Double pulse tests for the new commutation loops show the improved switching characteristics under different load current cases. In addition, the quantitative analysis of the system loss breakdown and the phase leg loss distribution verifies the loss reduction and redistribution result. The proposed method is also applied on a 200-kW three-level ANPC converter for verification.
Under the influence of global epidemics and the need for urban expansion, many outpatient buildings have been rapidly constructed, but the problem of high energy consumption has been neglected. There ...is a lack of research on the impact of outpatient building forms on energy consumption in different climate zones. Many studies have demonstrated that the energy consumption of a given building can be greatly reduced by adopting a reasonable spatial form design at the early stages of design. Therefore, if architects choose a reasonable spatial form, this could effectively reduce energy consumption. In this study, outpatient building cases in China were summarized, and three typical spatial forms were proposed: the centralized, corridor, and courtyard forms. The DesignBuilder tool was used to simulate and analyse the typical building energy consumption in different climate zones. The results showed that the corridor form (southwards) should be chosen in the severe cold zone, the centralized form (southwards) should be chosen in the cold zone and the hot summer and cold winter zone, the centralized form (northwards) should be chosen in the hot summer and warm winter zone, and the centralized or corridor form can be chosen in the warm zone. The results of this study could provide a reference for energy-efficient design of outpatient buildings in China and other regions with similar conditions and could help architects quickly select reasonable spatial forms at the early stages of design.
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DOBA, IZUM, KILJ, NUK, PILJ, PNG, SAZU, SIK, UILJ, UKNU, UL, UM, UPUK
A continuous and ultra-thin metal-phenolic network top layer on a polyethersulfone substrate surface was used as metal precursor for a metal-organic framework (MOF) membrane synthesis. A plant ...polyphenol tannic acid (TA) and Zn2+ based network top layer prepared by a layer-by-layer (LBL) self-assembly process was immersed into a 2-methylimidazole aqueous solution, and then a ZIF-8 top layer was facilely formed due to the partial self-conversion of TA-Zn2+ network to ZIF-8. The LBL process provides sufficient controllability of preparing a continuous and ultra-thin ZIF-8 top layer, which are crucial factors for nanofiltration membrane separation performance. The optimized ZIF-8 membrane exhibited a pure water permeance (PWP) of 5.1 L m−2 h−1 bar−1, a 55.2% NaCl rejection and a 93.6% Na2SO4 rejection. This is one of the few MOF membranes that possesses a divalent inorganic salt rejection higher than 90%. The novel zinc source of ZIF-8 synthesis disclosed in this study can provide a new incentive to not only MOF membrane preparation but also engineering MOFs towards a wide energy and environmental applications.
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•Metal-phenolic network was used as a precursor for a ZIF-8 membrane synthesis.•Layer-by-layer assembly of TA and Zn2+ gives a continuous and ultrathin precursor layer.•A continuous and ultrathin ZIF-8 membrane was synthesized.•It is one of the few MOF membranes whose divalent ion rejection higher than 90%.
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GEOZS, IJS, IMTLJ, KILJ, KISLJ, NLZOH, NUK, OILJ, PNG, SAZU, SBCE, SBJE, UILJ, UL, UM, UPCLJ, UPUK, ZAGLJ, ZRSKP
The harmonic filter for a three-level neutral-point-clamped (NPC) grid interface converter is designed in this paper with good filtering performance and small component size. LCL topology is selected ...because of the attenuation and size tradeoff. The design of the inverter-side inductor L1 is emphasized due to its cost. A detailed inductor current ripple analysis is given based on the space vector modulation. The analysis derives the inductor volt-second and the maximum current ripple equation in line cycle. It also reveals the switching cycle current ripple distribution over a line cycle, with the consideration of power factor. The total system loss is calculated with different ripple current. Inductor L1 is determined by the loss and size tradeoff. Also the capacitor- and grid-side inductor L2 is designed based on attenuation requirement. Different damping circuits for LCL filter are compared and investigated in detail. The filter design is verified by both simulation and 200-kVA three-level NPC converter hardware.
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