Bark on trees protects the plant against environmentally adverse conditions as well as fungi and insect attacks. There are different chemical substances, mostly in the outer bark of trees, which can ...stop fungi from developing. Bark as a by-product of wood plantations is available in high quantity and can serve as an excellent source for the production of eco-fungicides. In the presented article, bark of various poplar clones from two short-rotation coppices (SRC) in Poland and Germany was examined to determine the chemical composition, the possible extraction of potential fungicides (terpenes, aromatic and phenolic substances), and influence of their extracts on slowing the growth of mold fungi. It was proved that the content of the fungicidal substances depends strongly on the clone type. Two methods of extraction—Soxhlet and batch—were compared to obtain fungicidal extracts. Fungicidal substances were found in extracts gained with both approaches. Triterpenes, fatty acids, aldehydes, and alcohols were primarily the active fungicides in the Soxhlet extracts, whereas phenolic substances act as fungicides in the batch extracts.
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CEKLJ, EMUNI, FIS, FZAB, GEOZS, GIS, IJS, IMTLJ, KILJ, KISLJ, MFDPS, NLZOH, NUK, OILJ, PNG, SAZU, SBCE, SBJE, SBMB, SBNM, UKNU, UL, UM, UPUK, VKSCE, ZAGLJ
This study aimed to investigate the suitability of the interlaminar shear (ILS) testing method for veneer-based composites. The ILS testing method is an established method for composite materials as ...a qualitative evaluation of the adhesion within the composite. The applicability of this method to veneer based composites enables a simple qualitative statement on the adhesion of the individual layers. The ILS method complements existing wood-based material tests that focus on bonding, using significantly smaller material dimensions.
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DOBA, IZUM, KILJ, NUK, PILJ, PNG, SAZU, UILJ, UKNU, UL, UM, UPUK
The temperature resistance of glued timber, which is crucial for glued wood construction, represents a significant assessment criterion. To gain insights into this aspect, this study utilized methods ...such as a shear strength test in accordance with EN 302-1:2013-06 under thermal loading (from 20 °C to 200 °C), and Differential Scanning Calorimetry (DSC) to determine the glass transition temperature (Tg). An increase in thermal load resulted in a decrease in shear strength and an increase in wood breakage. A hierarchy of adhesive groups was established based on strength performance and wood failure percentage (WFP) at 200 °C. Thermoset adhesives (MF: Melamine Formaldehyde, PRF: Phenol Resorcinol Formaldehyde) led the ranking, followed by elastomer adhesives (1C-PUR: One-Component Polyurethane, EPI: Emulsion Polymer Isocyanate), with thermoplastic adhesive (PVAc: Polyvinyl Acetate) last. Thermoset adhesives further cured under heat. PUR adhesives exhibited higher strength performance at 150 °C and lower temperatures.
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IZUM, KILJ, NUK, PILJ, PNG, SAZU, UL, UM, UPUK
Biopolymer-based flame retardants (FR) are a promising approach to ensure adequate protection against fire while minimizing health and environmental risks. Only a few, however, are suitable for ...industrial purposes because of their poor flame retardancy, complex synthesis pathway, expensive cleaning procedures, and inappropriate application properties. In the present work, wheat starch was modified using a common phosphate/urea reaction system and tested as flame retardant additive for wood fibers. The results indicate that starch derivatives from phosphate/urea systems can reach fire protection efficiencies similar to those of commercial flame retardants currently used in the wood fiber industry. The functionalization leads to the incorporation of fire protective phosphates (up to 38 wt.%) and nitrogen groups (up to 8.3 wt.%). The lowest levels of burning in fire tests were measured with soluble additives at a phosphate content of 3.5 wt.%. Smoldering effects could be significantly reduced compared to unmodified wood fibers. The industrial processing of a starch-based flame retardant on wood insulating materials exhibits the fundamental applicability of flame retardants. These results demonstrate that starch modified from phosphate/urea-systems is a serious alternative to traditional flame retardants.
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IZUM, KILJ, NUK, PILJ, PNG, SAZU, UL, UM, UPUK
To obtain special wood properties for various technical applications, fungi with their broad spectrum of activity can make a contribution. The foundations for today's mycological wood modifications ...were laid by researchers who wanted to increase the yield of edible mushrooms. They noticed the changed properties of the wooden substrate by the progressive wood degradation. Controlled use of fungi and an eye for the technical benefits of mycologically degraded wood revolutionized the fundaments of wood modification, primarily biological. In this context, the so-called Myko-Holz (myco-wood) plays a unique role and influences the current research for pencil wood, tone wood or even spalting.
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•Acoustic, mechanical and swelling properties of Indian Rosewood (Dalbergia latifolia Roxb.), Ziricote (Cordia dodecandra DC), African Blackwood (Dalbergia melanoxylon Roxb.) and ...Ebony (Diospyros crassiflora Hiern.).•Limited availability of tropical tonewoods according to CITES.•Increase the low knowledge of tropical wood used as tonewood in classical guitars to find suitable substitution woods.
There is a need of substitution woods for the use in musical instruments because of the limited availability of some commonly used tropical tonewoods. Before substitutions can be found, it is necessary to know about the required properties. Hence, in this paper acoustical, mechanical and physical properties of four common tropical hardwoods (Indian rosewood, ziricote, African blackwood and ebony) were determined because there are less literature values for some properties available, e.g. internal friction, hardness or swelling behaviour. The acoustic properties were determined by means of experimental modal analysis, the mechanical properties by means of static bending tests and tests of the Brinell hardness. For the swelling behaviour the volume swelling and also the differential swelling coefficients were determined. With the results it is possible to look for new ‘tonewoods’ or to specifically modified woods, e.g. thermally treated wood, to substitute tropical wood species.
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GEOZS, IJS, IMTLJ, KILJ, KISLJ, NLZOH, NUK, OILJ, PNG, SAZU, SBCE, SBJE, UILJ, UL, UM, UPCLJ, UPUK, ZAGLJ, ZRSKP
The replacement of potentially hazardous synthetic dyes with natural dyes and pigments are of great interest for a sustainable economy. In order to obtain cost‐efficient, environmentally friendly and ...competitive products, improvements in the cultivation and extraction of pigment‐producing organisms and in dyeing processes are necessary. In our study, we were able to scale up the production of xylindein by Chlorociboria aeruginascens from 3 to 70 L bioreactor cultivations. We have identified important bioprocess parameters like low shear stress (150 rpm, tip speed <0.5 m/s) for optimal pigment yield (4.8 mg/L/d). Additionally, we have demonstrated the potential of laetiporic acid production by Laetiporus sulphureus in various cultivation systems and media, achieving dried biomass concentrations of almost 10 g/L with a 7 L bioreactor cultivation after 17 days. Extractions performed at 70°C and 15 min incubation time showed optimal results. To the best of our knowledge, we have described for the first time the use of this pigment in silk dyeing, which results in a brilliant hue that cannot easily be produced by other natural pigments.
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BFBNIB, FZAB, GIS, IJS, KILJ, NLZOH, NUK, OILJ, SBCE, SBMB, UL, UM, UPUK
The mechanical properties of cured wood adhesive films were tested in a dry state by means of nanoindentation. These studies have found that the application of adhesives have an effect on the ...accuracy of the hardness and elastic modulus determination. The highest values of hardness among the tested adhesives at 20 °C have condensation resins: MF (0.64 GPa) and RPF (0.52 GPa). Then the decreasing EPI (0.43 GPa), PUR (0.23 GPa) and PVAc (0.14 GPa) adhesives. The values of the elastic modulus look a little bit different. The highest values among the tested adhesives at 20 °C have EPI (11.97 GPa), followed by MF (10.54 GPa), RPF (7.98 GPa), PVAc (4.71 GPa) and PUR (3.37 GPa). X-ray micro-computed tomography was used to evaluate the adhesive joint by the determination of the voids. It has been proven that this value depends on the type of adhesive, glue quantity and reactivity. The highest values of the void ratio achieve the PUR (17.26%) adhesives, then PVAc (13.97%), RRF (6.88%), MF (1.78%) and EPI (0.03%). The ratio of the gaps increases with the higher joint thickness. A too high proportion of voids may weaken the adhesive joint.
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IZUM, KILJ, NUK, PILJ, PNG, SAZU, UL, UM, UPUK
This paper deals with comparative studies of bending behavior of untreated and modified European beech (Fagus sylvatica L.), European oak (Quercus spp.) and black locust (Robinia pseudoacacia L.). ...The modification of the woods included both ammonia treatment and ammonia treatment in combination with mechanical densification. For each ammonia treatment, pure gaseous ammonia was used. The investigations were conducted by means of three-point bending tests. The bulk density increases significantly due to ammonia treatment and, furthermore, due to additional mechanical densification. The modulus of rupture is not affected by ammonia treatment. Additional mechanical densification, however, leads to a strong increase in the strength and stiffness. The deflection behavior changes in such a way that the ammonia treatment leads to an increase in deflection, and the additional mechanical densification further reinforces this trend.
In the field of lightweight construction, the use of natural fibers as reinforcement in composites has been increasingly discussed. Additionally, the damping properties of natural fibers are known ...from fiber materials such as fiber insulation boards. In the scope of the work presented here, the focus is on identifying the potential of natural fibers for lightweight structures with high vibration damping capacity. For this purpose, test specimens made of flax fiber-reinforced and glass fiber-reinforced thermoplastic composites were manufactured and characterized. Contrary to expectations, the flax fiber-reinforced composite exhibited an almost isotropic damping characteristic. A comparison of the damping and stiffness properties determined by measurement confirms the high potential of natural fiber-reinforced materials for lightweight structures with high damping.