Reprocessing of spent nuclear fuel (SNF) is an important task in a frame of ecology and rational use of natural resources. Uranium, as the main component of SNF (>95%), can be recovered for further ...use as fresh nuclear fuel. To minimize an amount of solid radioactive waste generated during SNF reprocessing, new extractants are under investigation. Diamides of 1,10-phenanthroline-2,9-dicarboxylic acid are perspective tetradentate N-donor ligands that form strong complexes with f-elements, which are soluble in polar organic solvents. As an example of three ligands of this class, we conducted a comparative study and showed how the substituent in the amide functional group affects the extraction ability toward uranyl nitrate from nitric acid media. We have performed a careful study (NMR, FT-IR, XRD, RMC-EXAFS) of the structures of synthesized complexes of new ligands with uranyl nitrate and used quantum mechanical calculations to explain the discovered regularities through.
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IJS, KILJ, NUK, PNG, UL, UM
Gut microbiota of patients with Parkinson’s disease and healthy volunteers was analyzed by the method of high throughput 16S rRNA sequencing of bacterial genomes. In patients with Parkinson’s ...diseases, changes in the content of 9 genera and 15 species of microorganisms were revealed: reduced content of
Dorea
,
Bacteroides
,
Prevotella
,
Faecalibacterium
,
Bacteroides massiliensis
,
Stoquefichus massiliensis
,
Bacteroides coprocola
,
Blautia glucerasea
,
Dorea longicatena
,
Bacteroides dorei
,
Bacteroides plebeus
,
Prevotella copri
,
Coprococcus eutactus
, and
Ruminococcus callidus
, and increased content of
Christensenella
,
Catabacter
,
Lactobacillus
,
Oscillospira
,
Bifidobacterium
,
Christensenella minuta
,
Catabacter hongkongensis
,
Lactobacillus mucosae
,
Ruminococcus bromii
, and
Papillibacter cinnamivorans
. This microbiological pattern of gut microflora can trigger local inflammation followed by aggregation of α-synuclein and generation of Lewy bodies.
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EMUNI, FIS, FZAB, GEOZS, GIS, IJS, IMTLJ, KILJ, KISLJ, MFDPS, NLZOH, NUK, OBVAL, OILJ, PNG, SAZU, SBCE, SBJE, SBMB, SBNM, UKNU, UL, UM, UPUK, VKSCE, ZAGLJ
Abstract The paper presents the first experimental observation of an atypical phenomena during self-organization of dust particles into a one-dimensional chain structure levitated vertically in the ...plasma of a DC glow discharge. Using a laser, the third (middle) dust particle was removed from the chain of five particles so that the positions of the remaining particles did not significantly change, and a vacancy occurred in the place of the removed particle. This state of the chain turned out to be very stable, which is confirmed by the observation of the subsequent exchange of places of the fourth and the fifth particles of the chain upon the action of the laser on the forth particle. After the exchange process, vertical positions of all particles (first, second, fourth and fifth) in the chain remained almost the same as before the exchange, and the vacancy at the position of the third particle was preserved. The experimental data and the video record of the observed phenomena as well as the estimates of the plasma parameters are presented. An assumption has been made about the mechanism of the discovered phenomena that at present discharge conditions both the vacancy formation and the dust particles positions exchange are possible due to a strong ion wakes which are formed behind the upstream dust particles of the chain.
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IZUM, KILJ, NUK, PILJ, PNG, SAZU, UL, UM, UPUK
The origin and nature of extreme energy cosmic rays (EECRs), which have energies above the
5
⋅
10
19
eV
—the Greisen-Zatsepin-Kuzmin (GZK) energy limit, is one of the most interesting and complicated ...problems in modern cosmic-ray physics. Existing ground-based detectors have helped to obtain remarkable results in studying cosmic rays before and after the GZK limit, but have also produced some contradictions in our understanding of cosmic ray mass composition. Moreover, each of these detectors covers only a part of the celestial sphere, which poses problems for studying the arrival directions of EECRs and identifying their sources. As a new generation of EECR space detectors, TUS (Tracking Ultraviolet Set-up), KLYPVE and JEM-EUSO, are intended to study the most energetic cosmic-ray particles, providing larger, uniform exposures of the entire celestial sphere. The TUS detector, launched on board the Lomonosov satellite on April 28, 2016 from Vostochny Cosmodrome in Russia, is the first of these. It employs a single-mirror optical system and a photomultiplier tube matrix as a photo-detector and will test the fluorescent method of measuring EECRs from space. Utilizing the Earth’s atmosphere as a huge calorimeter, it is expected to detect EECRs with energies above
10
20
eV
.
It will also be able to register slower atmospheric transient events: atmospheric fluorescence in electrical discharges of various types including precipitating electrons escaping the magnetosphere and from the radiation of meteors passing through the atmosphere. We describe the design of the TUS detector and present results of different ground-based tests and simulations.
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DOBA, EMUNI, FIS, FZAB, GEOZS, GIS, IJS, IMTLJ, IZUM, KILJ, KISLJ, MFDPS, NLZOH, NUK, OBVAL, OILJ, PILJ, PNG, SAZU, SBCE, SBJE, SBMB, SBNM, UILJ, UKNU, UL, UM, UPUK, VKSCE, ZAGLJ
We trace what happens with asymptotically free behavior of the running coupling in φ3 theory in six-dimensional spacetime, if to compactify two spatial dimensions on a 2D closed manifold. The result ...can be considered as an effective 4D theory of infinitely many KK-type scalar fields with triple interactions. The effective dimensional coupling constant inherits running to zero at high mass scales in a modified form depending on the size of the compact manifold. Some physical implications are discussed.
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CMK, CTK, FMFMET, IJS, NUK, PNG, UM
Abstract
The work presents the results of the energy confinement study carried out on the compact spherical tokamak Globus-M2 with a toroidal magnetic field as high as 0.8 T. A reproducible and ...stable discharge was obtained with the average plasma density (5–10) × 10
19
m
−3
. Despite the increase in the magnetic field, the neutral beam injection (NBI) led to clear and reproducible transition to the H-mode accompanied by a decrease in the turbulence level at the plasma edge. NBI allowed effectively heat the plasma: electron and ion temperatures in the plasma core exceeded 1 keV. Compared to the previous experiments carried out with a toroidal magnetic field as high as 0.4 T plasma total stored energy was increased by a factor of 4. The main reason or this phenomenon is a strong dependence of the energy confinement time on the toroidal magnetic field in the spherical tokamak. It was experimentally confirmed that such kind of dependence is valid for ST with magnetic field up to 0.8 T. It has also been shown that the enhancement of the energy confinement in Globus-M2 with collisionality decrease is associated with an improvement of both electron and ion thermal insulation.
ABSTRACT
We have analysed the differences in positions of 9081 matched sources between the Gaia Data Release 2 (DR2) and very long baseline interferometry (VLBI) catalogues. The median position ...uncertainty of matched sources in the VLBI catalogue is a factor of two larger than the median position uncertainty in Gaia DR2. There are 9 per cent matched sources with statistically significant offsets between both catalogues. We found that the reported positional errors should be rescaled by a factor of 1.3 for VLBI and 1.06 for Gaia and, in addition, the Gaia errors should be multiplied by the square root of chi squared per degree of freedom in order to best fit the normalized position differences to the Rayleigh distribution. We have established that the major contributor to statistically significant position offsets is the presence of optical jets. Among the sources for which the jet direction was determined, the position offsets are parallel to the jet directions for 62 per cent of the outliers. Among the matched sources with significant proper motion, the fraction of objects with proper motion directions parallel to jets is a factor of three greater than on average. Such sources have systematically higher chi squared per degree of freedom. We explain these proper motions as a manifestation of the source position jitter caused by flares, which we predicted earlier. Therefore, the assumption that quasars are fixed points, and thus that differential proper motions determined with respect to quasar photocentres can be regarded as absolute proper motions, should be treated with great caution.
Abstract
A time-dependent model of laser amplification in an Yb : YAG crystal is considered based on a system of balance equations, as well as radiation transfer and heat conduction equations. The ...model also takes into account the dependence of the laser characteristics of the gain medium on the injection wavelength and the effect of amplified spontaneous emission. This model is verified based on a diode-pumped amplifier with cryogenic cooling of active elements. The dependences of the gain on the pump pulse energy are experimentally measured for different amplification regimes and compared with simulation results.
In this work we report on new examples of phenanthrolindiamides containing asymmetric centers in amide substituents. The synthesized ligands are expected to have complex thermodynamic behavior. Their ...structure was unambiguously confirmed by a combination of spectral analysis methods and X-ray analysis. It is shown that the obtained ligands form complexes with nitrates of rare-earth elements, and the stability constants of such complexes in acetonitrile solution were also measured. The performed solvent extraction tests revealed a significant effect of methyl groups in cyclic amide substituents on the distribution ratios and selectivity factors in the lanthanides(
iii
) and Am(
iii
) series in comparison with the previously studied ligands based on unsubstituted pyrrolidine. The observed effects are explained from the standpoint of quantum chemistry calculations taking into account possible stereoisomerism.
In this work we report on new examples of phenanthrolindiamides containing asymmetric centers in amide substituents.
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