The merger of photoredox catalysis with transition metal catalysis, termed metallaphotoredox catalysis, has become a mainstay in synthetic methodology over the past decade. Metallaphotoredox ...catalysis has combined the unparalleled capacity of transition metal catalysis for bond formation with the broad utility of photoinduced electron- and energy-transfer processes. Photocatalytic substrate activation has allowed the engagement of simple starting materials in metal-mediated bond-forming processes. Moreover, electron or energy transfer directly with key organometallic intermediates has provided novel activation modes entirely complementary to traditional catalytic platforms. This Review details and contextualizes the advancements in molecule construction brought forth by metallaphotocatalysis.
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IJS, KILJ, NUK, PNG, UL, UM
Although the processes by which glacial debris mantles alter the melting of glacier ice have been well studied, the mass balance and runoff patterns of Himalayan debris-covered glaciers and the ...response of these factors to climate change are not well understood. Many previous studies have addressed mechanisms of ice melt under debris mantles by applying multiplicative parameters derived from field experiments, and other studies have calculated the details of heat conduction through the debris layer. However, those approaches cannot be applied at catchment scale because distributions of thickness and thermal property of debris are heterogeneous and difficult to measure. Here, we established a runoff model for a Himalayan debris-covered glacier in which the spatial distribution of the thermal properties of the debris mantle is estimated from remotely sensed multi-temporal data. We applied the model to the Tsho Rolpa Glacial Lake-Trambau Glacier basin in the Nepal Himalaya, using hydro-meteorological observations obtained for a 3.5-year period (1993-1996). We calculated long-term averages of runoff components for the period 1980-2007 using gridded reanalysis datasets. Our calculations suggest that excess meltwater, which implies the additional water runoff compared with the ice-free terrain, from the debris-covered area contributes significantly to the total runoff, mainly because of its location at a lower elevation. Uncertainties in runoff simulation due to estimations of the thermal properties and albedo of the debris-covered surface were assessed to be approximately 8% of the runoff from the debris-covered area. We evaluated the sensitivities of runoff components to changes in air temperature and precipitation. As expected, warmer air temperatures increase the total runoff by increasing the melting rate; however, increased precipitation slightly reduces the total runoff, as ice melting is suppressed by the increased snow cover and associated high albedo. The response of total runoff to changing precipitation is complex because of the different responses of individual components (glacier, debris, and ice-free terrain) to precipitation.
In the heavy-fermion metal CePdAl, long-range antiferromagnetic order coexists with geometric frustration of one-third of the Ce moments. At low temperatures, the Kondo effect tends to screen the ...frustrated moments. We use magnetic fields B to suppress the Kondo screening and study the magnetic phase diagram and the evolution of the entropy with B employing thermodynamic probes. We estimate the frustration by introducing a definition of the frustration parameter based on the enhanced entropy, a fundamental feature of frustrated systems. In the field range where the Kondo screening is suppressed, the liberated moments tend to maximize the magnetic entropy and strongly enhance the frustration. Based on our experiments, this field range may be a promising candidate to search for a quantum spin liquid.
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CMK, CTK, FMFMET, IJS, NUK, PNG, UM
We present a new glacier inventory for high-mountain Asia named "Glacier Area Mapping for Discharge from the Asian Mountains" (GAMDAM). Glacier outlines were delineated manually using 356 Landsat ...ETM+ scenes in 226 path-row sets from the period 1999–2003, in conjunction with a digital elevation model (DEM) and high-resolution Google EarthTM imagery. Geolocations are largely consistent between the Landsat imagery and DEM due to systematic radiometric and geometric corrections made by the United States Geological Survey. We performed repeated delineation tests and peer review of glacier outlines in order to maintain the consistency and quality of the inventory. Our GAMDAM glacier inventory (GGI) includes 87 084 glaciers covering a total area of 91 263 ± 13 689 km2 throughout high-mountain Asia. In the Hindu Kush–Himalaya range, the total glacier area in our inventory is 93% that of the ICIMOD (International Centre for Integrated Mountain Development) inventory. Discrepancies between the two regional data sets are due mainly to the effects of glacier shading. In contrast, our inventory represents significantly less surface area (−24%) than the recent global Randolph Glacier Inventory, version 4.0 (RGI), which includes 119 863 ± 9201 km2 for the entirety of high Asian mountains. Likely causes of this disparity include headwall definition, effects of exclusion of shaded glacier areas, glacier recession since the 1970s, and inclusion of seasonal snow cover in the source data of the RGI, although it is difficult to evaluate such effects quantitatively. Further rigorous peer review of GGI will both improve the quality of glacier inventory in high-mountain Asia and provide new opportunities to study Asian glaciers.
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IZUM, KILJ, NUK, PILJ, PNG, SAZU, UL, UM, UPUK
Among meteorological elements, precipitation has a large spatial variability and less observation, particularly in high-mountain Asia, although precipitation in mountains is an important parameter ...for hydrological circulation. We estimated precipitation contributing to glacier mass at the median elevation of glaciers, which is presumed to be at equilibrium-line altitude (ELA) such that mass balance is zero at that elevation, by tuning adjustment parameters of precipitation. We also made comparisons between the median elevation of glaciers, including the effect of drifting snow and avalanche, and eliminated those local effects. Then, we could obtain the median elevation of glaciers depending only on climate to estimate glacier surface precipitation. The calculated precipitation contributing to glacier mass can elucidate that glaciers in arid high-mountain Asia receive less precipitation, while much precipitation makes a greater contribution to glacier mass in the Hindu Kush, the Himalayas, and the Hengduan Shan due to not only direct precipitation amount but also avalanche nourishment. We classified glaciers in high-mountain Asia into summer-accumulation type and winter-accumulation type using the summer-accumulation ratio and confirmed that summer-accumulation-type glaciers have a higher sensitivity than winter-accumulation-type glaciers.
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IZUM, KILJ, NUK, PILJ, PNG, SAZU, UL, UM, UPUK
The Gorkha earthquake (Magnitude 7.8) on 25 April 2015 and later aftershocks struck South Asia, killing approx.9,000 and damaging a large region. Supported by a large campaign of responsive satellite ...data acquisitions over the earthquake disaster zone, our team undertook a satellite image survey of the earthquakes induced geohazards in Nepal and China and an assessment of the geomorphic, tectonic, and lithologic controls on quake-induced landslides. Timely analysis and communication aided response and recovery and informed decision makers. We mapped 4,312 co-seismic and post-seismic landslides. We also surveyed 491 glacier lakes for earthquake damage, but found only 9 landslide-impacted lakes and no visible satellite evidence of outbursts. Landslide densities correlate with slope, peak ground acceleration, surface downdrop, and specific metamorphic lithologies and large plutonic intrusions.
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BFBNIB, NMLJ, NUK, ODKLJ, PNG, SAZU, UL, UM, UPUK
To understand the formation conditions of debris-covered glaciers, we examined the dimension and shape of debris-covered areas and potential debris-supply (PDS) slopes of 213 glaciers in the Bhutan ...Himalaya. This was undertaken using satellite images with 2.5 m spatial resolution for manual delineation of debris-covered areas and PDS slopes. The most significant correlation exists between surface area of southwest-facing PDS slopes and debris-covered area. This result suggests that the southwest-facing PDS slopes supply the largest quantity of debris mantle. The shape of debris-covered areas is also an important variable, quantitatively defined using a geometric index. Elongate or stripe-like debris-covered areas on north-flowing glaciers are common throughout the Bhutan Himalaya. In contrast, south-flowing glaciers have large ablation zones, entirely covered by debris. Our findings suggest that this difference is caused by effective diurnal freeze-thaw cycles rather than seasonal freeze-thaw cycles, permafrost degradation, or snow avalanches. In terms of geographic setting, local topography also contributes to glacier debris supply and the proportion of debris cover on the studied glaciers is suppressed by the arid Tibetan climate, whereas the north-to-south asymmetric topography of the Bhutan Himalaya has less influence on the proportion of debris cover.
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IZUM, KILJ, NUK, PILJ, PNG, SAZU, UL, UM, UPUK
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