Nanomaterials open an alternative way for water disinfection. However, limitations such as aggregation, toxicity, and complex post‐treatment block their practical application. In this study, an ...antibacterial silver/reduced graphene oxide (Ag/rGO) hydrogel consisting of controlled porous rGO network and well‐dispersed Ag nanoparticle is synthesized by a facile hydrothermal reaction. Scanning electron microscopy, transmission electron microscope, X‐ray diffraction, mercury porosimetry, and Fourier transform IR spectroscopy are employed to characterize the Ag/rGO hydrogel. The 3D structure of the rGO network serves as an excellent support for Ag nanoparticles. Disinfection experiments show that the Ag/rGO hydrogel exhibits good efficacy against Escherichia coli when used as a bactericidal filter driven by gravity. The mechanistic study indicates that bacteria cells are inactivated due to cell membrane damage induced by silver nanoparticles and rGO nanosheets when they flow through Ag/rGO hydrogel. Moreover, due to the retaining of Ag by rGO, the leaching level of silver from Ag/rGO hydrogel is considerably lower than the drinking water standard. This study sheds new light on designing antibacterial materials for point‐of‐use water disinfection application.
A novel bactericidal silver/reduced graphene oxide (Ag/rGO) hydrogel with well‐dispersed Ag nanoparticles and controlled porous rGO network is synthesized by an environment‐friendly one‐pot hydrothermal reaction. The highly porous Ag/rGO hydrogel exhibits excellent antibacterial performance when it is used to filter real impaired water driven only by gravity, inactivating more than 94% of Escherichia coli cells and around 99% of coliforms.
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BFBNIB, FZAB, GIS, IJS, KILJ, NLZOH, NUK, OILJ, SAZU, SBCE, SBMB, UL, UM, UPUK
The synthesis of hydrogen peroxide (H2O2) from H2O and O2 by metal-free photocatalysts (e.g., graphitic carbon nitride, C3N4) is a potentially promising approach to generate H2O2. However, the ...photocatalytic H2O2 generation activity of the pristine C3N4 in pure H2O is poor due to unpropitious rapid charge recombination and unfavorable selectivity. Herein, we report a facile method to boost the photocatalytic H2O2 production by grafting cationic polyethylenimine (PEI) molecules onto C3N4. Experimental results and density functional theory (DFT) calculations demonstrate PEI can tune the local electronic environment of C3N4. The unique intermolecular electronic interaction in PEI/C3N4 not only improves the electron–hole separation but also promotes the two-electron O2 reduction to H2O2 via the sequential two-step single-electron reduction route. With the synergy of improved charge separation and high selectivity of two-electron O2 reduction, PEI/C3N4 exhibits an unexpectedly high H2O2 generation activity of 208.1 μmol g–1 h–1, which is 25-fold higher than that of pristine C3N4. This study establishes a paradigm of tuning the electronic property of C3N4 via functional molecules for boosted photocatalysis activity and selectivity.
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IJS, KILJ, NUK, PNG, UL, UM
With energy intake restriction and exercise remaining the key diet and lifestyle approaches to weight loss, this is not without potential negative implications for body composition, metabolic health, ...and quality and quantity of life. Ideally, weight loss should be derived almost exclusively from the fat mass compartment as this is the main driver of metabolic disease, however, several studies have shown that there is an accompanying loss of tissue from the fat-free compartment, especially skeletal muscle. Population groups including post-menopausal women, the elderly, those with metabolic disease and athletes may be particularly at risk of skeletal muscle loss when following a weight management programme. Research studies that have addressed this issue across a range of population groups are reviewed with a focus upon the contribution of resistance and endurance forms of exercise and a higher intake dietary protein above the current guideline of 0.8 g/kg body weight/day. While findings can be contradictory, overall, the consensus appears that fat-free and skeletal muscle masses can be preserved, albeit to varying degrees by including both forms of exercise (but especially resistance forms) in the weight management intervention. Equally, higher intakes of protein can protect loss of these body compartments, acting either separately or synergistically with exercise. Elderly individuals in particular may benefit most from this approach. Thus, the evidence supports the recommendations for intakes of protein above the current guidelines of 0.8 g/kg body weight/d for the healthy elderly population to also be incorporated into the dietary prescription for weight management in this age group.
Stormwater biofilters have great potential to treat stormwater for harvesting and reuse, but their variable performance in pathogen removal requires further optimisation prior to widespread uptake. ...This paper provides the first evidence that real time control (RTC) of stormwater biofilters can mitigate the impact of operational characteristics that result in poor microbial removal. We developed two RTC strategies and validated them using long-term laboratory experiments, utilising biofilters with a raised outlet pipe that creates a submerged zone. The first RTC strategy focuses on delivering the best water quality for harvesting and reuse or for recreational waterways. It has two components which ensure adequate treatment (microbial die-off): (1) it retains water in the biofilter for at least two days before allowing any further inputs into the system, and (2) the input volume is restricted to the submerged zone’s pore volume. This strategy was effective and significantly improved water quality in the biofilter effluent. However, since the system favours bypassing influent to ensure good quality effluent, only 28.4% of the stormwater was treated. This still resulted in a 62.3% reduction in the influent E. coli load because the system was effective at removing E. coli under controlled conditions. The second RTC strategy builds upon the first strategy, and focuses on delivering a balance between good water quality for harvesting and protecting the environment (i.e., lower bypass). Three hours before the next rainfall event begins, the water that has remained in the biofilter’s submerged zone for at least two days is drained and collected for harvesting through a bottom pipe. When stormwater inflow begins, the bottom pipe is closed and the biofilter operates without control, with water leaving the biofilter to the environment via the raised outlet pipe. The harvested effluent of this RTC strategy met the Australian stormwater harvesting guideline requirements for dual reticulation with indoor and outdoor use and irrigation of commercial food crops. Although only 5.4% of stormwater was collected for harvesting in this strategy, the environment was better protected because of a significantly reduced bypass volume. Our experiments also showed that the nutrient and sediment removal was high for both RTC strategies. This study presents the first stepping stone toward RTC of stormwater biofilters, demonstrating that these systems can deliver safe stormwater for harvesting and reuse, and for active recreational uses.
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•First attempt of real time control (RTC) in biofilters for stormwater harvesting.•Developed and validated two RTC strategies for microbial removal enhancement.•The effluent of RTC biofilters could meet the requirements in harvesting guidelines.•The nutrient and sediment removal was also high for both RTC strategies.•Analysed practical implication to explore RTC application in stormwater harvesting.
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GEOZS, IJS, IMTLJ, KILJ, KISLJ, NLZOH, NUK, OILJ, PNG, SAZU, SBCE, SBJE, UL, UM, UPCLJ, UPUK, ZRSKP
Current Water Sensitive Urban Design (WSUD) models are either purely technical or overly simplified, lacking consideration of urban planning and stakeholder preferences to adequately support ...stakeholders. We developed the Urban Biophysical Environments and Technologies Simulator (UrbanBEATS), which integrates stormwater management with urban planning to support the design and implementation of WSUD. This study specifically describes and tests UrbanBEATS' WSUD Planning Module, which combines spatial analysis, infrastructure design, preference elicitation and Monte Carlo methods to generate feasible stormwater management and harvesting infrastructure options in greenfield and existing urban environments. By applying UrbanBEATS to a real-world greenfield development case study in Melbourne, Australia (with data sourced from the project's water management plans and design consultants), we explore the variety of options generated by the model and analyse them collectively to demonstrate that UrbanBEATS can design similar WSUD systems (e.g. select suitable technology types, their sizes and locations) to actual infrastructure choices.
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•We develop and test a spatial algorithm for designing stormwater management infrastructure.•We integrate design of Water Sensitive Urban Design (WSUD) systems with urban planning.•We test our model against an already implemented integrated water management plan of a greenfield site.•Our model provides a useful method for exploring stakeholder preferences in WSUD planning.
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GEOZS, IJS, IMTLJ, KILJ, KISLJ, NLZOH, NUK, OILJ, PNG, SAZU, SBCE, SBJE, UILJ, UL, UM, UPCLJ, UPUK, ZAGLJ, ZRSKP
Urban stormwater is a crucial resource at a time when climate change and population growth threaten freshwater supplies; but there are health risks from contaminants, such as toxic metals. It is ...vitally important to understand how to use this resource safely and responsibly. Our study investigated the extent of metal contamination in vegetable crops irrigated with stormwater under short- and long-term conditions. We created artificially aged gardens by adding metal-contaminated sediment to soil, simulating accumulation of metals in the soil from irrigation with raw stormwater over zero, five and ten years. Our crops--French bean (Phaseolus vulgaris), kale (Brassica oleracea var. acephala), and beetroot (Beta vulgaris)--were irrigated twice a week for 11 weeks, with either synthetic stormwater or potable water. They were then tested for concentrations of Cd, Cr, Pb, Cu and Zn. An accumulation of Pb was the most marked sign of contamination, with six of nine French bean and seven of nine beetroot leaf samples breaching Australia's existing guidelines. Metal concentration in a crop tended to increase with the effective age of the garden; but importantly, its rate of increase did not match the rate of increase in the soil. Our study also highlighted differences in sensitivity between different crop types. French bean demonstrated the highest levels of uptake, while kale displayed restrictive behaviour. Our study makes it clear: irrigation with stormwater is indeed feasible, as long as appropriate crops are selected and media are frequently turned over. We have also shown that an understanding of such risks yields meaningful information on appropriate safeguards. A holistic approach is needed--to account for all routes to toxic metal exposure, including especially Pb. A major outcome of our study is critical information for minimising health risks from stormwater irrigation of crops.
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DOBA, IZUM, KILJ, NUK, PILJ, PNG, SAZU, SIK, UILJ, UKNU, UL, UM, UPUK
Porous pavements are commonly used stormwater management systems. However, the understanding of their long-term capacity to retain heavy metals is limited. This study aims to investigate the ...long-term removal of heavy metals in three different porous pavements – Porous Asphalt (PA), Hydrapave (HP) and Permapave (PP) over accelerated laboratory experiments representing 26 years with varying hydrological conditions (drying/wetting periods and flow rates). A treatment model that simulates adsorption and desorption processes was developed for the first time to predict the long-term heavy metal removal by porous pavements. Unsurprisingly, all tested porous pavements performed better in removing metals that tend to attach to solid particles (e.g. Pb, Al, Fe) than more soluble ones (e.g. Cu, Zn, and Mn). There was a general increase of heavy metal concentrations at the outlet of the pavements over time as a result of a decrease in adsorption capacity of the systems, especially after the occurrence of clogging; the soluble heavy metals removal decreased with a reduction in flow rates which was speculated to be due to more time being available for desorption of metals and breakdown of accumulated sediments. The proposed model simulated the trend, fluctuations and peaks of heavy metal concentrations reasonably well, achieving the Nash-Sutcliffe coefficient (NSE) values of 0.53–0.68 during model calibration. The model was most promising in predicting Al and Cu release from porous pavements (50%–91% of the observed data within the 90% uncertainty bands, NSE = 0.44–0.74), followed by Fe and Pb (27–77% observations within the bands, NSE = 0.20–0.69). Further improvements of the model are needed for it to be applicable for Zn and Mn.
•Long term metal removal by porous pavement was studied at varying conditions.•An increasing trend of outflow concentrations from was observed except for Mn.•Clogging led to poorer system performance with higher variability.•The first process-based model was developed to predict heavy metal performance.•The model was promising in predicting Al and Cu removal, followed by Fe and Pb.
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GEOZS, IJS, IMTLJ, KILJ, KISLJ, NLZOH, NUK, OILJ, PNG, SAZU, SBCE, SBJE, UL, UM, UPCLJ, UPUK, ZRSKP
Biofilters with real time control (RTC) have great potential to remove microbes from stormwater to protect human health for uses such as swimming and harvesting. However, RTC strategies need to be ...further explored and optimised for each specific location or end-use. This paper demonstrates that the newly developed BioRTC model can fulfil this requirement and allow effective and efficient exploration of the potential of RTC applications. We describe the development of BioRTC as the first RTC model for stormwater biofilters, including: selection of a 'base' model for microbial removal prediction, its modification to include RTC capabilities, as well as calibration and validation. BioRTC adequately predicted the performance of two previously developed RTC strategies, with Nash Sutcliffe Efficiency (Ec) ranging from 0.65 to 0.80. In addition, high parameter transferability was demonstrated during model validation, where we employed the parameter sets calibrated for another biofilter study without RTC to predict the performance of RTC biofilters. We then employed the BioRTC model to explore RTC applications on a hypothetical biofilter system located at the outlet of an existing catchment. With different scenarios, we tested the impact of input parameters such as RTC set-points and design characteristics, and evaluated the influence of operational conditions on the microbial removal performance of the hypothetical biofilter with RTC. The results showed that strategy rules, set-point values, and biofilter design all govern the performance of RTC biofilters, and that operational conditions could impact the suitability of different RTC strategies. Particularly, the presence of Pareto fronts established that muti-objective optimisation is necessary to balance competing needs. These results underscore the importance of RTC, which allows for local experimentation, climate change adaptation, and adjustment to changing demands for the harvested water. Furthermore, they illustrate the practical use of the newly developed BioRTC model, enabling researchers and practitioners to explore and assess potential RTC strategies and scenarios quickly and cost-effectively.
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GEOZS, IJS, IMTLJ, KILJ, KISLJ, NLZOH, NUK, OILJ, PNG, SAZU, SBCE, SBJE, UL, UM, UPCLJ, UPUK, ZRSKP
Electrochemical oxidation (ECO) has shown good potential for disinfection of wastewater discharges but has not been tested for stormwater. Due to far lower salinity and chloride levels present in ...stormwater than in wastewaters, the knowledge so far on the ECO disinfection performance cannot simply be used for stormwater applications. This paper presents the first study on the feasibility of ECO technology for disinfection of pre-treated stormwater. Disinfection performance of E. coli was tested using a dimensional stable anode (DSA) in a series of batch experiments with synthetic stormwater of ‘typical’ chemical and microbial composition. The results showed that effective disinfection could be achieved with very low energy consumption; e.g. the current density of 1.74 mA/cm2 achieved total disinfection in 1.3 min, using only 0.018 kWh per ton of stormwater treatment. Chlorination was found to be the key disinfection mechanism, despite the synthetic stormwater containing only 9 mg/L of chloride. Real stormwater collected from three stormwater treatment systems in Melbourne was then used to validate the findings for indigenous microbe species. Disinfection below the detection limit was achieved for stormwater from the two sites where chloride levels were 9 and 200 mg/l, respectively, but not for the third site where stormwater contained only 2 mg/L chloride. Unfortunately, deterioration of the DSA anode was observed after only 8–10 h of its cumulative operation time, very likely due to high voltage that had to be applied to low saline stormwater to achieve the required current density. In conclusion, ECO was found to be a very promising low energy disinfection technology for stormwater, but far more work is needed to optimise the technology for unique stormwater conditions.
•ECO disinfection performance of pre-treated low chloride stormwater is assessed.•3 log reduction of faecal coliform was achieved under low unit energy consumption.•The dominant disinfection mechanism is chlorination.•Deterioration of tested anode was occurred due to the high operational voltage.•Further anode study should be carried to select the fit for purpose anode type.
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GEOZS, IJS, IMTLJ, KILJ, KISLJ, NLZOH, NUK, OILJ, PNG, SAZU, SBCE, SBJE, UL, UM, UPCLJ, UPUK, ZRSKP
•The first study investigating new biofilter designs with copper-zeolite.•Consistently higher E. coli removal by new designs during 8 months monitoring.•Improved E. coli removal by new designs after ...extensive drying weather.•Survival of vegetation in new designs.
Existing biofiltration systems have shown variable and often inadequate bacterial removal efficacy. Previous work has shown antimicrobial media copper-zeolite as a promising alternative to reduce the variability and excessive discharge of faecal indicator bacteria such as Escherichia coli. A large-scale biofilter column study was conducted over eight months to investigate the benefits of incorporating copper-zeolite into biofilters on E. coli removal. The incorporation of copper-zeolite into biofilters improved E. coli log removal rate by 53% reducing E. coli concentration from 21,800MPN/100mL (median inflow) to 126MPN/100mL (median outflow) comparable to international primary contact recreational water quality. In addition, the E. coli removal performance of copper-zeolite amended biofilters increased after intermittent dry weather periods; this is notable, especially considering biofilter performance usually decreases after drying. Furthermore, these designs reduced inflow copper concentration by 91% (comparable to the metal removal performance of traditional biofilters) and provided a median effluent copper concentration of 8μg/L. The vegetation in copper-zeolite filters survived. These results validate the use of copper-zeolite as bioretention media, particularly for sites requiring microbial reduction. Future research will include systematic investigation of the processes involved in reduction of bacteria in copper-zeolite filters and optimise filter design to augment the system performance to meet more stringent stormwater reuse requirements.
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GEOZS, IJS, IMTLJ, KILJ, KISLJ, NUK, OILJ, PNG, SAZU, SBCE, SBJE, UL, UM, UPCLJ, UPUK, ZRSKP
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