Microplastic (MP) pollution is a raising global concern in recent years due to its wide distribution. Additionally, most of the MPs have undergone extensive weathering in the environment, and ...weathered MPs may exhibit different physicochemical properties from pristine ones. The review reveals the change in physicochemical properties (e.g. size, color, crystallinity, mechanical property and oxygen-containing groups) and the release of additives and MP-derived intermediates (i.e. oligomers and oxygenated compounds) during weathering processes. Weathering further affects the sorption behavior of MPs for environmental pollutants because of the changed crystallinity, specific surface area and oxygen functional groups. The interaction mechanisms of pristine and weathered MPs with pollutants are summarized, and how weathering processes affect sorption behavior is critically revealed. Because of the changed size, color and surface charges, weathered MPs might be ingested by aquatic organisms in different ways from the pristine ones. The detailed effects of weathering on the ingestion of MPs are discussed, and the potential toxicity of leachates from weathering processes is evaluated. In addition, the environmental components (e.g. natural organic matter and salinity) and biofilm correlated to the sorption behavior of MPs are reviewed. As for the knowledge gap, further studies should focus on the long-term weathering of MPs and the relationships between weathering properties and sorption capacities toward pollutants. The potential risks of weathered MPs and leachates on organisms should be explored.
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•Weathering significantly changes the physicochemical properties of microplastics.•Surface area, oxygen groups and crystallinity critically affect sorption of pollutants.•Effects of weathering on the risks of microplastics and leachates are revealed.•NOM, salinity and biofilms involved in the environmental behavior are reviewed.
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GEOZS, IJS, IMTLJ, KILJ, KISLJ, NLZOH, NUK, OILJ, PNG, SAZU, SBCE, SBJE, UILJ, UL, UM, UPCLJ, UPUK, ZAGLJ, ZRSKP
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•Aging of polystyrene (PS) microplastics was accelerated by photo-Fenton reaction.•The intermediates released from aging process of PS were analyzed.•Aging process significantly ...changed the adsorption mechanism of PS for pharmaceuticals.•Aging intermediates affected the adsorption of PS microplastics for pharmaceuticals.•Impact of aging intermediates mainly depended on their electrostatic interaction with PS.
In the environment, aging obviously changes physicochemical properties of microplastics (MPs), but the effects of aging process on adsorption behavior of MPs are not fully understood. In this study, the aging of polystyrene (PS) was accelerated by photo-Fenton reaction. The adsorption mechanism of different aged PS toward atorvastatin (ATV) and amlodipine (AML) and the role of PS-derived intermediates in adsorption process were investigated. Results showed that the adsorption of pristine PS toward pharmaceuticals relied on hydrophobic and π-π interaction, while for aged PS, electrostatic interaction and hydrogen bonding controlled the adsorption. The study revealed that the intermediates released from aging process in high concentration (TOC of 10 mg/L) significantly decreased the adsorption of ATV (10 mg/L) on PS (5.0 g/L) but increased the adsorption of AML (10 mg/L). However, those intermediates at environmental concentration (0.1 mg/L) exhibited low effects on adsorption of pharmaceuticals (1.0 mg/L) on MPs (0.5 g/L of PS). The impact mainly depended on electrostatic interaction between MPs and aging intermediates. Besides, the adsorption of low-degree aged PS was more susceptible to the aging intermediates than that of high-degree aged ones. These findings highlight significant implication of MP-derived intermediates in aquatic environments.
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GEOZS, IJS, IMTLJ, KILJ, KISLJ, NLZOH, NUK, OILJ, PNG, SAZU, SBCE, SBJE, UILJ, UL, UM, UPCLJ, UPUK, ZAGLJ, ZRSKP
Herein, we report a strategy to construct highly efficient perfluorooctanoic acid (PFOA) adsorbents by installing synergistic electrostatic/hydrophobic sites onto porous organic polymers (POPs). The ...constructed model material of PAF-1-NDMB (NDMB = N,N-dimethyl-butylamine) demonstrates an exceptionally high PFOA uptake capacity over 2000 mg g
, which is 14.8 times enhancement compared with its parent material of PAF-1. And it is 32.0 and 24.1 times higher than benchmark materials of DFB-CDP (β-cyclodextrin (β-CD)-based polymer network) and activated carbon under the same conditions. Furthermore, PAF-1-NDMB exhibits the highest k
value of 24,000 g mg
h
among all reported PFOA sorbents. And it can remove 99.99% PFOA from 1000 ppb to <70 ppt within 2 min, which is lower than the advisory level of Environmental Protection Agency of United States. This work thus not only provides a generic approach for constructing PFOA adsorbents, but also develops POPs as a platform for PFOA capture.
A novel ternary eutectic salt, NaNO3-KNO3-Na2SO4 (TMS), was designed and prepared for thermal energy storage (TES) to address the issues of the narrow temperature range and low specific heat of solar ...salt molten salt. The thermo-physical properties of TMS-2, such as melting point, decomposition temperature, fusion enthalpy, density, viscosity, specific heat capacity and volumetric thermal energy storage capacity (ETES), were determined. Furthermore, a comparison of the thermo-physical properties between commercial solar salt and TMS-2 was carried out. TMS-2 had a melting point 6.5 °C lower and a decomposition temperature 38.93 °C higher than those of solar salt. The use temperature range of TMS molten salt was 45.43 °C larger than that of solar salt, which had been widened about 13.17%. Within the testing temperature range, the average specific heat capacity of TMS-2 (1.69 J·K−1·g−1) was 9.03% higher than that of solar salt (1.55 J·K−1·g−1). TMS-2 also showed higher density, slightly higher viscosity and higher ETES. XRD, FTIR and Raman spectra SEM showed that the composition and structure of the synthesized new molten salt were different, which explained the specific heat capacity increasing. Molecular dynamic (MD) simulation was performed to explore the different macroscopic properties of solar salt and TMS at the molecular level. The MD simulation results suggested that cation–cation and cation–anion interactions became weaker as the temperature increased and the randomness of molecular motion increased, which revealed that the interaction between the cation cluster and anion cluster became loose. The stronger interaction between Na-SO4 cation–anion clusters indicated that TMS-2 molten salt had a higher specific heat capacity than solar salt. The result of the thermal stability analysis indicated that the weight losses of solar salt and TMS-2 at 550 °C were only 27% and 53%, respectively. Both the simulation and experimental study indicated that TMS-2 is a promising candidate fluid for solar power generation systems.
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IZUM, KILJ, NUK, PILJ, PNG, SAZU, UL, UM, UPUK
Abstract
Crystalline porous materials such as covalent organic frameworks (COFs), metal-organic frameworks (MOFs) and porous organic cages (POCs) have been widely applied in various fields with ...outstanding performances. However, the lack of general and effective methodology for large-scale production limits their further industrial applications. In this work, we developed a general approach comprising high pressure homogenization (HPH), which can realize large-scale synthesis of crystalline porous materials including COFs, MOFs, and POCs under benign conditions. This universal strategy, as illustrated in the proof of principle studies, has prepared 4 COFs, 4 MOFs, and 2 POCs. It can circumvent some drawbacks of existing approaches including low yield, high energy consumption, low efficiency, weak mass/thermal transfer, tedious procedures, poor reproducibility, and high cost. On the basis of this approach, an industrial homogenizer can produce 0.96 ~ 580.48 ton of high-performance COFs, MOFs, and POCs per day, which is unachievable via other methods.
With the advent of the era of big data, various education models adapted to informatization and modernization are emerging. Microlectures, as a new type of educational resource, are gradually being ...widely applied in the field of online education. This article introduces the characteristics and advantages of microlectures, and analyzes the issues that should be paid attention to in the construction of micro course resources, and proposes a construction plan. Taking the computer courses in universities as an example, an innovative teaching method based on microlecture technology is designed to build “micro” classrooms for university computer courses, ultimately improving teaching quality and efficiency. With the continuous development of technology, microlectures will play a more important role in future university teaching.
A viscoacoustic vertical transverse isotropic (VTI) quasi-differential wave equation, which takes account for both the viscosity and anisotropy of media, is proposed for wavefield simulation in this ...study. The finite difference method is used to solve the equations, for which the attenuation terms are solved in the wavenumber domain, and all remaining terms in the time-space domain. To stabilize the adjoint wavefield, robust regularization operators are applied to the wave equation to eliminate the high-frequency component of the numerical noise produced during the backward propagation of the viscoacoustic wavefield. Based on these strategies, we derive the corresponding gradient formula and implement a viscoacoustic VTI full waveform inversion (FWI). Numerical tests verify that our proposed viscoacoustic VTI FWI can produce accurate and stable inversion results for viscoacoustic VTI data sets. In addition, we test our method's sensitivity to velocity, Q, and anisotropic parameters. Our results show that the sensitivity to velocity is much higher than that to Q and anisotropic parameters. As such, our proposed method can produce acceptable inversion results as long as the Q and anisotropic parameters are within predefined thresholds.
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GEOZS, IJS, IMTLJ, KILJ, KISLJ, NUK, OILJ, PNG, SAZU, SBCE, SBJE, UL, UM, UPCLJ, UPUK, ZRSKP
In marine seismic exploration, elastic reverse time migration (ERTM) uses both compressional (P-) and shear (S-) waves of ocean-bottom cable (OBC) data to produce multi-component images with adequate ...amplitude information and illumination of the subsurface. If the fluid-solid medium has an irregular seabed interface, the conventional rectangular-grid-based finite difference (FD) method cannot obtain accurate source and receiver wavefields. In addition, the conventional ERTM applies Helmholtz decomposition to separate P- and S-wavefields, suffering from a change of the wavefield dynamics properties and polarity reversals in PS- and SP-image components. To overcome these problems, we propose a curvilinear-coordinate marine separated-wavefield elastic reverse time migration (CM-SERTM). In this method, the fluid-solid velocity models are meshed into orthogonal grids and mapped to the curvilinear coordinates. A curvilinear-coordinate acoustic-elastic coupled forward modelling algorithm is then developed by introducing boundary functions to combine the acoustic and elastic equations together. The decoupled P- and S-wave equations in the curvilinear coordinates and vector imaging conditions are introduced to implement the CM-SERTM. In numerical examples, we use a simple fluid-solid model and a modified Marmousi2 model to verify that our CM-SERTM method has great superiority over three conventional ERTMs.
•We propose a curvilinear-coordinate marine separated-wavefield elastic reverse time migration.•A curvilinear-coordinate coupled acoustic-elastic wavefields simulation algorithm is developed.•Eight-component imaging conditions are introduced to suppress the crosstalk noises.•Our method has great superiority in suppressing spurious diffraction and P- and S-wave crosstalk artifacts
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GEOZS, IJS, IMTLJ, KILJ, KISLJ, NUK, OILJ, PNG, SAZU, SBCE, SBJE, UL, UM, UPCLJ, UPUK, ZRSKP