This study takes the Yangtze River Economic Belt as a study area and analyzes the impacts of natural and socioeconomic factors on air pollution based on a dataset of urban air quality monitoring data ...in 2015 and meteorological and economic statistical data. We first apply the grey relational degree to test for the quantitative relationships between the natural and socioeconomic factors and air pollution. We then employ a novel method, specifically, the geographical detector, from the perspective of spatial stratified heterogeneity to reveal the potential impacts and interaction impacts of the natural and socioeconomic factors on air pollution. The results are as follows. (1) The grey relational degree results reveal that all factors in the topographical and meteorological layer, pollution sources layer, economic development layer, and urbanization layer have high relational degrees, indicating that these factors are closely correlated with air pollution. (2) The factor detector analysis reveals that the PM2.5 factor has the biggest q value, indicating that it is the primary contributor to air pollution, followed by PM10 and elevation. (3) The interaction detector analysis reveals that the interaction of two factors plays a more important role in influencing air pollution than does each factor individually. Moreover, the interactions between pair factors of pollution sources are the strongest. (4) The risk detector analysis reveals that elevation and precipitation are negatively correlated with air pollution, whereas pollution and urbanization factors are positively correlated with air pollution. (5) Finally, two leading impact areas for atmospheric pollution, namely, the Yangtze River Delta urban agglomeration and the Wuhan metropolitan area are predominantly attributed to the combination of natural and urbanization factors, whereas Yunnan and Guizhou are the least impact areas for atmospheric pollution because of their topographical and meteorological factors.
•The relations between air pollution and natural and economic factors are found.•The novel geographical detector method is applied in this study.•PM2.5 factor has the biggest q value, implying the primary pollutant.•Interaction of factors plays a more important role in affecting air pollution.
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GEOZS, IJS, IMTLJ, KILJ, KISLJ, NLZOH, NUK, OILJ, PNG, SAZU, SBCE, SBJE, UILJ, UL, UM, UPCLJ, UPUK, ZAGLJ, ZRSKP
Automatic modulation classification (AMC) is an essential part in a cognitive radio receiver. Benefited from the discriminative constellation characteristics among most modulations, AMC methods based ...on constellation diagrams usually achieve pleasant performance. However, in noncooperation communication systems, constellation diagrams expressing modulations explicitly are difficult to obtain via blind symbol timing synchronization, especially in complicated wireless channels. Therefore, this article proposes a novel constellation diagram-based AMC architecture called attentive Siamese networks (ASNs) by considering multitiming constellation diagrams (MCDs) and selecting the proper symbol timings at the feature level, which is a more robust way than the conventional signal-level symbol timing synchronization. In detail, convolutional neural networks sharing the same parameters first extract deep feature vectors for MCDs. Then, an attention inference module weights all the deep feature vectors. Finally, AMC is realized based on the weighted feature vectors. Moreover, the ASN architecture can be trained end-to-end. Comparing with the state-of-the-art methods that take diverse representations of received baseband signals as input, experimental results based on the RadioML 2018.01A dataset and non-Gaussian noise dataset demonstrate that ASN achieves a remarkable improvement, whose classification accuracy goes over 99% when the signal-to-noise ratio (SNR) > 10 dB.
The lithium (Li)–air battery has an ultrahigh theoretical specific energy, however, even in pure oxygen (O2), the vulnerability of conventional organic electrolytes and carbon cathodes towards ...reaction intermediates, especially O2−, and corrosive oxidation and crack/pulverization of Li metal anode lead to poor cycling stability of the Li‐air battery. Even worse, the water and/or CO2 in air bring parasitic reactions and safety issues. Therefore, applying such systems in open‐air environment is challenging. Herein, contrary to previous assertions, we have found that CO2 can improve the stability of both anode and electrolyte, and a high‐performance rechargeable Li–O2/CO2 battery is developed. The CO2 not only facilitates the in situ formation of a passivated protective Li2CO3 film on the Li anode, but also restrains side reactions involving electrolyte and cathode by capturing O2−. Moreover, the Pd/CNT catalyst in the cathode can extend the battery lifespan by effectively tuning the product morphology and catalyzing the decomposition of Li2CO3. The Li–O2/CO2 battery achieves a full discharge capacity of 6628 mAh g−1 and a long life of 715 cycles, which is even better than those of pure Li–O2 batteries.
CO2 can do: CO2 makes Li–O2 batteries more stable. On the anode side, CO2 can facilitate the formation of a protective and self‐healing Li2CO3 film, which can expel the H2O and aggressive intermediates during cycling. The cathode and electrolyte are also protected because the O2− intermediate is captured by CO2 to prevent the formation of 1O2.
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BFBNIB, FZAB, GIS, IJS, KILJ, NLZOH, NUK, OILJ, SBCE, SBMB, UL, UM, UPUK
Metal organic frameworks (MOFs) have drawn wide attention as potential catalysts, offering high densities of catalytic sites in high-area porous solids, some with stabilities at high temperatures. ...The field is at an early stage, characterized by numerous discoveries and novel demonstrations of catalytic properties associated with the crystalline structures of MOFs, but applications of MOFs as catalysts are still lacking. In this perspective we summarize advantages and limitations of MOFs as catalysts and fundamental issues to be addressed about their potential applications. MOF framework compositions and pore structures can strongly influence catalytic performance, allowing, for example, shape-selective and bifunctional catalysis, but research is needed to quantify reaction/transport processes in MOFs, identify catalytic sites, and determine intrinsic catalytic reaction rates. Progress is hindered by the lack of understanding of the heterogeneity of MOFs, with catalytic sites sometimes being in structures such as defects not determined by X-ray diffraction crystallography. Determination of the dynamics of MOFs and their catalytic sites, as well as the intrinsic kinetics of catalytic reactions, will help to advance guidelines for synthesizing optimum catalysts. Further, MOFs present challenges related to stability and regeneration as catalysts, some associated with the unique nature of MOFs, such as the node–linker bonds, which can break during catalysis. There are opportunities to understand these matters in depth and to find conditions of catalytic operation that minimize the processes leading to deactivation.
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IJS, KILJ, NUK, PNG, UL, UM
Porous organic polymers (POPs) composed of organic building units linked
via
covalent bonds are a class of lightweight porous network materials with high surface areas, tuneable pores, and designable ...components and structures. Owing to their well-preserved characteristics in terms of structure and composition, POPs applied as electrocatalysts have shown promising activity and achieved considerable advances in numerous electrocatalytic reactions, including the hydrogen evolution reaction, oxygen evolution reaction, oxygen reduction reaction, CO
2
reduction reaction, N
2
reduction reaction, nitrate/nitrite reduction reaction, nitrobenzene reduction reaction, hydrogen oxidation reaction, and benzyl alcohol oxidation reaction. Herein, we present a systematic overview of recent advances in the applications of POPs in these electrocatalytic reactions. The synthesis strategies, specific active sites, and catalytic mechanisms of POPs are summarized in this review. The fundamental principles of some electrocatalytic reactions are also concluded. We further discuss the current challenges of and perspectives on POPs for electrocatalytic applications. Meanwhile, the possible future directions are highlighted to afford guidelines for the development of efficient POP electrocatalysts.
The application of porous organic polymers in various electrocatalytic reactions has been systematically summarized.
Propane dehydrogenation (PDH) has great potential to meet the increasing global demand for propylene, but the widely used Pt‐based catalysts usually suffer from short‐term stability and ...unsatisfactory propylene selectivity. Herein, we develop a ligand‐protected direct hydrogen reduction method for encapsulating subnanometer bimetallic Pt–Zn clusters inside silicalite‐1 (S‐1) zeolite. The introduction of Zn species significantly improved the stability of the Pt clusters and gave a superhigh propylene selectivity of 99.3 % with a weight hourly space velocity (WHSV) of 3.6–54 h−1 and specific activity of propylene formation of 65.5 molC3H6
gPt−1 h−1 (WHSV=108 h−1) at 550 °C. Moreover, no obvious deactivation was observed over PtZn4@S‐1‐H catalyst even after 13000 min on stream (WHSV=3.6 h−1), affording an extremely low deactivation constant of 0.001 h−1, which is 200 times lower than that of the PtZn4/Al2O3 counterpart under the same conditions. We also show that the introduction of Cs+ ions into the zeolite can improve the regeneration stability of catalysts, and the catalytic activity kept unchanged after four continuous cycles.
A lean, mean, propylene machine: Subnanometer bimetallic Pt–Zn clusters are encapsulated inside silicalite‐1 (S‐1) zeolite via a ligand‐protected direct hydrogen reduction method. In the propane dehydrogenation (PDH) reaction, the PtZn4@S‐1‐H catalyst exhibited a very high propylene selectivity of 99.3 % and specific activity of propylene formation of 65.5 molC3H6
gPt−1 h−1 at 550 °C. Moreover, no obvious deactivation was observed over catalyst even after 13000 min on stream.
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BFBNIB, FZAB, GIS, IJS, KILJ, NLZOH, NUK, OILJ, SBCE, SBMB, UL, UM, UPUK
Non-invasive visualization of dynamic molecular events in real-time via molecular imaging may enable the monitoring of cascade catalytic reactions in living systems, however effective imaging ...modalities and a robust catalytic reaction system are lacking. Here we utilize three-dimensional (3D) multispectral photoacoustic (PA) molecular imaging to monitor in vivo cascade catalytic therapy based on a dual enzyme-driven cyclic reaction platform. The system consists of a two-dimensional (2D) Pd-based nanozyme conjugated with glucose oxidase (GOx). The combination of nanozyme and GOx can induce the PA signal variation of endogenous molecules. Combined with the PA response of the nanozyme, we can simultaneously map the 3D PA signals of dynamic endogenous and exogenous molecules associated with the catalytic process, thus providing a real-time non-invasive visualization. We can also treat tumors under the navigation of the PA imaging. Therefore, our study demonstrates the imaging-guided potential of 3D multispectral PA imaging in feedback-looped cascade catalytic therapy.
Designing high-performance and cost-effective electrocatalysts toward oxygen evolution and hydrogen evolution reactions in water-alkali electrolyzers is pivotal for large-scale and sustainable ...hydrogen production. Earth-abundant transition metal oxide-based catalysts are particularly active for oxygen evolution reaction; however, they are generally considered inactive toward hydrogen evolution reaction. Here, we show that strain engineering of the outermost surface of cobalt(II) oxide nanorods can turn them into efficient electrocatalysts for the hydrogen evolution reaction. They are competitive with the best electrocatalysts for this reaction in alkaline media so far. Our theoretical and experimental results demonstrate that the tensile strain strongly couples the atomic, electronic structure properties and the activity of the cobalt(II) oxide surface, which results in the creation of a large quantity of oxygen vacancies that facilitate water dissociation, and fine tunes the electronic structure to weaken hydrogen adsorption toward the optimum region.
To construct a long noncoding RNA (lncRNA)–microRNA (miRNA)–messenger RNA (mRNA) regulatory network related to epithelial ovarian cancer (EOC) cisplatin‐resistant, differentially expressed genes ...(DEGs), differentially expressed lncRNAs (DELs), and differentially expressed miRNAs (DEMs) between MDAH and TOV‐112D cells lines were identified. Gene Ontology (GO) analysis and Kyoto Encyclopedia of Genes and Genomes (KEGG) pathway analysis were conducted to analyze the biological functions of DEGs. Downstream mRNAs or upstream lncRNAs for miRNAs were analyzed at miRTarBase 7.0 or DIANA‐LncBase V2, respectively. A total of 485 significant DEGs, 85 DELs, and 5 DEMs were identified. Protein–protein interaction (PPI) network of DEGs contrains 81 nodes and 141 edges was constructed, and 25 hub genes related to EOC cisplatin‐resistant were identified. Subsequently, a lncRNA–miRNA–mRNA regulatory network contains 4 lncRNAs, 4 miRNAs, and 35 mRNAs was established. Taken together, our study provided evidence concerning the alteration genes involved in EOC cisplatin‐resistant, which will help to unravel the mechanisms underlying drug resistant.
1.
A long noncoding RNA–microRNA–messenger RNA network related to epithelial ovarian cancer (EOC) cisplatin‐resistant was established.
2.
Genes involved in EOC cisplatin‐resistant were identified.
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BFBNIB, FZAB, GIS, IJS, KILJ, NLZOH, NUK, OILJ, SBCE, SBMB, UL, UM, UPUK
Flexible metal–organic frameworks (MOFs) receive much attention owing to their attractive properties that originate from their flexibility and dynamic behavior, and show great potential applications ...in many fields. Here, recent progress in the discovery, understanding, and property investigations of flexible MOFs are reviewed, and the examples of their potential applications in storage and separation, sensing, and guest capture and release are presented to highlight the developing trends in flexible MOFs.
Flexible metal–organic frameworks are widely investigated as functional materials based on their remarkable properties, and potential applications of these materials are found in many fields. The most recent advances in the discovery, understanding and property investigations are reviewed, and new trends for their applications are highlighted.
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BFBNIB, FZAB, GIS, IJS, KILJ, NLZOH, NUK, OILJ, SBCE, SBMB, UL, UM, UPUK
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