The initial melting quality of a high-speed laser cladding layer has an important impact on its post-treatment and practical application. In this study, based on the repair of hydraulic support ...columns of coal mining machines, the influence of high-speed laser cladding process parameters on the quality of Fe-Cr-Ni alloy coatings was investigated to realize the accurate prediction of coating quality. The Taguchi orthogonal method was used to design the L
(5
) test. The prediction models of the relationship between the cladding process and the coating quality were established using the Random Forest (RF) and AdaBoost (Adaptive Boosting, AB) algorithms, respectively. Then, the prediction accuracy of the two models was compared, and the process parameter features were screened for importance evaluation. The results show that the AB prediction model is more accurate than the RF prediction model and more sensitive to abnormal data. The importance evaluation based on the AdaBoost model shows that the scanning speed has a great influence on the height and surface roughness of the coating. On the other hand, the overlap rate is the most important factor in controlling the dilution ratio and near-surface grain size of high-speed laser melting coatings. In addition, the micro-hardness of the coating and the thermal effect of the substrate can be effectively enhanced by adjusting the laser power and scanning speed. Finally, it was verified that the AB prediction model could accurately estimate the quality indexes of the coating with a prediction error less than 6%. The results show that it is feasible to predict the quality of high-speed laser cladding with the AB algorithm. It provides a basis for the adjustment of process parameters in the subsequent quality control process of cladding.
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IZUM, KILJ, NUK, PILJ, PNG, SAZU, UL, UM, UPUK
Nano ZrO2-8% Y2O3 (molar fraction) (8YSZ) powder was doped with 20% (mass fraction) micron CeO2 powder, and the CeO2-8YSZ (CYSZ) composite agglomerated powder was synthesized by spray drying. ...Scanning electron microscope (SEM) and energy dispersive spectrometer (EDS) were used to investigate the effect of carboxymethyl cellulose (CMC) mass fraction on the properties of composite agglomerate powders. CYSZ thermal barrier coatings with columnar structure were prepared by PS-PVD The cross-section and surface of the coating were analyzed by EDS. The phase of the coating was analyzed by X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS). The results showed that when the mass fraction of the binder reached 2%, a high degree of sphericity could be obtained. , agglomerated powder with uniform particle size distribution; Ce elements in the prepared coating are uniformly distributed; the coating phase is basically a t-phase structure, in which Ce4+ replaces Zr4+ into the ZrO2 lattice to form a homogeneo
In this paper, a laser-based directed energy deposition (DED) technique is used to fabricate FeCoNiCr and CrMnFeCoNi multi-principal-element alloys (MPEAs). Comparing the above samples, the FeCoNiCr ...samples with coarse columnar grains cracked, while the CrMnFeCoNi samples with equiaxed grain were crack-free. The strategy that removes cracks is to induce a columnar-grain-to-equiaxed-grain transition (CET) with Mn addition to offer more grain boundaries to withstand residual stress in the process of DED-fabricated FeCoNiCr and to help minimize hot cracking. Furthermore, the yield strength, tensile strength, and tensile ductility of the DED-fabricated CrMnFeCoNi obviously improved compared with the DED-fabricated CoCrFeNi and exhibited better isotropic mechanical properties. The present work provides a novel strategy to utilize CET for resisting crack propagation in the process DED-fabricated MPEAs and improvement in mechanical properties of MPEAs.
Shear fatigue damage to the waterproof cohesive layer has not received enough attention in bridge deck pavement design. Meanwhile, there is less theoretical basis for the design of a waterproof ...cohesive layer. In this study, direct shear and shear fatigue tests were used to compare the shear strength and fatigue performance of waterproof adhesive materials under different disposal schemes for a cement slab surface, bonding materials, and spreading schemes, and the recommended optimal dosage of waterproof adhesive material for the bridge deck is given. Based on the shear fatigue tests results of indoor waterproof adhesive materials, an equation for prediction fatigue at 15 °C was established and temperature correction was applied. Based on these results, we propose a waterproof cohesive layer design method for bridge deck pavement with interlayer shear damage as the design index. The life expectancy of the shear damage between the decks was calculated for a real bridge deck. These results provide scientific guidance for design of a waterproof cohesive layer in a bridge deck, which can effectively extend the service life of a bridge deck.
•La2O3 improved the temperature gradient and reduces crack susceptibility.•La2O3 promoted nucleation and grain refinement and increases dislocation density.•La2O3 doping increased the hardness of the ...coating and improved the wear pattern.
In this study, CoCrFeNiMoSi and CoCrFeNiMoSi + 0.5 % La2O3 High entropy alloy (HEA) coatings were prepared by laser cladding. The microstructure was consisted mainly of body-centered cubic structure, face-centered cubic structure and intermetallic compounds of Si. The addition of rare earth La2O3 resulted in the refinement and uniformity of the CoCrFeNiMoSi + 0.5 % La2O3 HEA coating grains, leading to an increase in microhardness from 430 HV to 520 HV. Additionally, the friction coefficient decreased by 0.15 and the wear rate decreased by 2/3. These findings indicate that the appropriate addition of La2O3 has significant potential in enhancing the friction and wear performance of HEA coatings.
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GEOZS, IJS, IMTLJ, KILJ, KISLJ, NLZOH, NUK, OILJ, PNG, SAZU, SBCE, SBJE, UILJ, UL, UM, UPCLJ, UPUK, ZAGLJ, ZRSKP
To further strengthen the AlCoCrFeNi high-entropy alloy (HEA) coating prepared by high-speed laser cladding (HLC), laser remelting (LR) was chosen to reprocess it. The effects of LR on the ...topography, microstructure, growth orientation, phase distribution, and properties were investigated. It was revealed that there were a large number of liquid phase separation (LPS) zones in the HLC coating because of an ultrafast cooling rate. After LR, the LPS zones were eliminated. Compared to HLC coating, the microhardness increased from 622 HV to 762 HV, and the friction coefficient and the wear weight loss were reduced by 0.1 and 0.5 mg, respectively. In electrochemical testing, the self-corrosion potential increased by 45.9 mV and the self-corrosion current density decreased by one order of magnitude. Meanwhile, EBSD analysis indicated that the LPS zones were prone to recrystallization. The LPS zones were nickel-poor, low hardness, also BCC phase, and had a clearer (101) orientation. With the elimination of the LPS zones, the kernel average misorientation values were reduced, Taylor factor values and high angle grain boundaries were increased, and the average grain size was reduced from 2.43 μm to 2.12 μm. Eventually, for LR coatings, the combination of fine grain strengthening, solid solution strengthening, spalling reduction, and Cr element segregation resulted in better wear and corrosion resistances. The overall results show that a reasonable LR application can induce the microstructure of the HLC coating and improve its service properties.
● The AlCoCrFeNi high-entropy alloy coatings were prepared by high-speed laser cladding (HLC) and reprocessed by laser remelting (LR).● There were a large number of liquid phase separation (LPS) zones in the HLC coating. After LR, the LPS zones were replaced by fine equiaxed crystals.● The LPS zones were nickel-poor and low hardness, had a clearer (101) orientation, and tended to spall off in the wear test, causing a decrease in the overall wear resistance of the coating.● As a result of the elimination of the LPS zones, the microhardness and wear resistance of the LR coating were improved by solid solution strengthening and fine grain strengthening.● Appropriate undercooling and more high angle grain boundaries caused by LR provided a larger driving force for grain boundary segregation. The elemental content of Cr at the grain boundaries became higher, and the corrosion resistance of the LR coatings increased significantly. Display omitted
•HLC led to a large number of the LPS zones in the AlCoCrFeNi HEA coating.•LR could successfully eliminate the LPS zones.•Recrystallization made the grains of the LPS zones coarse and soft.•The microhardness and wear resistance of the coating were improved by LR.•Higher Cr content at grain boundaries boosted corrosion resistance of LR coating.
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GEOZS, IJS, IMTLJ, KILJ, KISLJ, NLZOH, NUK, OILJ, PNG, SAZU, SBCE, SBJE, UILJ, UL, UM, UPCLJ, UPUK, ZAGLJ, ZRSKP
The negative effects of thermal cycles in the process of additive manufacture present a challenge for the control of microstructure so as to fabricate the products with improved properties compared ...with conventional casting technique. In this work, AlCoCrFeNi2.1 eutectic high-entropy alloy (EHEA) was prepared by laser metal deposition (LMD). Compared with conventionally cast EHEA samples, the LMD-fabricated EHEA samples showed significantly enhanced tensile strength (by 19.7%) and increased tensile ductility (by 56.4%). Such enhancement in tensile properties was attributed to the refinement of the uniformly distributed eutectic-structure, which improved the strain hardening/dislocation accumulation capability of the EHEA. The present work provides a new strategy to utilize both the high cooling rates of LMD and the eutectic-structure characteristics for forming refined homogeneous structures and thus achieving superior mechanical properties to those prepared by traditional processing techniques.
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To strengthen face-centered cubic structured high entropy alloys, this paper explores a new method of ceramic reinforced CoCrFeNiMo0.2 high entropy alloy composite gradient coating. In this study, ...four sets of gradients were created by first preparing a pristine alloy coating without silicon carbide content on the substrate, followed by preparing composite coatings with varying silicon carbide mass fractions (8 %, 16 %, 24 %) on the pristine coatings. The coatings were then analyzed for their phase composition, microstructure, microstructure evolution process, and friction wear properties. The study reveals that the microstructure of the initial alloy coating consists of a single-phase face-centered cubic solid solution. It is observed that intragranular segregation occurs in the coating, resulting in the boundary enrichment of Mo and Cr elements. As the silicon carbide addition increases, the segregation behavior becomes more pronounced, and the generation of body-centered cubic phase is observed. The second, third, and fourth layers exhibit significantly higher average hardness, measuring at 594 HV, 722 HV, and 788 HV respectively. This can be attributed to the presence of body-centered cubic structure, carbide, and grain boundary strengthening effects. On average, the hardness of these layers is three to four times higher than that of the first layer. With an increase in the number of layers, the wear mechanism changes from adhesive wear to abrasive wear. The wear rates of the second, third, and fourth layers were all reduced by at least 87 % compared to the first layer. However, there were different forms of abrasive wear observed between these layers. The findings of this study have significant engineering implications.
•The microstructural evolution of columnar grains to equiaxed dendrites was studied.•The high-density of dislocations enhances the diffusion of Mo and Cr elements.•The tissue shows phase separation act containing the BCC structure.•The shift behavior of the wear mechanism of the gradient structure was studied.
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Solid-solution agglomerated ZrO2-based powders co-doped with Gd2O3, Yb2O3 and Y2O3 rare earth oxides were synthesized by solid-phase sintering and spray drying. The corresponding GYYZO coating was ...prepared by using atmospheric plasma spraying, while the 8YSZ coating was also prepared as a control group for the high temperature performance investigation. The high temperature structure and phase stability as well as the sintering resistance of both coatings were investigated by SEM, XRD, DSC, EPMA and TEM observations. The results showed that the 8YSZ coating began to undergo a phase transition of tetragonal (t) phase to monoclinic (m) after 50 h heat treatment at 1400 °C, while the GYYZO coating remained free of phase transition even heat-treated for up to 200 h, demonstrating a better phase stability. In addition, as an indicator of sintering resistance of the coating, the porosity of the 8YSZ coating decreased up to 90.1 % after 200 h heat treatment, while that of the GYYZO coating decreased only 20.6 %. The superior high temperature performance of GYYZO coating can be explained by the pinning effect of nano-pores on grain boundaries. The formation of nano-pores was associated with the evolution of defect clusters in the coating, which were facilitated by the substitution defects and oxygen vacancies created by the GdYb co-doping. During the heating process, these clusters migrated along with the grain boundaries and formed pearl-string-like nano-pores at the grain boundaries. The eventual formation of nanopores not only further inhibits grain boundary migration to reduce sintering, but also prevents the segregation of Y elements to hinder t-phase to m-phase transition.
•GYYZO coating has excellent phase stability and sintering resistance at high temperature.•The nanopores of GYYZO coating have pinning effect on grain boundaries.•The pinning effect of nanopores can inhibit grain boundaries migration and Y elements segregation.
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