Lightweight intermetallic γ-TiAl based alloys are innovative high-temperature structural materials. So far, these alloys are in use as turbine blades or turbocharger turbine wheels in advanced ...aerospace and automotive engines, where they are produced by means of investment casting as well as wrought processing, e.g. hot-forging. Through the development of powder-based additive manufacturing processes within the last decade, a real paradigm shift for future component production as well as their design and materials properties was created. While so-called proven alloy systems are presently used worldwide for additive manufacturing, the approach of this work is the development of novel process-adapted γ-TiAl based alloys, which on the one hand fulfill the specific requirements of additive manufacturing and on the other hand provide excellent high temperature properties after a suitable heat treatment. Based on the concept of an engineering γ-TiAl based alloy, i.e. the so-called TNM alloy, two alloys are presented. Due to the chemical reactivity of titanium aluminide alloys, electron beam melting processes come into consideration as production methods using optimized manufacturing parameters, providing dense components with only small variations in the Al content between the individual powder layers, which is a decisive factor for the subsequent heat treatment above the γ solvus temperature. The additively produced samples show a fine equiaxed microstructure, whereas the heat-treated samples exhibit a fully lamellar α₂/γ microstructure with an excellent creep resistance. In summary, the adaptation of the additive manufacturing parameters in combination with innovative alloys and subsequent heat treatments are the basis for producing reliable high-performance TiAl components in the near future.
•Development of novel process adapted γ-TiAl based alloys for electron beam melting.•Manufacturing the alloys with optimized parameters and a subsequent heat treatment.•The fully lamellar microstructure shows no banded or columnar phase distribution.•The microstructure of the heat-treated samples provides excellent creep resistance.
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GEOZS, IJS, IMTLJ, KILJ, KISLJ, NLZOH, NUK, OILJ, PNG, SAZU, SBCE, SBJE, UILJ, UL, UM, UPUK, ZAGLJ, ZRSKP
•Atomized powders contain required Y and mechanical alloying is not necessary.•Oxidation of powder particles develops a metastable oxide layer on their surface.•HIP at high temperature dissociates ...metastable Cr2O3 and Y2O3.•XAS and TEM confirm precipitation of very stable oxide nanoparticles.•TMTs are required to increase density of oxide nanoparticles.
Oxide Dispersion Strengthened Ferritic Stainless Steels (ODS FS) are candidate materials for structural components in fusion reactors. Their ultrafine microstructure and the presence of a very stable dispersion of Y-Ti-O nanoclusters provide reasonable fracture toughness, high mechanical and creep strength, and resistance to radiation damage at the operation temperature, up to about 750 °C.
An innovative route to produce ODS FS with composition Fe-14Cr-2W-0.3Ti-0.3Y2O3 (wt.%), named STARS (Surface Treatment of gas Atomized powder followed by Reactive Synthesis), is presented. This route avoids the mechanical alloying (MA) of the elemental or prealloyed powders with yttria to dissolve the yttrium in the ferritic matrix.
In this study, starting powders containing Ti and Y are obtained by gas atomization at laboratory and industrial scale. Then, a metastable Cr- and Fe- rich oxide layer is formed on the surface of the powder particles. During consolidation by HIP the metastable oxide layer at Prior Particle Boundaries (PPBs) dissociates, the oxygen diffuses towards saturated solutions or metallic Ti- and Y-rich particles, and Y-Ti-O nano-oxides (mainly Y2TiO5) precipitate in the ferritic matrix.
Detailed Microstructural characterization by X-ray Photoelectron Spectroscopy (XPS), X-ray Absorption Spectroscopy (XAS), Scanning Electron Microscopy (SEM) and Transmission Electron Microscopy (TEM) of powders and consolidated materials is presented and correlated with mechanical behaviour.
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GEOZS, IJS, IMTLJ, KILJ, KISLJ, NLZOH, NUK, OILJ, PNG, SAZU, SBCE, SBJE, UILJ, UL, UM, UPUK, ZAGLJ, ZRSKP
S2148 The Pneumoperitoneum Mimicker Torres-Rosario, Lorna M.; Negron-Ocasio, Gabriela M.; Adams Chahin, Juan J. ...
The American journal of gastroenterology,
10/2022, Volume:
117, Issue:
10S
Journal Article
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