A majority of anion exchange membrane fuel cells (AEMFCs) reported in the literature have been unable to achieve high current or power. A recently proposed theory is that the achievable current is ...largely limited by poorly balanced water during cell operation. In this work, we present convincing experimental results – coupling operando electrochemical measurements and neutron imaging – supporting this theory and allowing the amount and distribution of water, and its impact on AEMFC performance, to be quantified for the first time. We also create new electrode compositions by systematically manipulating the ionomer and carbon content in the anode catalyst layer, which allowed us to alleviate the mass transport behavior limitations of H 2 /O 2 AEMFCs and achieve a new record-setting peak power density of 1.9 W cm −2 – a step-change to existing literature. Our efforts cast a new light on the design and optimization of AEMFCs – potentially changing the way that AEMFCs are constructed and operated.
There is a need to understand the water dynamics of alkaline membrane fuel cells under various operating conditions to create electrodes that enable high performance and stable, long-term operation. ...Here we show, via operando neutron imaging and operando micro X-ray computed tomography, visualizations of the spatial and temporal distribution of liquid water in operating cells. We provide direct evidence for liquid water accumulation at the anode, which causes severe ionomer swelling and performance loss, as well as cell dryout from undesirably low water content in the cathode. We observe that the operating conditions leading to the highest power density during polarization are not generally the conditions that allow for long-term stable operation. This observation leads to new catalyst layer designs and gas diffusion layers. This study reports alkaline membrane fuel cells that can be operated continuously for over 1000 h at 600 mA cm
with voltage decay rate of only 32-μV h
- the best-reported durability to date.
Enhancement of plant drought stress tolerance by plant growth‐promoting rhizobacteria (PGPR) has been increasingly documented in the literature. However, most studies to date have focused on ...PGPR‐root/plant interactions; very little is known about PGPR's role in mediating physiochemical and hydrological changes in the rhizospheric soil that may impact plant drought stress tolerance. Our study aimed to advance mechanistic understanding of PGPR‐mediated biophysical changes in the rhizospheric soil that may contribute to plant drought stress tolerance in addition to plant responses. We measured soil water retention characteristics, hydraulic conductivity, and water evaporation in soils with various textures (i.e., pure sand, sandy soil, and clay) as influenced by a representative PGPR (Bacillus subtilis strain UD1022) using the HYPROP system. We found that all PGPR‐treated soils held more water and had reduced hydraulic conductivity and accumulative evaporation, compared to their corresponding controls. We discuss three mechanisms, due to B. subtilis incubation or production of extracellular polymeric substances (EPS), that are potentially responsible for the changes in hydraulic properties and soil evaporation: (i) EPS have a large water holding capacity; (ii) EPS alter soil matrix structure and connectivity of pore space; (iii) EPS modify the physicochemical properties of water (surface tension and viscosity). These results clearly demonstrate PGPR's ability to increase water availability to plants by slowing down evaporation and by increasing the time available for plants to make metabolic adjustments to drought stress.
Plain Language Summary
PGPR is a group of beneficial bacteria known to improve plant growth by, e.g., reducing pathogenic infection and/or promoting drought/salt tolerance. Despite the important role PGPR could potentially play in reducing drought stress to plants, we lack a complete understanding on the mechanisms through which PGPR mediate plant tolerance to drought. This study aimed to advance mechanistic understanding of PGPR‐mediated biophysical changes in soil through microbe‐soil interactions, to complement better understanding gained from previous studies that focused on microbe‐plant interactions. Through laboratory measurements and imaging of water retention in soil, we show that a representative PGPR (B. subtilis UD1022) can increase soil water retention and reduce soil water evaporation. This effect is likely caused by the PGPR's ability to produce extracellular polymeric substances, which have high water holding capacity and can induce changes in soil physical properties. These changes lead to slower evaporation from soil, which can make more water available to plants as well as increase the time available for plants to make metabolic adjustments to drought stress. Our results provide scientific support to recent efforts in promoting application of rhizobacteria isolates as “underground resource” to contribute to solving globally challenging issues, e.g., water resource shortage and food security.
Key Points
Improved soil water holding capacity and reduced soil water evaporation were found for PGPR‐treated soil samples
EPS production was responsible for the changes in the observed hydraulic properties
Findings imply PGPR increase water availability, slow down the drying processes, and relieve the stress experienced by roots upon drought
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BFBNIB, FZAB, GIS, IJS, KILJ, NLZOH, NUK, OILJ, SAZU, SBCE, SBMB, UL, UM, UPUK
There are conflicting views in the literature concerning the optimum moisture state for an existing substrate prior to the application of a repair material. Both saturated-surface-dry (SSD) and dry ...substrates have been found to be preferable in a variety of studies. One confounding factor is that some studies evaluate bonding of the repair material to the substrate via pull-off (direct tension) testing, while others have employed some form of shear specimens as their preferred testing configuration. Available evidence suggests that dry substrate specimens usually perform equivalently or better in shear testing, while SSD ones generally exhibit higher bond strengths when a pull-off test is performed, although exceptions to these trends have been observed. This paper applies a variety of microstructural characterization tools to investigate the interfacial microstructure that develops when a fresh repair material is applied to either a dry or SSD substrate. Simultaneous neutron and X-ray radiography are employed to observe the dynamic microstructural rearrangements that occur at this interface during the first 4 h of curing. Based on the differences in water movement and densification (particle compaction) that occur for the dry and SSD specimens, respectively, a hypothesis is formulated as to why different bond tests may favor one moisture state over the other, also dependent on their surface roughness. It is suggested that the compaction of particles at a dry substrate surface may increase the frictional resistance when tested under slant shear loading, but contribute relatively little to the bonding when the interface is submitted to pull-off forces. For maximizing bond performance, the fluidity of the repair material and the roughness and moisture state of the substrate must all be given adequate consideration.
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GEOZS, IJS, IMTLJ, KILJ, KISLJ, NLZOH, NUK, OILJ, PNG, SAZU, SBCE, SBJE, UL, UM, UPCLJ, UPUK, ZRSKP
Recent advances in visualization technologies are providing new discoveries as well as answering old questions with respect to the phase structure and flow of hydrogen-rich fluids, such as water and ...oil, within porous media. Magnetic resonance and x-ray imaging are sometimes employed in this context, but are subject to significant limitations. In contrast, neutrons are ideally suited for imaging hydrogen-rich fluids in abiotic non-hydrogenous porous media because they are strongly attenuated by hydrogen and can “see” through the solid matrix in a non-destructive fashion. This review paper provides an overview of the general principles behind the use of neutrons to image hydrogen-rich fluids in both 2-dimensions (radiography) and 3-dimensions (tomography). Engineering standards for the neutron imaging method are examined. The main body of the paper consists of a comprehensive review of the diverse scientific literature on neutron imaging of static and dynamic experiments involving variably-saturated geomaterials (rocks and soils) and engineered porous media (bricks and ceramics, concrete, fuel cells, heat pipes, and porous glass). Finally some emerging areas that offer promising opportunities for future research are discussed.
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GEOZS, IJS, IMTLJ, KILJ, KISLJ, NUK, OILJ, PNG, SAZU, SBCE, SBJE, UL, UM, UPCLJ, UPUK
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•Low to high porosity gradient in the anode PTL for high performance.•50% reduction in PTL gas with low to high porosity gradient.•Enhanced water permeability for low to high porosity ...gradient.
Decarbonizing society’s energy infrastructure is foundational for a sustainable future and can be realized by harnessing renewable energy for clean hydrogen and on-demand power with fuel cells. Here, we elucidate how graded porous transport layers (PTLs) are instrumental for high performance gas evolving electrochemical energy conversion devices, with an emphasis on polymer electrolyte membrane (PEM) electrolyzers. Spatially graded PTLs fabricated by vacuum plasma spraying are examined via in operando neutron imaging, electrochemical characterization, and pore network modelling. The results reveal the staggering benefits of positioning the lower porosity region adjacent to the catalyst layer and the higher porosity region adjacent to the flow field, which lead to current densities up to 4.5 A/cm2 with a 29 % reduction in cell potential, 38 % reduction in mass transport overpotential, and 50 % reduction in PTL gas saturation. The liquid water permeability of the PTL also enhances by an order of magnitude, with a drastic reduction in gas saturation adjacent to the catalyst layer. Custom graded PTLs have the potential to transform performance levels for a broad array of gas evolving electrochemical energy conversion devices.
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GEOZS, IJS, IMTLJ, KISLJ, NLZOH, NUK, OILJ, SAZU, SBCE, UILJ, UL, UM, UPCLJ, UPUK, ZAGLJ
The FtsZ protein is a central component of the bacterial cell division machinery. It polymerizes at mid-cell and recruits more than 30 proteins to assemble into a macromolecular complex to direct ...cell wall constriction. FtsZ polymers exhibit treadmilling dynamics, driving the processive movement of enzymes that synthesize septal peptidoglycan (sPG). Here, we combine theoretical modelling with single-molecule imaging of live bacterial cells to show that FtsZ's treadmilling drives the directional movement of sPG enzymes via a Brownian ratchet mechanism. The processivity of the directional movement depends on the binding potential between FtsZ and the sPG enzyme, and on a balance between the enzyme's diffusion and FtsZ's treadmilling speed. We propose that this interplay may provide a mechanism to control the spatiotemporal distribution of active sPG enzymes, explaining the distinct roles of FtsZ treadmilling in modulating cell wall constriction rate observed in different bacteria.
An experimental study to investigate the through-plane thermal conductivity of three different diffusion media (DM) used in polymer electrolyte fuel cells (PEFCs) as a function of compression (from ...0.1 MPa to 2 MPa) and saturation (from 0 to 25%) was performed. Additionally, measurements to determine the stress–strain relationship for the materials were made using an optical microscope. Both compression and water content had a significant impact on the through-plane thermal conductivity, which should be accounted for in multiphase modeling efforts. An analytical expression for the theoretical maximum of the through-plane thermal conductivity, as a function of both compression and saturation, was developed to help understand the nature of liquid connectivity in saturated pores. Additionally, a relationship was developed to predict actual thermal conductivity of the tested materials as a function of both compression and saturation based on experimentally measured data.
•Stress–strain relationship was measured to determine thickness and porosity of DM.•Thermal conductivity was found highly dependent on compression and water content.•Theoretical prediction of the maximum thermal conductivity was developed.•Internal cell temperature difference was estimated as a function of saturation.•PCI flow is more influential on multiphase transport with DM at lower saturation.
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GEOZS, IJS, IMTLJ, KILJ, KISLJ, NUK, OILJ, PNG, SAZU, SBCE, SBJE, UL, UM, UPCLJ, UPUK
Liquid water saturation profiles were determined using high resolution neutron radiography for commercially available fuel cell materials and hardware. Temperature, pressure, and relative humidity ...(concentration) gradients were imposed on the cell to determine individual influences on water content for each gradient. The asymmetric anode/cathode channel/land architecture used in this work results in significant water accumulation in the anode diffusion media with saturation values of up to ∼50%. Anode water content was found to change substantially with imposed pressure or concentration gradient, whereas the cathode saturation profile remained relatively consistent, indicating the channel/land ratio and thickness have a determinant role in diffusion media retention. The data generated in this work has been made publicly available through www.pemfcdata.org, and should be useful for computational modelers seeking validation data.
•High resolution neutron radiography used to determine through-plane water content.•Test conditions chosen to push limitations of multi-phase models.•Online database provides rich validation data for multiphase models.•Flow field geometry significantly influences diffusion media saturation levels.•Anode was more sensitive to water content with asymmetric flow field.
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GEOZS, IJS, IMTLJ, KILJ, KISLJ, NUK, OILJ, PNG, SAZU, SBCE, SBJE, UL, UM, UPCLJ, UPUK
We demonstrate a three phase-grating moiré neutron interferometer in a highly intense neutron beam as a robust candidate for large area interferometry applications and for the characterization of ...materials. This novel far-field moiré technique allows for broad wavelength acceptance and relaxed requirements related to fabrication and alignment, thus circumventing the main obstacles associated with perfect crystal neutron interferometry. We observed interference fringes with an interferometer length of 4 m and examined the effects of an aluminum 6061 alloy sample on the coherence of the system. Experiments to measure the autocorrelation length of samples and the universal gravitational constant are proposed and discussed.
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CMK, CTK, FMFMET, IJS, NUK, PNG, UL, UM
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