Transient electronics that can physically vanish in solution can offer opportunities to address the ecological challenges for dealing with the rapidly growing electronic waste. As one important ...component, it is desirable that memory devices combined with the transient feature can also be developed as secrecy information storage systems besides the above advantage. Resistive switching (RS) memory is one of the most promising technologies for next‐generation memory. Herein, the biocompatible pectin extracted from natural orange peel is introduced to fabricate RS memory devices (Ag/pectin/indium tin oxides (ITO)), which exhibit excellent RS characteristics, such as forming free characteristic, low operating voltages (≈1.1 V), fast switching speed (<70 ns), long retention time (>104 s), and multilevel RS behaviors. The device performance is not degraded after 104 bending cycles, which will be beneficial for flexible memory applications. Additionally, instead of using acid solution, the Ag/pectin/ITO memory device can be dissolved rapidly in deionized water within 10 min thanks to the good solubility arising from ionization of its carboxylic groups, which shows promising application for green electronics. The present biocompatible memory devices based on natural pectin suggest promising material candidates toward enabling high‐density secure information storage systems applications, flexible electronics, and green electronics.
Biocompatible pectin extracted from natural orange peel is introduced to fabricate flexible multilevel resistive switching (RS) memory devices (Ag/pectin/indium tin oxides). The device exhibits excellent RS characteristics and it can be dissolved in deionized water rapidly thanks to the good solubility of pectin arising from ionization of its carboxylic groups.
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BFBNIB, FZAB, GIS, IJS, KILJ, NLZOH, NUK, OILJ, SAZU, SBCE, SBMB, UL, UM, UPUK
Ultrathin metal layers can be highly active carbon dioxide electroreduction catalysts, but may also be prone to oxidation. Here we construct a model of graphene confined ultrathin layers of highly ...reactive metals, taking the synthetic highly reactive tin quantum sheets confined in graphene as an example. The higher electrochemical active area ensures 9 times larger carbon dioxide adsorption capacity relative to bulk tin, while the highly-conductive graphene favours rate-determining electron transfer from carbon dioxide to its radical anion. The lowered tin-tin coordination numbers, revealed by X-ray absorption fine structure spectroscopy, enable tin quantum sheets confined in graphene to efficiently stabilize the carbon dioxide radical anion, verified by 0.13 volts lowered potential of hydroxyl ion adsorption compared with bulk tin. Hence, the tin quantum sheets confined in graphene show enhanced electrocatalytic activity and stability. This work may provide a promising lead for designing efficient and robust catalysts for electrolytic fuel synthesis.
Metal-organic frameworks on electrospun modified nanofibers and N-doped carbon nanotubes are constructed for an high-performance asymmetric supercapacitor.
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Metal-organic framework ...(MOF)-based electrode materials have become a hot subject for supercapaitors. Herein, Ni-MOFs grown on Co nanoparticles modified carbon nanofibers (CNFs) (C-Co@MOF) are prepared via a facile process. Interestingly, the presence of Co nanoparticles in CNFs not only boosts the hybridization of CNF and MOFs, but also releases Co ions to participate in the growth of MOF, leading to a favorable electrochemical behavior. In detail, the specific capacitance of C-Co@MOF reaches 1201.6 F g−1 that exceeds those of C-M@MOFs (M = Ni, V, Mo, Mn, Fe, Cu and Zn) and CNF@MOF. More importantly, an asymmetric solid-state supercapacitor is assembled using C-Co@MOF and nitrogen-doped carbon nanotubes derived from polyaniline as positive and negative electrode materials, respectively, representing a high energy density of 37.0 Wh kg−1 and outstanding durability. This work highlights the superiority of electrospun CNFs modified by metal nanoparticles for the growth of MOF, showing great potential for electrochemical energy storage and conversion applications.
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GEOZS, IJS, IMTLJ, KILJ, KISLJ, NLZOH, NUK, OILJ, PNG, SAZU, SBCE, SBJE, UILJ, UL, UM, UPCLJ, UPUK, ZAGLJ, ZRSKP
Solar CO2 reduction efficiency is largely limited by poor photoabsorption, sluggish electron–hole separation, and a high CO2 activation barrier. Defect engineering was employed to optimize these ...crucial processes. As a prototype, BiOBr atomic layers were fabricated and abundant oxygen vacancies were deliberately created on their surfaces. X‐ray absorption near‐edge structure and electron paramagnetic resonance spectra confirm the formation of oxygen vacancies. Theoretical calculations reveal the creation of new defect levels resulting from the oxygen vacancies, which extends the photoresponse into the visible‐light region. The charge delocalization around the oxygen vacancies contributes to CO2 conversion into COOH* intermediate, which was confirmed by in situ Fourier‐transform infrared spectroscopy. Surface photovoltage spectra and time‐resolved fluorescence emission decay spectra indicate that the introduced oxygen vacancies promote the separation of carriers. As a result, the oxygen‐deficient BiOBr atomic layers achieve visible‐light‐driven CO2 reduction with a CO formation rate of 87.4 μmol g−1 h−1, which was not only 20 and 24 times higher than that of BiOBr atomic layers and bulk BiOBr, respectively, but also outperformed most previously reported single photocatalysts under comparable conditions.
BiOBr atomic layers with abundant oxygen vacancies were synthesized. The photoresponse of BiOBr extends into the visible range, while charge delocalization around the vacancies contributes to CO2 conversion into COOH*. The material catalyzes visible‐light‐driven CO2 reduction with a CO formation rate of 87.4 μmol g−1 h−1, which is 20 and 24 times greater than that of BiOBr atomic layers and bulk BiOBr, respectively.
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BFBNIB, FZAB, GIS, IJS, KILJ, NLZOH, NUK, OILJ, SAZU, SBCE, SBMB, UL, UM, UPUK
The concurrent transformation of carbon dioxide and water into hydrocarbons and oxygen by low-photonic-energy IR light still represents a huge challenge. Here, we design an ultrathin conductor ...system, in which the special partially occupied band serves as the mediator to simultaneously guarantee IR light harvesting and satisfy band-edge positions, while the ultrathin configuration improves charge separation rates and surface redox kinetics. Taking the low cost and earth-abundant CuS as an example, we first fabricate ultrathin CuS layers, where temperature-dependent resistivities, valence-band spectra, and theoretical calculations affirm their metallic nature. Synchrotron-radiation photoelectron and ultraviolet–visible–near-infrared spectra show that metallic CuS atomic layers could realize a new cooperative intraband–interband transition under IR light irradiation, where the generated electrons and holes could simultaneously involve the carbon dioxide reduction and water oxidation reactions. As a result, CuS atomic layers exhibit nearly 100% selective CO production with an evolution rate of 14.5 μmol g–1 h–1 under IR light irradiation, while the catalytic performance shows no obvious decay after a 96 h test. Briefly, benefiting from ultrahigh conductivity and a unique partially occupied band, abundant conductor materials such as conducting metal sulfides and metal nitrides hold great promise for applications as effective IR light responsive photocatalysts.
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IJS, KILJ, NUK, PNG, UL, UM
Unraveling the role of surface oxide on affecting its native metal disulfide’s CO2 photoreduction remains a grand challenge. Herein, we initially construct metal disulfide atomic layers and hence ...deliberately create oxidized domains on their surfaces. As an example, SnS2 atomic layers with different oxidation degrees are successfully synthesized. In situ Fourier transform infrared spectroscopy spectra disclose the COOH* radical is the main intermediate, whereas density-functional-theory calculations reveal the COOH* formation is the rate-limiting step. The locally oxidized domains could serve as the highly catalytically active sites, which not only benefit for charge-carrier separation kinetics, verified by surface photovoltage spectra, but also result in electron localization on Sn atoms near the O atoms, thus lowering the activation energy barrier through stabilizing the COOH* intermediates. As a result, the mildly oxidized SnS2 atomic layers exhibit the carbon monoxide formation rate of 12.28 μmol g–1 h–1, roughly 2.3 and 2.6 times higher than those of the poorly oxidized SnS2 atomic layers and the SnS2 atomic layers under visible-light illumination. This work uncovers atomic-level insights into the correlation between oxidized sulfides and CO2 reduction property, paving a new way for obtaining high-efficiency CO2 photoreduction performances.
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IJS, KILJ, NUK, PNG, UL, UM
Additive manufacturing (AM) technologies appear as a paradigm for scalable manufacture of electrochemical energy storage (EES) devices, where complex 3D architectures are typically required but are ...hard to achieve using conventional techniques. The combination of these technologies and innovative material formulations that maximize surface area accessibility and ion transport within electrodes while minimizing space are of growing interest. Herein, aqueous inks composed of atomically thin (1–3 nm) 2D Ti3C2Tx
with large lateral size of about 8 µm possessing ideal viscoelastic properties are formulated for extrusion‐based 3D printing of freestanding, high specific surface area architectures to determine the viability of manufacturing energy storage devices. The 3D‐printed device achieves a high areal capacitance of 2.1 F cm−2 at 1.7 mA cm−2 and a gravimetric capacitance of 242.5 F g−1 at 0.2 A g−1 with a retention of above 90% capacitance for 10 000 cycles. It also exhibits a high energy density of 0.0244 mWh cm−2 and a power density of 0.64 mW cm−2 at 4.3 mA cm−2. It is anticipated that the sustainable printing and design approach developed in this work can be applied to fabricate high‐performance bespoke multiscale and multidimensional architectures of functional and structural materials for integrated devices in various applications.
A current‐collector‐free, interdigitated‐supercapacitor device is manufactured by 3D printing with water‐based MXene ink. Simple modifications to the ink synthesis and formulation provide unique rheological properties, which enable the printability of 3D structures of up to 25 layers high. The final structures demonstrate high specific area, resulting in high areal capacitance of the micro‐supercapacitor device.
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BFBNIB, FZAB, GIS, IJS, KILJ, NLZOH, NUK, OILJ, SAZU, SBCE, SBMB, UL, UM, UPUK
Converting CO2 and H2O into carbon‐based fuel by IR light is a tough task. Herein, compared with other single‐component photocatalysts, the most efficient IR‐light‐driven CO2 reduction is achieved by ...an element‐doped ultrathin metallic photocatalyst‐Ni‐doped CoS2 nanosheets (Ni‐CoS2). The evolution rate of CH4 over Ni‐CoS2 is up to 101.8 μmol g−1 h−1. The metallic and ultrathin nature endow Ni‐CoS2 with excellent IR light absorption ability. The PL spectra and Arrhenius plots indicate that Ni atoms could facilitate the separation of photogenerated carriers and the decrease of the activation energy. Moreover, in situ FTIR, DFT calculations, and CH4‐TPD reveal that the doped Ni atoms in CoS2 could effectively depress the formation energy of the *COOH, *CHO and desorption energy of CH4. This work manifests that element doping in atomic level is a powerful way to control the reaction intermediates, providing possibilities to realize high‐efficiency IR‐light‐driven CO2 reduction.
It is a tough task to achieve IR‐light‐driven CO2 reduction. Herein, an element‐doped ultrathin metallic photocatalyst is designed to achieve IR‐light‐driven CO2 reduction. Among the reported single‐component photocatalysts, the most efficient IR‐light‐driven CO2 reduction is realized by Ni‐doped CoS2 nanosheets.
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BFBNIB, FZAB, GIS, IJS, KILJ, NLZOH, NUK, OILJ, SAZU, SBCE, SBMB, UL, UM, UPUK
An effective tumor vaccine vector that can rapidly display neoantigens is urgently needed. Outer membrane vesicles (OMVs) can strongly activate the innate immune system and are qualified as ...immunoadjuvants. Here, we describe a versatile OMV-based vaccine platform to elicit a specific anti-tumor immune response via specifically presenting antigens onto OMV surface. We first display tumor antigens on the OMVs surface by fusing with ClyA protein, and then simplify the antigen display process by employing a Plug-and-Display system comprising the tag/catcher protein pairs. OMVs decorated with different protein catchers can simultaneously display multiple, distinct tumor antigens to elicit a synergistic antitumour immune response. In addition, the bioengineered OMVs loaded with different tumor antigens can abrogate lung melanoma metastasis and inhibit subcutaneous colorectal cancer growth. The ability of the bioengineered OMV-based platform to rapidly and simultaneously display antigens may facilitate the development of these agents for personalized tumour vaccines.
Rapid cut‐off of blood supply in diseases involving thrombosis is a major cause of morbidity and mortality worldwide. However, the current thrombolysis strategies offer limited results due to the ...therapeutics' short half‐lives, low targeting ability, and unexpected bleeding complications. Inspired by the innate roles of platelets in hemostasis and pathological thrombus, platelet membrane‐camouflaged polymeric nanoparticles (nanoplatelets) are developed for targeting delivery of the thrombolytic drug, recombinant tissue plasminogen activator (rt‐PA), to local thrombus sites. The tailor‐designed nanoplatelets efficiently accumulate at the thrombi in pulmonary embolism and mesenteric arterial thrombosis model mice, eliciting a significantly enhanced thrombolysis activity compared to free rt‐PA. In addition, the nanoplatelets exhibit improved therapeutic efficacy over free rt‐PA in an ischemic stroke model. Analysis of in vivo coagulation indicators suggests the nanoplatelets might possess a low risk of bleeding complications. The hybrid biomimetic nanoplatelets described offer a promising solution to improve the efficacy and reduce the bleeding risk of thrombolytic therapy in a broad spectrum of thrombosis diseases.
Tailor‐designed platelet membrane‐camouflaged polymeric nanoparticles (designated as nanoplatelet) for targeting delivery of the thrombolytic drug (rt‐PA) are developed to navigate multiple acute thrombosis diseases. This nanoplatform can efficiently target to clot sites and dissolve thrombus, simultaneously overcoming the main disadvantages of existing thrombolysis therapy (i.e., life‐threatening bleeding risk, a narrow therapeutic time window, and extremely low drug circulation time).
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BFBNIB, FZAB, GIS, IJS, KILJ, NLZOH, NUK, OILJ, SAZU, SBCE, SBMB, UL, UM, UPUK
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