Electrochemical reduction of CO2 (ERC) into useful products, such as formic acid and carbon monoxide, is a fascinating approach for CO2 fixation as well as energy storage. Sn‐based materials are ...attractive catalysts for highly selective ERC into C1 products (including HCOOH and CO), but still suffer from high overpotential, low current density, and poor stability. Here, One‐dimensional (1D) SnO2 with wire‐in‐tube (WIT) structure is synthesized and shows superior selectivity for C1 products. Using the WIT SnO2 as the ERC catalyst, very high Faradaic efficiency of C1 products (>90%) can be achieved at a wide potential range from −0.89 to −1.29 V versus RHE, thus substantially suppressing the hydrogen evolution reaction. The electrocatalyst also exhibits excellent long‐term stability. The improved catalytic activity of the WIT SnO2 over the commercial SnO2 nanoparticle indicates that higher surface area and large number of grain boundaries can effectively enhance the ERC activity. Synthesized via a facile and low‐cost electrospinning technology, the reduced WIT SnO2 can serve as a promising electrocatalyst for efficient CO2 to C1 products conversion.
In this work, a novel One‐dimensional (1D) SnO2 with wire‐in‐tube (WIT) structure is synthesized via a facile and low‐cost electrospinning technology for CO2 reduction. Superior selectivity for C1 products (>90%) is achieved at a wide potential range. This WIT SnO2 can serve as a promising electrocatalyst for efficient CO2 to C1 products conversion.
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BFBNIB, FZAB, GIS, IJS, KILJ, NLZOH, NUK, OILJ, SAZU, SBCE, SBMB, UL, UM, UPUK
Electrocatalytic reduction of carbon dioxide (CO2ER) in rechargeable Zn–CO2 battery still remains a great challenge. Herein, a highly efficient CO2ER electrocatalyst composed of coordinatively ...unsaturated single‐atom copper coordinated with nitrogen sites anchored into graphene matrix (Cu–N2/GN) is reported. Benefitting from the unsaturated coordination environment and atomic dispersion, the ultrathin Cu–N2/GN nanosheets exhibit a high CO2ER activity and selectivity for CO production with an onset potential of −0.33 V and the maximum Faradaic efficiency of 81% at a low potential of −0.50 V, superior to the previously reported atomically dispersed Cu–N anchored on carbon materials. Experimental results manifest the highly exposed and atomically dispersed Cu–N2 active sites in graphene framework where the Cu species are coordinated by two N atoms. Theoretical calculations demonstrate that the optimized reaction free energy for Cu–N2 sites to capture CO2 promote the adsorption of CO2 molecules on Cu–N2 sites; meanwhile, the short bond lengths of Cu–N2 sites accelerate the electron transfer from Cu–N2 sites to *CO2, thus efficiently boosting the *COOH generation and CO2ER performance. A designed rechargeable Zn–CO2 battery with Cu–N2/GN nanosheets deliver a peak power density of 0.6 mW cm−2, and the charge process of battery can be driven by natural solar energy.
Highly efficient Cu–N2 sites for CO2 electroreduction: an ultrathin Cu–N2/GN nanosheet with highly exposed and coordinatively unsaturated Cu–N2 active sites is developed for highly efficient CO2 reduction to CO.
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BFBNIB, FZAB, GIS, IJS, KILJ, NLZOH, NUK, OILJ, SAZU, SBCE, SBMB, UL, UM, UPUK
•We developed a model to decompose carbon emissions into five factors.•We estimated the directions and magnitudes of the influences of five factors.•We find the sources of carbon emissions from ...sectors and regions.•We discussed some strategies for China’s emissions abatement.
This study analyzes factors that influence carbon emissions due to fossil energy consumption in China to identify key factors for policies promoting carbon emission reductions. Carbon emissions for energy consumption are decomposed into energy structure, energy intensity, industry structure, economic output, and population scale effects. The major driver of carbon emissions is the economic output effect, followed by population scale and energy structure effects. The energy intensity effect is a main inhibitory factor. The factors influencing carbon emissions in China were investigated for different industries, sectors and regions. The results show that carbon emissions mostly arise from industry, while the other sectors generally exhibit good performance in reducing emissions. In industry, the main contributors to carbon emissions are electricity production, petroleum processing and coking, metal smelting and rolling, chemical manufacture, and non-metal mineral products. Regional analysis revealed differences in economic output, energy intensity, and industrial structure among three regions of China. Policy implications in terms of industrial structure and energy consumption are highlighted.
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GEOZS, IJS, IMTLJ, KILJ, KISLJ, NUK, OILJ, PNG, SAZU, SBCE, SBJE, UL, UM, UPCLJ, UPUK
Using the logarithmic mean Divisia index (LMDI) method, we decomposed the factors that affect carbon emissions at a multi-regional level. Based on a comparative analysis of the regional contributions ...to carbon emissions in China from 1995 to 2012, we found that economic growth is a major factor that increases carbon emissions. Excluding Hainan, Guangxi, Ningxia, and Xinjiang, the energy intensity effects of other provinces and municipalities inhibited carbon emissions clearly. The energy structure effect in Beijing and Shanghai inhibited carbon emissions most obviously, whereas the energy structure effect in Xinjiang promoted carbon emissions to the greatest extent. The energy structure effect in most regions had little influence on carbon emissions. The output proportion effect enhances carbon emissions on the whole, which indicates China's regional economic development is not coordinated from the perspective of carbon emission reductions. Overall, Shandong, Inner Mongolia, and Hebei made the biggest contributions to national carbon emissions. Policy implications in terms of our study results are discussed.
•We decomposed the factors affecting carbon emissions from multi-regional perspective.•The energy structure effects of various regions differed greatly.•The energy intensity effects of most regions inhibited carbon emissions.•The output proportion effect indicates regional economic development is not coordinated.
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GEOZS, IJS, IMTLJ, KILJ, KISLJ, NUK, OILJ, PNG, SAZU, SBCE, SBJE, UL, UM, UPCLJ, UPUK, ZRSKP
Interleukin (IL)-15 has multiple roles in innate and adaptive immunity, especially regarding CD8+ T cells and natural killer cells. However, the role of IL-15 in regulating differentiation of T ...helper cell subsets and mononuclear phagocytes (MPs) in different tissues in vivo is unknown. Here we report that IL-15 indirectly regulates Th17 but not other Th subsets in the intestinal lamina propria (LP), apparently through effects on MPs. Th17 cells in the LP were more prevalent in IL-15 KO mice than their wild-type counterparts, and less prevalent in IL-15 transgenic mice than their wild-type littermates, even co-caged. MPs from the LP of these mice were sufficient to mimic the in vivo finding in vitro by skewing of cocultured wild type OVA-specific CD4+ T cells. However, production of IL-15 or lack thereof by these MPs was not sufficient to explain the skewing, as addition or blockade of IL-15 in the cultures had no effect. Rather, a skewing of the relative proportion of CD11b+, CD103+ and double positive LP MP subsets in transgenic and KO could explain the differences in Th17 cells. Thus, IL-15 may influence MP subsets in the gut in a novel way that alters the frequency of LP Th17 cells.
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DOBA, IZUM, KILJ, NUK, PILJ, PNG, SAZU, SIK, UILJ, UKNU, UL, UM, UPUK
Growth pattern and electronic and magnetic properties of Ag
Cr (n = 1-16) clusters have been investigated via density functional theory (DFT) combined with CALYPSO structure search method. The ...optimized geometry shows that the growth of the global minimum structures of Ag
Cr clusters have obvious rule. when n > 12, silver atoms grow around an icosahedron which is almost unchanged in each structure. Analyses of electronic properties indicate that the doped Cr atom can only enhance the stability of larger silver clusters. Optical absorption and photoelectron spectra of Ag
Cr isomers have been predicted and can be used for their structural identification. The icosahedral Ag
Cr cluster with large energy level gap can be seen as a superatom. The adsorption capacity of Cr atom in Ag
Cr cluster to CO is much higher than that of free Cr atom. The intensity of IR and Ramam spectra can be dramatically enhanced when CO is absorbed on Ag
Cr cluster that Cr atom is encapsulated by Ag atoms. Moreover, the red shift of IR and Raman spectra of CO adsorbed on these clusters is also very small compared to free CO. Magnetism calculations show that the magnetic moment of Ag
Cr clusters decreases linearly from n = 6 to 12 and increases linearly from n = 12 to 16. The total magnetic moment of Ag
Cr cluster is mainly localized on the Cr atom. The change of magnetic moment of Cr atom is related to the charge transfer between Cr and Ag atoms.
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BFBNIB, FZAB, GIS, IJS, KILJ, NLZOH, NUK, OILJ, SAZU, SBCE, SBMB, UL, UM, UPUK
Meteorin‐like (Metrnl) is a novel adipokine that is highly expressed in white adipose tissue. Metrnl stimulates energy expenditure and improves glucose tolerance in rodents. However, whether Metrnl ...plays a role in coronary artery disease (CAD) remains to be elucidated. The present study aimed to investigate the association of serum Metrnl with CAD in Chinese patients. A total of 193 patients with CAD and 156 control subjects were enrolled in this study. Serum Metrnl concentration was measured by enzyme‐linked immunosorbent assay. Anthropometric phenotypes, fasting glucose, serum lipids, and inflammatory cytokines were measured. Serum Metrnl was lower in CAD patients when compared to those controls (132.41 vs 173.17 pg/mL, P < 0.001). Serum Metrnl was negatively correlated with metabolic parameters, including body mass index, total cholesterol, and low‐density lipoprotein cholesterol as well as inflammatory markers including high‐sensitivity C‐reactive protein, IL‐1β, and IL‐11 even after adjustment for potential confounding variables (P < 0.05). In multivariable logistic regression analyses, compared to those in the highest tertile of serum Metrnl levels, subjects in the lowest tertile had the highest risks for CAD (adjusted OR = 2.63, 95% CI = 1.46‐4.27, P = 0.001). After adjustment for potential confounding variables, serum Metrnl was also decreased as the number of stenosed vessels increased (P < 0.001). Furthermore, decreased Metrnl level was negatively correlated with the severity of CAD quantified by the Gensini score. This first case‐control study shows significant associations of serum Metrnl with the presence and severity of CAD, suggesting Metrnl might be a new promising therapeutic target for CAD.
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FZAB, GIS, IJS, KILJ, NLZOH, NUK, OILJ, SAZU, SBCE, SBMB, UL, UM, UPUK
Hypoxia‐inducible factor 1α (HIF‐1α) plays a critical role in the apoptotic process during cardiac ischaemia/reperfusion (I/R) injury. This study aimed to investigate whether post‐treatment with ...dexmedetomidine (DEX) could protect against I/R‐induced cardiac apoptosis in vivo and in vitro via regulating HIF‐1α signalling pathway. Rat myocardial I/R was induced by occluding the left anterior descending artery for 30 minutes followed by 6‐hours reperfusion, and cardiomyocyte hypoxia/reoxygenation (H/R) was induced by oxygen‐glucose deprivation for 6 hours followed by 3‐hours reoxygenation. Dexmedetomidine administration at the beginning of reperfusion or reoxygenation attenuated I/R‐induced myocardial injury or H/R‐induced cell death, alleviated mitochondrial dysfunction, reduced the number of apoptotic cardiomyocytes, inhibited the activation of HIF‐1α and modulated the expressions of apoptosis‐related proteins including BCL‐2, BAX, BNIP3, cleaved caspase‐3 and cleaved PARP. Conversely, the HIF‐1α prolyl hydroxylase‐2 inhibitor IOX2 partly blocked DEX‐mediated cardioprotection both in vivo and in vitro. Mechanistically, DEX down‐regulated HIF‐1α expression at the post‐transcriptional level and inhibited the transcriptional activation of the target gene BNIP3. Post‐treatment with DEX protects against cardiac I/R injury in vivo and H/R injury in vitro. These effects are, at least in part, mediated via the inhibition of cell apoptosis by targeting HIF‐1α signalling.
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FZAB, GIS, IJS, KILJ, NLZOH, NUK, OILJ, SAZU, SBCE, SBMB, UL, UM, UPUK
Synthetic nitrogen (N) fertilizer has played a key role in enhancing food production and keeping half of the world's population adequately fed. However, decades of N fertilizer overuse in many parts ...of the world have contributed to soil, water, and air pollution; reducing excessive N losses and emissions is a central environmental challenge in the 21st century. China's participation is essential to global efforts in reducing N-related greenhouse gas (GHG) emissions because China is the largest producer and consumer of fertilizer N. To evaluate the impact of China's use of N fertilizer, we quantify the carbon footprint of China's N fertilizer production and consumption chain using life cycle analysis. For every ton of N fertilizer manufactured and used, 13.5 tons of CO₂-equivalent (eq) (tCO₂-eq) is emitted, compared with 9.7 t CO₂-eq in Europe. Emissions in China tripled from 1980 131 terrogram (Tg) of CO₂-eq (Tg CO₂-eq) to 2010 (452 Tg CO₂-eq). N fertilizer-related emissions constitute about 7% of GHG emissions from the entire Chinese economy and exceed soil carbon gain resulting from N fertilizer use by several-fold. We identified potential emission reductions by comparing prevailing technologies and management practices in China with more advanced options worldwide. Mitigation opportunities indude improving methane recovery during coal mining, enhancing energy efficiency in fertilizer manufacture, and minimizing N overuse in field-level crop production. We find that use of advanced technologies could cut N fertilizer-related emissions by 20-63%, amounting to 102-357 Tg CO₂-eq annually. Such reduction would decrease China's total GHG emissions by 2-6%, which is significant on a global scale.
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BFBNIB, NMLJ, NUK, PNG, SAZU, UL, UM, UPUK
Measurement device-independent quantum key distribution (MDI-QKD) protocols are immune to all possible attacks on the photon detectors during quantum communication, but their key generation rates are ...low compared with those of other QKD schemes. Increasing each individual photon’s channel capacity is an efficient way to increase the key generation rate, and high-dimensional (HD) encoding is a powerful tool for increasing the channel capacity of photons. In this paper, we propose an HD MDI-QKD protocol with qudits hyper-encoded in spatial mode and polarization degrees of freedom (DOFs). In the proposed protocol, keys can be generated using the spatial mode and polarization DOFs simultaneously. The proposed protocol is unconditionally secure, even for weak coherent pulses with decoy states. The proposed MDI-QKD protocol may be useful for future quantum secure communication applications.
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EMUNI, FIS, FZAB, GEOZS, GIS, IJS, IMTLJ, KILJ, KISLJ, MFDPS, NLZOH, NUK, OBVAL, OILJ, PNG, SAZU, SBCE, SBJE, SBMB, SBNM, UKNU, UL, UM, UPUK, VKSCE, ZAGLJ
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