This study reports the most comprehensive assessment to date of the relations that the domains and facets of Big Five and HEXACO personality have with self-reported subjective well-being (SWB: life ...satisfaction, positive affect, and negative affect) and psychological well-being (PWB: positive relations, autonomy, environmental mastery, purpose in life, self-acceptance, and personal growth). It presents a meta-analysis (n = 334,567, k = 462) of the correlations of Big Five and HEXACO personality domains with the dimensions of SWB and PWB. It provides the first meta-analysis of personality and well-being to examine (a) HEXACO personality, (b) PWB dimensions, and (c) a broad range of established Big Five measures. It also provides the first robust synthesis of facet-level correlations and incremental prediction by facets over domains in relation to SWB and PWB using 4 large data sets comprising data from prominent, long-form hierarchical personality frameworks: NEO PI-R (n = 1,673), IPIP-NEO (n = 903), HEXACO PI-R (n = 465), and Big Five Aspect Scales (n = 706). Meta-analytic results highlighted the importance of Big Five neuroticism, extraversion, and conscientiousness. The pattern of correlations between Big Five personality and SWB was similar across personality measures (e.g., BFI, NEO, IPIP, BFAS, Adjectives). In the HEXACO model, extraversion was the strongest well-being correlate. Facet-level analyses provided a richer description of the relationship between personality and well-being, and clarified differences between the two trait frameworks. Prediction by facets was typically around 20% better than domains, and this incremental prediction was larger for some well-being dimensions than others.
Public Significance Statement
This meta-analysis provides a comprehensive and detailed overview of the substantial links between personality traits and well-being. It is the first investigation to incorporate the two most widely accepted frameworks for measuring personality (i.e., the Big Five and the HEXACO model) as well as two of the most influential models of human well-being (i.e., subjective and psychological well-being). Results of the meta-analysis provide important insights into the various pathways through which people build well-being in their lives.
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CEKLJ, FFLJ, NUK, ODKLJ, PEFLJ, UPUK
Functionalization of atomically thin nanomaterials enables the tailoring of their chemical, optical and electronic properties. Exfoliated black phosphorus (BP)-a layered two-dimensional ...semiconductor-exhibits favourable charge-carrier mobility, tunable bandgap and highly anisotropic properties, but it is chemically reactive and degrades rapidly in ambient conditions. Here we show that covalent aryl diazonium functionalization suppresses the chemical degradation of exfoliated BP even after three weeks of ambient exposure. This chemical modification scheme spontaneously forms phosphorus-carbon bonds, has a reaction rate sensitive to the aryl diazonium substituent and alters the electronic properties of exfoliated BP, ultimately yielding a strong, tunable p-type doping that simultaneously improves the field-effect transistor mobility and on/off current ratio. This chemical functionalization pathway controllably modifies the properties of exfoliated BP, and thus improves its prospects for nanoelectronic applications.
Two-dimensional (2D) semiconducting transition metal dichalcogenides (TMDCs) and black phosphorus (BP) have beneficial electronic, optical, and physical properties at the few-layer limit. As ...atomically thin materials, 2D TMDCs and BP are highly sensitive to their environment and chemical modification, resulting in a strong dependence of their properties on substrate effects, intrinsic defects, and extrinsic adsorbates. Furthermore, the integration of 2D semiconductors into electronic and optoelectronic devices introduces unique challenges at metal–semiconductor and dielectric–semiconductor interfaces. Here, we review emerging efforts to understand and exploit chemical effects to influence the properties of 2D TMDCs and BP. In some cases, surface chemistry leads to significant degradation, thus necessitating the development of robust passivation schemes. On the other hand, appropriately designed chemical modification can be used to beneficially tailor electronic properties, such as controlling doping levels and charge carrier concentrations. Overall, chemical methods allow substantial tunability of the properties of 2D TMDCs and BP, thereby enabling significant future opportunities to optimize performance for device applications.
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IJS, KILJ, NUK, PNG, UL, UM
The anisotropic thermal conductivity of passivated black phosphorus (BP), a reactive two‐dimensional material with strong in‐plane anisotropy, is ascertained. The room‐temperature thermal ...conductivity for three crystalline axes of exfoliated BP is measured by time‐domain thermoreflectance. The thermal conductivity along the zigzag direction is ≈2.5 times higher than that of the armchair direction.
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BFBNIB, FZAB, GIS, IJS, KILJ, NLZOH, NUK, OILJ, SAZU, SBCE, SBMB, UL, UM, UPUK
Solution dispersions of two-dimensional (2D) black phosphorus (BP)often referred to as phosphoreneare achieved by solvent exfoliation. These pristine, electronic-grade BP dispersions are produced ...with anhydrous organic solvents in a sealed-tip ultrasonication system, which circumvents BP degradation that would otherwise occur via solvated O2 or H2O. Among conventional solvents, N-methylpyrrolidone (NMP) is found to provide stable, highly concentrated (∼0.4 mg/mL) BP dispersions. Atomic force microscopy, scanning electron microscopy, transmission electron microscopy, Raman spectroscopy, and X-ray photoelectron spectroscopy show that the structure and chemistry of solvent-exfoliated BP nanosheets are comparable to mechanically exfoliated BP flakes. Additionally, residual NMP from the liquid-phase processing suppresses the rate of BP oxidation in ambient conditions. Solvent-exfoliated BP nanosheet field-effect transistors exhibit ambipolar behavior with current on/off ratios and mobilities up to ∼104 and ∼50 cm2 V–1 s–1, respectively. Overall, this study shows that stable, highly concentrated, electronic-grade 2D BP dispersions can be realized by scalable solvent exfoliation, thereby presenting opportunities for large-area, high-performance BP device applications.
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IJS, KILJ, NUK, PNG, UL, UM
Exfoliation of single-layer graphene from bulk graphite and the subsequent discovery of exotic physics and emergent phenomena in the atomically thin limit has motivated the isolation of other ...two-dimensional (2D) layered nanomaterials. Early work on isolated 2D nanomaterial flakes has revealed a broad range of unique physical and chemical properties with potential utility in diverse applications. For example, the electronic and optical properties of 2D nanomaterials depend strongly on atomic-scale variations in thickness, enabling enhanced performance in optoelectronic technologies such as light emitters, photodetectors, and photovoltaics. Much of the initial research on 2D nanomaterials has relied on micromechanical exfoliation, which yields high-quality 2D nanomaterial flakes that are suitable for fundamental studies but possesses limited scalability for real-world applications. In an effort to overcome this limitation, solution-processing methods for isolating large quantities of 2D nanomaterials have emerged. Importantly, solution processing results in 2D nanomaterial dispersions that are amenable to roll-to-roll fabrication methods that underlie lost-cost manufacturing of thin-film transistors, transparent conductors, energy storage devices, and solar cells. Despite these advantages, solution-based exfoliation methods typically lack control over the lateral size and thickness of the resulting 2D nanomaterial flakes, resulting in polydisperse dispersions with heterogeneous properties. Therefore, post-exfoliation separation techniques are needed to achieve 2D nanomaterial dispersions with monodispersity in lateral size, thickness, and properties. In this Account, we survey the latest developments in solution-based separation methods that aim to produce monodisperse dispersions and thin films of emerging 2D nanomaterials such as graphene, boron nitride, transition metal dichalcogenides, and black phosphorus. First, we motivate the need for precise thickness control in 2D nanomaterials by reviewing thickness-dependent physical properties. Then we present a succinct survey of solution-based exfoliation methods that yield 2D nanomaterial dispersions in organic solvents and aqueous media. The Account subsequently focuses on separation methods, including a critical analysis of their relative strengths and weaknesses for 2D nanomaterials with different buoyant densities, van der Waals interactions, and chemical reactivities. Specifically, we evaluate sedimentation-based density gradient ultracentrifugation (sDGU) and isopycnic DGU (iDGU) for post-exfoliation 2D nanomaterial dispersion separation. The comparative advantages of sedimentation and isopycnic methods are presented in both aqueous and nonaqueous media for 2D nanomaterials with varying degrees of chemical reactivity. Finally, we survey methods for forming homogeneous thin films from 2D nanomaterial dispersions and emerging technologies that are likely to benefit from these structures. Overall, this Account provides not only an overview of the present state-of-the-art but also a forward-looking vision for the field of solution-processed monodisperse 2D nanomaterials.
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IJS, KILJ, NUK, PNG, UL, UM
Unencapsulated, exfoliated black phosphorus (BP) flakes are found to chemically degrade upon exposure to ambient conditions. Atomic force microscopy, electrostatic force microscopy, transmission ...electron microscopy, X-ray photoelectron spectroscopy, and Fourier transform infrared spectroscopy are employed to characterize the structure and chemistry of the degradation process, suggesting that O2 saturated H2O irreversibly reacts with BP to form oxidized phosphorus species. This interpretation is further supported by the observation that BP degradation occurs more rapidly on hydrophobic octadecyltrichlorosilane self-assembled monolayers and on H-Si(111) versus hydrophilic SiO2. For unencapsulated BP field-effect transistors, the ambient degradation causes large increases in threshold voltage after 6 h in ambient, followed by a ∼103 decrease in FET current on/off ratio and mobility after 48 h. Atomic layer deposited AlO x overlayers effectively suppress ambient degradation, allowing encapsulated BP FETs to maintain high on/off ratios of ∼103 and mobilities of ∼100 cm2 V–1 s–1 for over 2 weeks in ambient conditions. This work shows that the ambient degradation of BP can be managed effectively when the flakes are sufficiently passivated. In turn, our strategy for enhancing BP environmental stability will accelerate efforts to implement BP in electronic and optoelectronic applications.
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At the atomic-cluster scale, pure boron is markedly similar to carbon, forming simple planar molecules and cage-like fullerenes. Theoretical studies predict that two-dimensional (2D) boron sheets ...will adopt an atomic configuration similar to that of boron atomic clusters. We synthesized atomically thin, crystalline 2D boron sheets (i.e., borophene) on silver surfaces under ultrahigh-vacuum conditions. Atomic-scale characterization, supported by theoretical calculations, revealed structures reminiscent of fused boron clusters with multiple scales of anisotropic, out-of-plane buckling. Unlike bulk boron allotropes, borophene shows metallic characteristics that are consistent with predictions of a highly anisotropic, 2D metal.
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BFBNIB, NMLJ, NUK, ODKLJ, PNG, SAZU, UL, UM, UPUK
Locke traces the concept of active power to the experience of voluntary action in ourselves. I argue that Locke does not find in voluntary action a necessary connection binding volition and action. I ...defend the application of Locke’s regularity theory of causal judgment to the operation of the will. The will is classified as a cause because it is regularly accompanied by a movement in our limbs or a change in our thoughts. I argue that Locke does not equate the concepts of cause and active power. He maintains that something can serve as a cause, and so bring about change, in virtue of activity or in virtue of its susceptibility to external influence. I go on to develop what I refer to as the ascription puzzle. Locke, who provides a criterion for classifying something as a cause, does not develop a criterion of for classifying causes as either active or passive in nature. The ascription puzzle is vexing because Locke has no principled way to establish, among other things, that humans, in acting voluntarily, exercise active power. The result is that Locke should not be taken to identify the experience of voluntary action as the origin of the concept of active power because of any metaphysical considerations bearing on human agency.
With a semiconducting band gap and high charge carrier mobility, two-dimensional (2D) black phosphorus (BP)often referred to as phosphoreneholds significant promise for next generation electronics ...and optoelectronics. However, as a 2D material, it possesses a higher surface area to volume ratio than bulk BP, suggesting that its chemical and thermal stability will be modified. Herein, an atomic-scale microscopic and spectroscopic study is performed to characterize the thermal degradation of mechanically exfoliated 2D BP. From in situ scanning/transmission electron microscopy, decomposition of 2D BP is observed to occur at ∼400 °C in vacuum, in contrast to the 550 °C bulk BP sublimation temperature. This decomposition initiates via eye-shaped cracks along the 001 direction and then continues until only a thin, amorphous red phosphorus like skeleton remains. In situ electron energy loss spectroscopy, energy-dispersive X-ray spectroscopy, and energy-loss near-edge structure changes provide quantitative insight into this chemical transformation process.
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IJS, KILJ, NUK, PNG, UL, UM
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