Recent studies show that millimeter wave (mmWave) communications can offer orders of magnitude, which increases in the cellular capacity. However, the secrecy performance of an mmWave cellular ...network has not been investigated so far. Leveraging the new path-loss and blockage models for mmWave channels, which are significantly different from the conventional microwave channel, this paper comprehensively studies the network-wide physical layer security performance of the downlink transmission in an mmWave cellular network under a stochastic geometry framework. We first study the secure connectivity probability and the average number of perfect communication links per unit area in a noise-limited mmWave network for both non-colluding and colluding eavesdroppers scenarios, respectively. Then, we evaluate the effect of the artificial noise (AN) on the secrecy performance, and derive the analysis result of average number of perfect communication links per unit area in an interference-limited mmWave network. Numerical results demonstrate the network-wide secrecy performance, and provide interesting insights into how the secrecy performance is influenced by various network parameters: antenna array pattern, base station intensity, and AN power allocation.
The rapid development in wearable electronics has spurred a great deal of interest in flexible energy storage devices, particularly fiber‐shaped energy storage devices (FSESDs), such as fiber‐shaped ...supercapacitors (FSSCs) and fiber‐shaped batteries (FSBs). Depending on their electrode configurations, FSESDs can contain five differently structured electrodes, including parallel fiber electrodes (PFEs), twisted fiber electrodes (TFDs), wrapped fiber electrodes (WFEs), coaxial fiber devices (CFEs), and rolled electrodes (REs). Various rational methods have been devised to incorporate these fiber‐shaped electrodes into multifunctional FSESDs, including fiber‐shaped supercapacitors, lithium‐ion batteries, lithium–sulfur batteries, lithium–air batteries, zinc–air batteries, and aluminum–air batteries. Although significant progress has been made in FSESDs, it remains a major challenge to make high‐performance fiber‐shaped devices at low cost. A focused and critical review of the recent advancements in fiber‐shaped supercapacitors and lithium‐ion batteries is provided here. The pros and cons for each of the aforementioned electrode configurations and FSESDs are discussed, along with current challenges and future opportunities for FSESDs.
The recent development of fiber‐shaped energy systems is reviewed, highlighting the structural design of fiber‐based electronic devices in combination with their applications in energy storage, energy harvesting, and other related fields. Current challenges and future outlooks regarding this emerging area are discussed.
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In this study, based on the regional land-use risk space division (regional ecological risk source/receptor space identification) using production-living-ecology analysis, three spatial function ...indexes, i.e., production, living, and ecology function indexes, were proposed for regional ecological risk assessment (RERA) with respect to human disturbance. The first two indexes can be regarded as regional ecological risk source indexes, whereas the final index can be regarded as a regional ecological risk receptor index. Using an artificial assignment method based on the land-use types and Defense Meteorological Program Operational Line-Scan System (DMSP/OLS) nighttime light intensity data, these three spatial function indexes were effectively manifested. By incorporating these indexes with eco-environmental vulnerability proxies, an RERA framework was established and applied in the Poyang Lake Eco-economic Zone (PLEZ), which is an ecological-protection and economic-development coordination-oriented region in China. The results suggest that (1) the DMSP/OLS nighttime light intensity data correlated well with the spatial distribution of regional urban/town areas; consequently, it was reasonable to use this dataset for representing regional production-living function space (urban/town area). (2) Overall, the forestlands and winter waterbodies of Poyang Lake were in the high-risk grade, and so did the Nanchang City construction land area; in contrast, the final risk levels of winter wetlands and croplands were relatively low. (3) Owing to the highest human disturbance (including both production and consumption human activities) and eco-environmental vulnerability level, urban/town areas such as Nanchang City had the highest final risk grade. (4) The low, medium, high, and very high-risk grades accounted for 21.22%, 39.53%, 36.31%, and 2.94% of the region, respectively. I believe that the proposed land use function indexes will be helpful in conducting human-caused RERA research in the future. Furthermore, the assessment results can provide a scientific basis for regional ecological risk management within the PLEZ.
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Ultrathin metal–organic framework (MOF) nanosheets (NSs) offer potential for many applications, but the synthetic strategies are largely limited to top‐down, low‐yield exfoliation methods. Herein, ...Ni–M–MOF (M=Fe, Al, Co, Mn, Zn, and Cd) NSs are reported with a thickness of only several atomic layers, prepared by a large‐scale, bottom‐up solvothermal method. The solvent mixture of N,N‐dimethylacetamide and water plays key role in controlling the formation of these two‐dimensional MOF NSs. The MOF NSs can be directly used as efficient electrocatalysts for the oxygen evolution reaction, in which the Ni–Fe–MOF NSs deliver a current density of 10 mA cm−2 at a low overpotential of 221 mV with a small Tafel slope of 56.0 mV dec−1, and exhibit excellent stability for at least 20 h without obvious activity decay. Density functional theory calculations on the energy barriers for OER occurring at different metal sites confirm that Fe is the active site for OER at Ni–Fe–MOF NSs.
Ultrathin, binary MOF nanosheets (NSs) have been successfully prepared for the first time and directly used as efficient oxygen evolution reaction (OER) catalysts. The binary MOF NSs exhibit a highly composition‐dependent OER activity. The optimized Ni–Fe–MOF NSs are highly active and stable towards the OER.
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In this paper, we study power-efficient resource allocation for multicarrier non-orthogonal multiple access systems. The resource allocation algorithm design is formulated as a non-convex ...optimization problem which jointly designs the power allocation, rate allocation, user scheduling, and successive interference cancellation (SIC) decoding policy for minimizing the total transmit power. The proposed framework takes into account the imperfection of channel state information at transmitter and quality of service requirements of users. To facilitate the design of optimal SIC decoding policy on each subcarrier, we define a channel-to-noise ratio outage threshold. Subsequently, the considered non-convex optimization problem is recast as a generalized linear multiplicative programming problem, for which a globally optimal solution is obtained via employing the branch-and-bound approach. The optimal resource allocation policy serves as a system performance benchmark due to its high computational complexity. To strike a balance between system performance and computational complexity, we propose a suboptimal iterative resource allocation algorithm based on difference of convex programming. Simulation results demonstrate that the suboptimal scheme achieves a close-to-optimal performance. Also, both proposed schemes provide significant transmit power savings than that of conventional orthogonal multiple access schemes.
Inorganic solid electrolytes play a critical role in solid‐state lithium batteries achieving high safety levels and high energy densities. The synthetic approaches to solid electrolytes are important ...for both fundamental research and practical applications. Li1+xAlxTi2−x(PO4)3 (LATP) and Li1+xAlxGe2−x(PO4)3 (LAGP) are two representative solid electrolytes with a sodium superionic conductor (NaSICON) structure. Herein, LATP and LAGP solid electrolytes are reviewed from the synthesis perspective, and correlated with their structure and conductive properties, as well as their electrochemical applications in batteries. First, the solid‐ and liquid‐based synthetic methods to LATP and LAGP solid electrolytes and the key influencing factors are described. Second, the crystal structures and phase purities obtained from different synthetic approaches are introduced. Third, the conductive mechanisms, composition effects, and synthetic effects on the conductivities of LATP and LAGP solid electrolytes are compared. Fourth, the electrochemical applications of these two solid electrolytes in full batteries are discussed, including roles as solid electrolytes, composite components in electrodes, and surface coatings on electrodes. In the last section, a brief outlook is provided on the future development of NaSICON‐type solid electrolytes for all‐solid‐state batteries.
How was it made? Li1+xAlxTi2−x(PO4)3 (LATP) and Li1+xAlxGe2−x(PO4)3 (LAGP), which are popular sodium superionic conductor (NaSICON)‐type solid electrolytes, are reviewed from the perspective of their synthesis. The synthetic methods have been correlated with the structures and conductive properties. Electrochemical applications of these electrolytes in batteries are also presented.
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In this article, we consider an intelligent reflecting surface (IRS) assisted Guassian multiple-input multiple-output (MIMO) wiretap channel (WTC), and focus on enhancing its secrecy rate. Due to ...MIMO setting, all the existing solutions for enhancing the secrecy rate over multiple-input single-output WTC completely fall to this work. Furthermore, all the existing studies are simply based on an ideal assumption that full channel state information (CSI) of eavesdropper (Ev) is available. Therefore, we propose numerical solutions to enhance the secrecy rate of this channel under both full and no Ev's CSI cases. For the full CSI case, we propose a barrier method and one-by-one (OBO) optimization combined alternating optimization (AO) algorithm to jointly optimize the transmit covariance R at transmitter (Tx) and phase shift coefficient Q at IRS. For the case of no Ev's CSI, we develop an artificial noise (AN) aided joint transmission scheme to enhance the secrecy rate. In this scheme, a bisection search (BS) and OBO optimization combined AO algorithm is proposed to jointly optimize R and Q. Such scheme is also applied to enhance the secrecy rate under a special scenario in which the direct link between Tx and receiver (Rx)/Ev is blocked due to obstacles. In particular, we propose a BS and minorization-maximization (MM) combined AO algorithm with slightly faster convergence to optimize R and Q for this scenario. Simulation results have validated the monotonic convergence of the proposed algorithms, and it is shown that the proposed algorithms for the IRS-assisted design achieve significantly larger secrecy rate than the other benchmark schemes under full CSI. When Ev's CSI is unknown, the secrecy performance of this channel also can be enhanced by the proposed AN aided scheme, and there is a trade-off between increasing the quality of service at Rx and enhancing the secrecy rate.
The amount of digital text available for analysis by consumer researchers has risen dramatically. Consumer discussions on the internet, product reviews, and digital archives of news articles and ...press releases are just a few potential sources for insights about consumer attitudes, interaction, and culture. Drawing from linguistic theory and methods, this article presents an overview of automated text analysis, providing integration of linguistic theory with constructs commonly used in consumer research, guidance for choosing amongst methods, and advice for resolving sampling and statistical issues unique to text analysis. We argue that although automated text analysis cannot be used to study all phenomena, it is a useful tool for examining patterns in text that neither researchers nor consumers can detect unaided. Text analysis can be used to examine psychological and sociological constructs in consumer-produced digital text by enabling discovery or by providing ecological validity.
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As a new generation of artificial enzymes, nanozymes have the advantages of high catalytic activity, good stability, low cost, and other unique properties of nanomaterials. Due to their wide range of ...potential applications, they have become an emerging field bridging nanotechnology and biology, attracting researchers in various fields to design and synthesize highly catalytically active nanozymes. However, the thorough understanding of experimental phenomena and the mechanisms beneath practical applications of nanozymes limits their rapid development. Herein, the progress of experimental and computational research of nanozymes on two issues over the past decade is briefly reviewed: (1) experimental development of new nanozymes mimicking different types of enzymes. This covers their structures and applications ranging from biosensing and bioimaging to therapeutics and environmental protection. (2) The catalytic mechanism proposed by experimental and theoretical study. The challenges and future directions of computational research in this field are also discussed.
The experimental development of new nanozymes mimicking different types of enzymes, their applications in biosensing, bioimaging, therapeutics, and environmental protection, and the catalytic mechanisms proposed by theoretical study are reviewed.
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