Monitoring of various naturally present substances or physical properties of the water, commonly called environmental tracers, can provide valuable insight in characteristics of groundwater flow ...systems and intrinsic processes. Analysis of individual tracer data most often gives an ambiguous interpretation, but employment of multiple diverse tracers can greatly increase interpretation reliability. We monitored multiple natural tracers including spring water electrical conductivity, temperature, loads of major anions and cations, stable isotopes of water, and total organic carbon together with discharge dynamics on Krbavica springs located in the Croatian part of Dinaric Karst region. We also monitored dissolved oxygen concentration as an indicator of “excess air” dynamics in the spring water, which is a very rarely recognized and not properly understood phenomenon in the karst groundwater studies. Analysis of the monitoring data revealed main characteristics of the karst system, among which following can be emphasized: (1) oxygen concentration together with conductivity and temperature (parameters monitored with high temporal resolution) were strongly related to discharge dynamics, while seasonal patterns were absent; (2) supersaturation with oxygen confirmed presence of “excess air”, most pronounced in high water conditions following the hydrograph peaks, indicating prevalence of closed flow conditions within the system; (3) electrical conductivity showed “anomalous” gradual decrease during the hydrograph recessions, attributed both to CO2 dynamics and mobilization of water from tiny fissures during high recharge conditions; and (4) stable isotope measurements confirmed good mixing of water within the system with mean residence time of a few years. Simultaneous monitoring of diverse tracer dynamics enabled detailed characterization of the karst system without excessive ambiguity.
Crystalline rocks are generally characterized by negligible porosity and permeability in terms of groundwater exploitability. However, alteration processes can greatly increase their fracture ...permeability and induce formation of modest, but locally important aquifers. Therefore, subsurface characteristics of alteration zones are of major importance for hydrogeological evaluation of crystalline terrains. Alteration processes greatly affect rock total porosity and water content, causing contrasting electrical resistivity of rocks affected by varying degrees of weathering. This makes electrical resistivity tomography (ERT) a preferable geophysical method for the exploration of alteration zones in crystalline rocks. In our research, we used an integrated approach, combining the ERT method with monitoring of spring discharge and hydrochemistry to characterize metamorphic aquifers on slopes of the Medvednica Mountain (Croatia). Significant fracture flow aquifers are found to be formed in intensely fractured but not highly weathered rock masses (medium to high resistivity values), while highly weathered masses (low resistivity values) form local barriers for fracture flows. Subsurface structure of the alteration zone proved to be highly irregular, with sharp contacts between more and less weathered rocks. Decrease of permeability below the alteration zone keeps the water level near the surface and enables spring occurrence on the mountain slopes. Studied aquifers have relatively limited extent, resulting in typical capacity of major springs of a few l/s. More frequent but less productive springs are attributed to the draining of the shallow part of the alteration zone (mostly saprolite). Combination of the ERT method with spring monitoring proved to be very effective as a first and relatively inexpensive methodology for hydrogeological characterization of crystalline terrains, both in local and catchment scales.
Full text
Available for:
IZUM, KILJ, NUK, PILJ, PNG, SAZU, UL, UM, UPUK
Tracer testing is the only method in karst hydrogeology that can definitively determine whether a particular site belongs to a watershed of a particular karst spring. Therefore, it is an essential ...technique for delineating groundwater basins in karst areas. The availability of tracer test results is often limited due to the complicated and relatively expensive application of this approach, especially for large regional watersheds. The Croatian part of the Dinaric karst region extends for several hundred kilometers along the Adriatic coast and consists almost entirely of highly karstified carbonate rocks. The groundwater basins in these areas almost never match the surface morphology of the terrain. In practice, all available results of previous surveys are often used to define watersheds, regardless of the methodology and age of their implementation. This is also true for the earlier delineations of the Gacka River watershed, a regional karst basin in the Croatian Dinaric karst. However, tracer testing methods, especially the accuracy of tracer determination and monitoring, have improved significantly during this time. In order to assess the reliability of past tracing results in this significant karst basin, we reviewed reports of previous tracer tests. More recent tests, in particular the most recent multitracer injection test with continuous tracer detection on the major springs, produced high-quality data that allowed us to assess the reliability of the findings from prior research. A number of large karst springs with partially overlapping subcatchments feed the Gacka River. After discarding unreliable tracing data, we reevaluated the subcatchments of the main springs as well as the characteristics of the regional groundwater flow patterns throughout the basin, which is particularly important for water quality protection measures of the springs. The Gacka River basin is used as a case study to emphasize the importance of thoroughly assessing the reliability of previous tracing data before using them in regional analyses.
Extreme heterogeneity of karst systems makes them very challenging to study. Various processes within the system affect its global response, usually measured at karst springs. Research conducted in ...caves provides a unique opportunity for in situ analysis of separate processes in karst underground. The aim of the present study was to research the water and air dynamics within a deep karst system. Air and water basic physical parameters across the Lukina jama–Trojama cave system (−1,431 m) were continuously monitored during a 1‐year period. Recorded hydrograph of the siphon lake at the bottom of the cave was used to interpret the characteristics of an unexplored phreatic/epiphreatic conduit network. Water origin in the siphon was determined based on temperature and electrical conductivity. Air temperature and humidity monitoring revealed a strong inflow of air of sub‐zero temperature into the upper portion of the cave during winter. Cave passage morphology was interpreted as the main determinant of air dynamics, which caused ice to accumulate extensively in the upper portions of the cave and caused the temperature on the top of the homothermic zone to be significantly below the mean outside temperature. Air dynamics also lowered the temperature of water flowing through the cave vadose zone and feeding the phreatic zone of the massif. The pronounced temperature difference between the phreatic zone and the top of the homothermic zone probably contributed to the thermal gradient observed in the cave, which is steeper than in ice‐free caves in the area. Our results enabled the development of a conceptual model that describes coupling between air and water dynamics in the cave system and its surroundings.
Full text
Available for:
BFBNIB, FZAB, GIS, IJS, KILJ, NLZOH, NUK, OILJ, SAZU, SBCE, SBMB, UL, UM, UPUK
Spring hydrographs and thermographs are a direct reflection of all processes that occur within aquifer systems. Therefore, they contain significant information about the hydrogeological ...characteristics of such systems. This article analyses hydrographs and thermographs from four springs located in the foothills of the Mt. Biokovo massif in southern Croatia. These springs are recharged by carbonate aquifers. Monitoring of yields and groundwater temperatures, as well as analysing hydrograph recessions, daily discharge and rainfall time series and water temperature dynamics, facilitated the identification of the main properties of the aquifer system located in the hinterland of the individual springs. Significant differences in the recharge mechanisms of individual springs were determined to be a consequence of varying geological conditions, degree of karstification and conduit network characteristics. The results suggest that the Cretaceous and Palaeogene basinal carbonate deposits (Kotisina limestones and breccias), the hydrogeology of which has not yet been studied, have the characteristics of permeable karstic rocks.
Full text
Available for:
IZUM, KILJ, NUK, ODKLJ, PILJ, PNG, SAZU, UL, UM, UPUK
Detailed field examination, U-Th age dating, and stable isotope analysis of Veternica flowstone and shelfstone deposits have been employed in order to unravel details about the geological history of ...Veternica Cave (Medvednica Mountain, Croatia). The study was carried out in the hydrologically inactive part of the main cave channel, which is developed mainly along the unconformity between Triassic dolostone and Miocene limestone. For 180 m from the cave entrance, (located at 320 metres above sea level (asl)), the morphology of the main channel reflects exclusively phreatic conditions in the cave until the end of its hydrological activity. From 180 to 390 m, the phreatic channel has a secondary vadose entrenchment in the bottom part as marked by massive flowstones at elevations from 306 to 313.5 m asl. From 390 m farther inside the cave (in the upstream direction), the main channel has a tall, narrow cross-section and is of mainly vadose origin. In this part of the cave shelfstone precipitates are observed at 9 different levels ranging from 318.8 to 320.2 m asl, indicating the water palaeolevels in the cave. U-Th dating revealed the age of the highest shelfstone (320.2 m asl) of ~380 kyrs BP, and the age of the lowermost analyzed shelfstone (318.9 m asl) of ~245 kyrs BP. Dating of flowstone deposits, located below the shelfstone level, revealed their formation from ~235 to 205 kyrs BP. A relatively rapid water table lowering and transition from phreatic to vadose conditions occurred within the cave, from ~245 to 235 ka BP, between formation of the youngest shelfstone (representing phreatic conditions below their level) and the oldest flowstone (marking the beginning of vadose conditions). The results provide unique new information about Veternica Cave genesis and geomorphologic evolution of the Medvednica Mountain area.
Full text
Available for:
IZUM, KILJ, NUK, ODKLJ, PILJ, PNG, SAZU, UL, UM, UPUK
Display omitted
•First regional investigation of EOCs in Dinaric karst aquifers.•65 different EOCs detected, conc. <1 ng/L for almost half.•EOC concentrations are two orders of magnitude lower than ...in other groundwater types.•EOCs are detected more frequently than in other types of groundwater.•EOCs are detected in greater or comparable numbers than in other groundwater types.
Emerging organic contaminants (EOCs) have become of increasing interest due to concerns about their impact on humans and the wider environment. Karst aquifers are globally widespread, providing critical water supplies and sustaining rivers and ecosystems, and are particularly susceptible to pollution. However, EOC distributions in karst remain quite poorly understood. This study looks at the occurrence of EOCs in the Croatian karst, which is an example of the “classical” karst, a highly developed type of karst that occurs throughout the Dinaric region of Europe. Samples were collected from 17 karst springs and one karst lake used for water supply in Croatia during two sampling campaigns. From a screen of 740 compounds, a total of 65 compounds were detected. EOC compounds from the pharmaceutical (n = 26) and agrochemical groups (n = 26) were the most frequently detected, while industrials and artificial sweeteners had the highest concentrations (range 8–440 ng/L). The number of detected compounds and the frequency of detection demonstrate the vulnerability of karst to EOC pollution. Concentrations of 5 compounds (acesulfame, sucralose, perfluorobutane sulfonate, emamectin B1b, and triphenyl phosphate) exceeded EU standards and occurred at concentrations that are likely to be harmful to ecosystems. Overall, most detections were at low concentrations (50 % <1 ng/L). This may be due to high dilution within the exceptionally large springs of the Classical karst, or due to relatively few pollution sources within the catchments. Nevertheless, EOC fluxes are considerable (10 to 106 ng/s) due to the high discharge of the springs. Temporal differences were observed, but without a clear pattern, reflecting the highly variable nature of karst springs that occurs over both seasonal and short-term timescales. This research is one of a handful of regional EOC investigations in karst groundwater, and the first regional study in the Dinaric karst. It demonstrates the need for more frequent and extensive sampling of EOCs in karst to protect human health and the environment.
Full text
Available for:
GEOZS, IJS, IMTLJ, KILJ, KISLJ, NLZOH, NUK, OILJ, PNG, SAZU, SBCE, SBJE, UILJ, UL, UM, UPUK, ZAGLJ, ZRSKP
Researching the hydrogeological properties of karst systems is very challenging due to their extreme heterogeneity. A grey-box approach in karst research combines the results from classical ...hydrogeological methods with direct observations within the karstic underground, i.e. in the caves. Isotope research has become a widely used method in the investigation of karst systems. The results presented are of a preliminary 2H and 18O stable isotope study of the Northern Velebit karst system (Croatia) employing the grey-box approach. Groundwater samples were collected during two summer expeditions in deep caves within the karst massif. Monthly precipitation samples were also collected (at three locations between approx. 900 m and 1600 m altitude), as well as water samples at some of the most significant springs, i.e. discharge outlets of the system. For a single expedition, the stable isotope composition is almost constant, i.e. the stable isotope measurements are within the measurement error across the complete cave profile. Similar characteristics across different caves during the same year were also noted. Samples of water from the springs were taken during base-flow conditions and they have similar isotopic contents to the cave water. The results obtained indicate that homogenization of the water already occurs within the subsurface epikarst zone above the sampling locations in the caves, but a future extended sampling campaign during variable hydrologic conditions is needed to confirm this. The final research goal is to establish a conceptual grey-box model for the functioning of this complex hydrogeological system.
Full text
Available for:
IZUM, KILJ, NUK, ODKLJ, PILJ, PNG, SAZU, UL, UM, UPUK
PDF
