Increased portability, versatility and ubiquity of electronics devices are a result of their progressive miniaturization, requiring current flow through narrow channels. Present-day devices operate ...close to the maximum current-carrying-capacity (that is, ampacity) of conductors (such as copper and gold), leading to decreased lifetime and performance, creating demand for new conductors with higher ampacity. Ampacity represents the maximum current-carrying capacity of the object that depends both on the structure and material. Here we report a carbon nanotube-copper composite exhibiting similar conductivity (2.3-4.7 × 10(5) S cm(-1)) as copper (5.8 × 10(5) S cm(-1)), but with a 100-times higher ampacity (6 × 10(8) A cm(-2)). Vacuum experiments demonstrate that carbon nanotubes suppress the primary failure pathways in copper as observed by the increased copper diffusion activation energy (~2.0 eV) in carbon nanotube-copper composite, explaining its higher ampacity. This is the only material with both high conductivity and high ampacity, making it uniquely suited for applications in microscale electronics and inverters.
By using long single-walled carbon nanotubes (SWNTs) as a filler possessing the highest aspect ratio and small diameter, we mimicked the chain structure of polymers in the matrix and realized a ...highly conductive elastomeric composite (30 S/cm) with an excellent mechanical durability (4500 strain cycles until failure), far superior to any other reported conductive elastomers. This exceptional mechanical durability was explained by the ability of long and traversing SWNTs to deform in concert with the elastomer with minimum stress concentration at their interfaces. The conductivity was sufficient to operate many active electronics components, and thus this material would be useful for practical stretchable electronic devices.
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Alignment represents an important structural parameter of carbon nanotubes (CNTs) owing to their exceptionally high aspect ratio, one-dimensional property. In this paper, we demonstrate a general ...approach to control the alignment of few-walled CNT forests from nearly random to nearly ideally aligned by tailoring the density of active catalysts at the catalyst formation stage, which can be experimentally achieved by controlling the CNT forest mass density. Experimentally, we found that the catalyst density and the degree of alignment were inseparably linked because of a crowding effect from neighboring CNTs, that is, the increasing confinement of CNTs with increased density. Therefore, the CNT density governed the degree of alignment, which increased monotonically with the density. This relationship, in turn, allowed the precise control of the alignment through control of the mass density. To understand this behavior further, we developed a simple, first-order model based on the flexural modulus of the CNTs that could quantitatively describe the relationship between the degree of alignment (HOF) and carbon nanotube spacing (crowding effect) of any type of CNTs.
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Among all known materials, we found that a forest of vertically aligned single-walled carbon nanotubes behaves most similarly to a black body, a theoretical material that absorbs all incident light. ...A requirement for an object to behave as a black body is to perfectly absorb light of all wavelengths. This important feature has not been observed for real materials because materials intrinsically have specific absorption bands because of their structure and composition. We found a material that can absorb light almost perfectly across a very wide spectral range (0.2-200 μm). We attribute this black body behavior to stem from the sparseness and imperfect alignment of the vertical single-walled carbon nanotubes.
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We demonstrate the efficient chemical vapor deposition synthesis of single-walled carbon nanotubes where the activity and lifetime of the catalysts are enhanced by water. Water-stimulated enhanced ...catalytic activity results in massive growth of superdense and vertically aligned nanotube forests with heights up to 2.5 millimeters that can be easily separated from the catalysts, providing nanotube material with carbon purity above 99.98%. Moreover, patterned, highly organized intrinsic nanotube structures were successfully fabricated. The water-assisted synthesis method addresses many critical problems that currently plague carbon nanotube synthesis.
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We report the interplay between the carbon nanotube (CNT) structure (wall number and diameter) and assembly structure (packing density) on the electrical conductivity of CNT thin films. By ...controlling the CNT average wall number from 1.0 to 5.5 (and inevitably changing of the diameter from 3.0 to 8.7nm), the electrical conductivity of CNT films showed a unique and unexpected phenomenon, i.e. peaking for films made from an average wall number of ∼2.7 that was ∼3-times higher than that from single-walled CNTs and ∼1.6-times higher than that from 5.5-walled CNTs. By developing a first-order model, the individual contributions of individual CNT structure and assembly structure were estimated, and we found that the peak arose from offsetting factors: increase in the effective CNT electrical conductivity and decrease in the packing density with increased wall number. The synergetic effect between the CNT structure and the assembly structure would provide a scientific framework to deeply understand CNT assemblies.
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GEOZS, IJS, IMTLJ, KILJ, KISLJ, NUK, OILJ, PNG, SAZU, SBCE, SBJE, UL, UM, UPUK
We report the highly efficient synthesis of sub-2-nm diameter single-walled carbon nanotube (SWCNT) forests with homogenous and controllable diameter (1.5–2.8 nm), millimeter-scale height, and ...extremely high purity. This control was achieved by combining a previously reported sandwich catalyst (Al/Fe/Al) with an atmospheric synthesis process and the water-assisted thermal chemical vapor deposition method. In this way, a dense array of small and stable catalyst nanoparticles, suitable to support vertical growth, while avoiding gas diffusion limitations, could be prepared from which SWCNT forests could be synthesized efficiently to achieve both high purity and mm-scale height. The mm-tall sub-2-nm diameter SWCNT forests showed good quality (Raman G/D ratio of ∼40) and exceptionally high as-grown purity (outer specific surface area of 1215 m2/g; ideal: 1315 m2/g), which can be directly used without additional post-growth purification process to avoid any potential damage to the CNTs. This result represents a significant advance in synthesizing highly pure, mm-scale length SWCNT forests with sub-2-nm diameters.
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GEOZS, IJS, IMTLJ, KILJ, KISLJ, NUK, OILJ, PNG, SAZU, SBCE, SBJE, UL, UM, UPUK
We have succeeded in synthesizing vertically aligned doubled-walled carbon nanotube (DWNT) forests with heights of up to 2.2 mm by water-assisted chemical vapour deposition (CVD). We achieved 85% ...selectivity of DWNTs through a semi-empirical analysis of the relationships between the tube type and mean diameter and between the mean diameter and the film thickness of sputtered Fe, which was used here as a catalyst. Accordingly, catalysts were engineered for optimum DWNT selectivity by precisely controlling the Fe film thickness. The high efficiency of water-assisted CVD enabled the synthesis of nearly catalyst-free DWNT forests with a carbon purity of 99.95%, which could be templated into organized structures from lithographically patterned catalyst islands.
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We report an approach to fabricate high conductivity graphite sheets based on a heat-and-current treatment of filtrated, exfoliated graphite flakes. This treatment combines heating (~ 900 °C) and ...in-plane electrical current flow (550 A·cm
−2
) to improve electrical conductivity through the reduction of crystalline defects. This process was shown to require only a 1-min treatment time, which resulted in a 2.1-fold increase in electrical conductivity (from 1088 ± 72 to 2275 ± 50 S·cm
−1
). Structural characterization by Raman spectroscopy and X-ray diffraction indicated that the improvement electrical conductivity originated from a 30-fold improvement in the crystallinity (Raman G/D ratio increase from 2.8 to 85.3) with no other observable structural transformations. Significantly, this treatment was found to act uniformly across a macroscopic (10 mm) sheet surface indicating it is on the development of applications, such as electrodes for energy generation and storage and electromagnetic shielding, as well as on the potential for the development of large-scale treatment technologies.
A novel approach for selective diameter control of single-walled carbon nanotubes (SWNTs) is performed in the gas-phase growth using two kinds of carbon sources with different decomposition ...properties; the one carbon source (1st carbon source) is the organic solvent which is difficult to decompose in the reactor and the another carbon source (2nd carbon source) is facile to decompose. The diameter distributions of SWNTs synthesized with various conditions of the flow rate of the 2nd carbon source were investigated by resonant Raman scattering, optical absorption, and photoluminescence (PL) mapping measurements. It was found that increasing the flow rate of the ethylene tends to decrease the diameter of synthesized SWNTs, probably due to the earlier nucleation of SWNTs induced by the ethylene addition. The controlling the flow rate of the ethylene used as a 2nd carbon source can selectively tune the diameter distribution of SWNTs in our growth system.