Soft acoustic metamaterials that embed soft materials in a host media have promising applications in aqueous environments. However, the preparation of soft metamaterials under water and realization ...of low‐frequency soft acoustic metamaterials remains a challenge. By combining 3D printing technology and surface hydrophobic properties, this work presents a general approach to construct 3D soft acoustic metamaterials using bubbles as resonator units. Low‐frequency broadband locally resonant metamaterials can be realized using patterned bubbles with bandgaps that are orders of magnitude wider than other locally resonant metamaterials. In addition, a water‐to‐air ultratransmission metasurface is prepared by patterning a layer of bubbles beneath the water surface, which allows for the ultratransmission of sound across an air–water interface. This strategy opens up promising avenues for many applications based on locally resonant metamaterials such as deep subwavelength acoustic superlenses or negative‐refraction metamaterials.
This work presents a general method for fabricating soft acoustic metamaterials based on bubble architectures. Low‐frequency broadband, locally resonant metamaterials can be achieved. In addition, a water‐to‐air ultratransmission metasurface is prepared by patterning a layer of bubbles beneath the water surface, which allows for ultratransmission of sound across an air–water interface.
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BFBNIB, FZAB, GIS, IJS, KILJ, NLZOH, NUK, OILJ, SAZU, SBCE, SBMB, UL, UM, UPUK
Room‐temperature sodium‐ion batteries (SIBs) have shown great promise in grid‐scale energy storage, portable electronics, and electric vehicles because of the abundance of low‐cost sodium. ...Sodium‐based layered oxides with a P2‐type layered framework have been considered as one of the most promising cathode materials for SIBs. However, they suffer from the undesired P2–O2 phase transition, which leads to rapid capacity decay and limited reversible capacities. Herein, we show that this problem can be significantly mitigated by substituting some of the nickel ions with magnesium to obtain Na0.67Mn0.67Ni0.33−xMgxO2 (0≤x≤0.33). Both the reversible capacity and the capacity retention of the P2‐type cathode material were remarkably improved as the P2–O2 phase transition was thus suppressed during cycling. This strategy might also be applicable to the modulation of the physical and chemical properties of layered oxides and provides new insight into the rational design of high‐capacity and highly stable cathode materials for SIBs.
The P2–O2 phase transition in P2‐Na0.67Mn0.67Ni0.33−xMgxO2 can be effectively suppressed by substituting some of the nickel ions with magnesium. Both the reversible capacity and the capacity retention of this cathode material were thus remarkably improved, and the various phases were characterized by scanning tunneling electron microscopy with atomic resolution.
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BFBNIB, FZAB, GIS, IJS, KILJ, NLZOH, NUK, OILJ, SAZU, SBCE, SBMB, UL, UM, UPUK
As the counterpart of electromagnetic and acoustic metamaterials, elastic metamaterials are artificial periodic elastic composite materials offering the possibility to manipulate elastic wave ...propagation in the subwavelength scale through different mechanisms. For the promising superlensing in the medical ultrasonic detection, double-negative metamaterials possessing the negative effective mass density and elastic modulus simultaneously can be utilized as the ideal superlens for breaking the diffraction limit. In this paper, we present a topology optimization scheme to design the two-dimensional (2D) single-phase anisotropic elastic metamaterials with broadband double-negative effective material properties and demonstrate the superlensing effect at the deep-subwavelength scale. We also discuss the impact of several design parameters adopted in the objective function and constraints on the optimized results. Unlike all previously reported mechanisms, the present optimized structures exhibit the novel quadrupolar or multipolar resonances for the negative effective mass density and negative effective elastic modulus. In addition, negative refraction of the transverse waves in a single-phase material is observed. Most optimized structures in this paper can serve as the anisotropic zero-index metamaterials for the longitudinal or transverse waves at a certain frequency. The cloaking effect is demonstrated for both the longitudinal and transverse waves. Moreover, with the particular constraints in the optimization procedure, a super-anisotropic metamaterial exhibiting the double-negative and hyperbolic dispersions in two principal directions within two different frequency ranges is obtained. The developed optimization scheme provides a robust computational tool for negative-index engineering of elastic metamaterials and may guide the design and optimization of other types of metamaterials, including the electromagnetic and acoustic metamaterials. The unusual properties of our optimized structures can inspire new ideas and novel applications including the low-frequency vibration attenuation, flat lens and ultrasonography for elastic waves.
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GEOZS, IJS, IMTLJ, KILJ, KISLJ, NUK, OILJ, PNG, SAZU, SBCE, SBJE, UL, UM, UPCLJ, UPUK, ZRSKP
By using the finite element method and a “coarse to fine” two-stage genetic algorithm as the forward calculation method and the inverse search scheme, respectively, we perform both the unconstrained ...and constrained optimal design of the unit cell topology of the two-dimensional square-latticed solid phononic crystals (PnCs), to maximize the relative widths of the gaps between the adjacent energy bands of the PnCs. In the constrained optimizations, the maximization is subjected to the constraint of a predefined average density. In the numerical results, the variation patterns of the optimized structures with the order of the bandgap for both the out-plane shear and the in-plane mixed elastic wave modes are presented, and the effects of both the material contrast and the predefined average density on the obtained optimal structures are discussed.
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EMUNI, FIS, FZAB, GEOZS, GIS, IJS, IMTLJ, KILJ, KISLJ, MFDPS, NLZOH, NUK, OBVAL, OILJ, PNG, SAZU, SBCE, SBJE, SBMB, SBNM, UKNU, UL, UM, UPUK, VKSCE, ZAGLJ
3D batteries continue to be of widespread interest for flexible energy storage where the 3D nanostructured cathode is the key component to achieve both high energy and power densities. While current ...work on flexible cathodes tends to emphasize the use of flexible scaffolds such as graphene and/or carbon nanotubes, this approach is often limited by poor electrical contact and structural stability. This communication presents a novel synthetic approach to form 3D array cathode for the first time, the single‐crystalline Na3(VO)2(PO4)2F (NVOPF) by using VO2 array as a seed layer. The NVOPF cathode exhibits both high‐rate capability (charge/discharge in 60 s) and long‐term durability (10,000 cycles at 50 C) for Na ion storage. Utilizing in situ X‐ray diffraction and first principles calculations, the high‐rate properties are correlated with the small volume change, 2D fast ion transport, and the array morphology. A novel all‐array flexible Na+ hybrid energy storage device based on pairing the intercalation‐type NVOPF array cathode with a cogenetic pseudocapacitive VO2 nanosheet array anode is demonstrated.
An oriented Na3(VO)2(PO4)2F nanorods array on flexible substrates is fabricated and demonstrates high‐rate capability and unprecedented long‐term durability (10,000 cycles at 50 C). Using the sodium vanadium fluorophosphates array cathode and pseudocapacitive VO2 array anode, an all‐array flexible Na‐ion hybrid device is constructed, which shows ultrafast sodium ion storage feature to 20 C with high energy density up to 215 W h kg−1.
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FZAB, GIS, IJS, KILJ, NLZOH, NUK, OILJ, SAZU, SBCE, SBMB, UL, UM, UPUK
Abstract
The topology concept in the condensed physics and acoustics is introduced into the elastic wave metamaterial plate, which can show the topological property of the flexural wave. The elastic ...wave metamaterial plate consists of the hexagonal array which is connected by the piezoelectric shunting circuits. The Dirac point is found by adjusting the size of the unit cell and numerical simulations are illustrated to show the topological immunity. Then the closing and breaking of the Dirac point can be generated by the negative capacitance circuits. These investigations denote that the topological immunity can be achieved for flexural wave in mechanical metamaterial plate. The experiments with the active control action are finally carried out to support the numerical design.
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IZUM, KILJ, NUK, PILJ, PNG, SAZU, UL, UM, UPUK
Double-negative acoustic metamaterials (AMMs) offer the promising ability of superlensing for applications in ultrasonography, biomedical sensing and nondestructive evaluation. However, the ...systematic design and realization of broadband double-negative AMMs are stilling missing, which hinder their practical implementations. In this paper, under the simultaneous increasing or non-increasing mechanisms, we develop a unified topology optimization framework involving different microstructure symmetries, minimal structural feature sizes and dispersion extents of effective parameters. The optimization framework is applied to conceive the heuristic resonance-cavity-based and space-coiling metamaterials with broadband double negativity. Meanwhile, we demonstrate the essences of double negativity derived from the novel artificial multipolar LC (inductor-capacitor circuit) and Mie resonances which can be induced by controlling mechanisms in optimization. Furthermore, abundant numerical simulations validate the corresponding double negativity, negative refraction, enhancement of evanescent waves and subwavelengh imaging. Finally, we experimentally show the desired broadband subwavelengh imaging by using the 3D-printed optimized space-coiling metamaterial. The present design methodology provides an ideal approach for constructing the constituent “atoms” of metamaterials according to any artificial physical and structural requirements. In addition, the optimized broadband AMMs and superlens lay the structural foundations of subwavelengh imaging technology.
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•Unified topology optimization framework is developed for designing double-negative acoustic metamaterials (AMMs).•Representative resonance-cavity-based and space-coiling microstructures are explored.•Broadband double negativity originating from novel multipolar LC or Mie resonances can be induced systematically.•Desired broadband subwavelength imaging of topology-optimized AMMs is verified experimentally.
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GEOZS, IJS, IMTLJ, KILJ, KISLJ, NLZOH, NUK, OILJ, PNG, SAZU, SBCE, SBJE, UILJ, UL, UM, UPCLJ, UPUK, ZAGLJ, ZRSKP
Acoustic metasurfaces can reshape a reflected wavefront rather arbitrarily, despite being much thinner than the wavelength, thus allowing on-demand wavefront modulation in a variety of applications. ...Recent passive metasurfaces, however, have suffered from bandwidth limitations, thus restricting their range of operation. In this work, we propose the systematic design of ultra-broadband passive metasurfaces by combining the broadband local reflection rule with an optimization method. The validation of the technique is demonstrated by fabrication and measurement of an ultra-broadband carpet cloak. Numerical and experimental results show that the relative bandwidth of the optimized carpet cloak, thinner than one fifth of the maximum wavelength, can exceed 93.33%, a value that is much larger than that of previous passive metasurfaces. Furthermore, multi-frequency pulse incidence tests reveal the excellent time-domain broadband characteristics of the metasurface over a wide range of angles of incidence. The proposed strategy opens a new route for the design of advanced passive metasurfaces for ultra-broadband wave manipulation and thus promotes practical applications of broadband acoustical devices.
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•An inverse optimization is proposed to design ultra-broadband passive metasurfaces.•More than 93% relative bandwidth is experimentally and numerically verified.•Time-domain broadband characteristic over a wide-angle range is revealed.
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GEOZS, IJS, IMTLJ, KILJ, KISLJ, NLZOH, NUK, OILJ, PNG, SAZU, SBCE, SBJE, UILJ, UL, UM, UPCLJ, UPUK, ZAGLJ, ZRSKP
Hyperbolic metamaterials, the highly anisotropic subwavelength media, immensely widen the engineering feasibilities for wave manipulation. However, limited by the empirical structural topologies, the ...reported hyperbolic elastic metamaterials (HEMMs) suffer from the limitations of the relatively narrow frequency width, inflexible adjustable operating subwavelength scale and difficulty to further improve the imaging resolution. Here, we show an inverse-design strategy for HEMMs by topology optimization. We design broadband single-phase HEMMs supporting multipolar resonances at different prescribed deep-subwavelength scales, and demonstrate the super-resolution imaging for longitudinal waves. Benefiting from the extreme enhancement of the evanescent waves, an optimized HEMM at an ultra-low frequency can yield an imaging resolution of ~λ/64, representing the record in the field of elastic metamaterials. The present research provides a novel and general design methodology for exploring the HEMMs with unrevealed mechanisms and guides the ultrasonography and general biomedical applications.
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IZUM, KILJ, NUK, PILJ, PNG, SAZU, UL, UM, UPUK
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