Controlled transport of water molecules through membranes and capillaries is important in areas as diverse as water purification and healthcare technologies
. Previous attempts to control water ...permeation through membranes (mainly polymeric ones) have concentrated on modulating the structure of the membrane and the physicochemical properties of its surface by varying the pH, temperature or ionic strength
. Electrical control over water transport is an attractive alternative; however, theory and simulations
have often yielded conflicting results, from freezing of water molecules to melting of ice
under an applied electric field. Here we report electrically controlled water permeation through micrometre-thick graphene oxide membranes
. Such membranes have previously been shown to exhibit ultrafast permeation of water
and molecular sieving properties
, with the potential for industrial-scale production. To achieve electrical control over water permeation, we create conductive filaments in the graphene oxide membranes via controllable electrical breakdown. The electric field that concentrates around these current-carrying filaments ionizes water molecules inside graphene capillaries within the graphene oxide membranes, which impedes water transport. We thus demonstrate precise control of water permeation, from ultrafast permeation to complete blocking. Our work opens up an avenue for developing smart membrane technologies for artificial biological systems, tissue engineering and filtration.
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KISLJ, NUK, SBMB, UL, UM, UPUK
Manipulating the surface energy, and thereby the wetting properties of solids, has promise for various physical, chemical, biological and industrial processes. Typically, this is achieved by either ...chemical modification or by controlling the hierarchical structures of surfaces. Here we report a phenomenon whereby the wetting properties of vermiculite laminates are controlled by the hydrated cations on the surface and in the interlamellar space. We find that vermiculite laminates can be tuned from superhydrophilic to hydrophobic simply by exchanging the cations; hydrophilicity decreases with increasing cation hydration free energy, except for lithium. The lithium-exchanged vermiculite laminate is found to provide a superhydrophilic surface due to its anomalous hydrated structure at the vermiculite surface. Building on these findings, we demonstrate the potential application of superhydrophilic lithium exchanged vermiculite as a thin coating layer on microfiltration membranes to resist fouling, and thus, we address a major challenge for oil-water separation technology.
Vegetation water content is one of the important biophysical features of vegetation health, and its remote estimation can be utilized to real-timely monitor vegetation water stress. Here, we compared ...the responses of canopy water content (CWC), leaf equivalent water thickness (EWT), and live fuel moisture content (LFMC) to different water treatments and their estimations using spectral vegetation indices (VIs) based on water stress experiments for summer maize during three consecutive growing seasons 2013-2015 in North Plain China.
Results showed that CWC was sensitive to different water treatments and exhibited an obvious single-peak seasonal variation. EWT and LFMC were less sensitive to water variation and EWT stayed relatively stable while LFMC showed a decreasing trend. Among ten hyperspectral VIs, green chlorophyll index (CI
), red edge normalized ratio (NR
), and red-edge chlorophyll index (CI
) were the most sensitive VIs responding to water variation, and they were optimal VIs in the prediction of CWC and EWT.
Compared to EWT and LFMC, CWC obtained the best predictive power of crop water status using VIs. This study demonstrated that CWC was an optimal indicator to monitor maize water stress using optical hyperspectral remote sensing techniques.
Let
H
H
be a pointed Hopf algebra with abelian coradical. Let
A
⊇
B
A\supseteq B
be left (or right) coideal subalgebras of
H
H
that contain the coradical of
H
H
. We show that
A
A
has a PBW basis ...over
B
B
, provided that
H
H
satisfies certain mild conditions. In the case that
H
H
is a connected graded Hopf algebra of characteristic zero and
A
A
and
B
B
are both homogeneous of finite Gelfand-Kirillov dimension, we show that
A
A
is a graded iterated Ore extension of
B
B
. These results turn out to be conceptual consequences of a structure theorem for each pair
S
⊇
T
S\supseteq T
of homogeneous coideal subalgebras of a connected graded braided bialgebra
R
R
with braiding satisfying certain mild conditions. The structure theorem claims the existence of a well-behaved PBW basis of
S
S
over
T
T
. The approach to the structure theorem is constructive by means of a combinatorial method based on Lyndon words and braided commutators, which is originally developed by V. K. Kharchenko Algebra Log. 38 (1999), pp. 476–507, 509 for primitively generated braided Hopf algebras of diagonal type. Since in our context we don’t priorilly assume
R
R
to be primitively generated, new methods and ideas are introduced to handle the corresponding difficulties, among others.
The gastrointestinal (GI) microbiota of vertebrates plays critical roles in nutrition, development, immunity and resistance against invasive pathogens. In the past decade, research of the GI ...microbiota of mammals has drastically increased our knowledge on the microbiota and their relationship with health and disease. However, our understanding of fish intestinal microbiota is limited. This review provides an overview of research on fish gut microbiota, including microbial composition, formation, factors that affect the GI microbes and characteristics of fish intestinal microbiota compared with human and mice. Further, the updated research on gnotobiotic zebrafish is elaborated and the insights gained on functions of the fish intestinal microbiota are discussed. Understanding the intestinal microbiota of fish will guide the development of probiotics, prebiotics and hopefully probiotic effectors as novel additives to improve the health of fish.
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FZAB, GIS, IJS, KILJ, NLZOH, NUK, OILJ, SBCE, SBMB, UL, UM, UPUK
Fresh meat is a highly perishable product due to its biological composition. Many interrelated factors influence the shelf life and freshness of meat such as holding temperature, atmospheric oxygen ...(O
2), endogenous enzymes, moisture, light and most importantly, micro-organisms. With the increased demand for high quality, convenience, safety, fresh appearance and an extended shelf life in fresh meat products, alternative non-thermal preservation technologies such as high hydrostatic pressure, superchilling, natural biopreservatives and active packaging have been proposed and investigated. Whilst some of these technologies are efficient at inactivating the micro-organisms most commonly related to food-borne diseases, they are not effective against spores. To increase their efficacy against vegetative cells, a combination of several preservation technologies under the so-called hurdle concept has also been investigated. The objective of this review is to describe current methods and developing technologies for preserving fresh meat. The benefits of some new technologies and their industrial limitations is presented and discussed.
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GEOZS, IJS, IMTLJ, KILJ, KISLJ, NUK, OILJ, PNG, SAZU, SBCE, SBJE, UL, UM, UPCLJ, UPUK
Increased concentrations of atmospheric greenhouse gases have led to a global mean surface temperature 1.0°C higher than during the pre-industrial period. We expand on the recent IPCC Special Report ...on global warming of 1.5°C and review the additional risks associated with higher levels of warming, each having major implications for multiple geographies, climates, and ecosystems. Limiting warming to 1.5°C rather than 2.0°C would be required to maintain substantial proportions of ecosystems and would have clear benefits for human health and economies. These conclusions are relevant for people everywhere, particularly in low- and middle-income countries, where the escalation of climate-related risks may prevent the achievement of the United Nations Sustainable Development Goals.
A
bstract
We investigate neutrinoless double beta decay (0
νββ
) in the presence of sterile neutrinos with Majorana mass terms. These gauge-singlet fields are allowed to interact with Standard-Model ...(SM) fields via renormalizable Yukawa couplings as well as higher-dimensional gauge-invariant operators up to dimension seven in the Standard Model Effective Field Theory extended with sterile neutrinos. At the GeV scale, we use Chiral effective field theory involving sterile neutrinos to connect the operators at the level of quarks and gluons to hadronic interactions involving pions and nucleons. This allows us to derive an expression for 0
νββ
rates for various isotopes in terms of phase-space factors, hadronic low-energy constants, nuclear matrix elements, the neutrino masses, and the Wilson coefficients of higher-dimensional operators. The required hadronic low-energy constants and nuclear matrix elements depend on the neutrino masses, for which we obtain interpolation formulae grounded in QCD and chiral perturbation theory that improve existing formulae that are only valid in a small regime of neutrino masses. The resulting framework can be used directly to assess the impact of 0
νββ
experiments on scenarios with light sterile neutrinos and should prove useful in global analyses of sterile-neutrino searches. We per- form several phenomenological studies of 0
νββ
in the presence of sterile neutrinos with and without higher-dimensional operators. We find that non-standard interactions involving sterile neutrinos have a dramatic impact on 0
νββ
phenomenology, and next-generation experiments can probe such interactions up to scales of
O
(100) TeV.
Superhydrophobic coatings have tremendous potential for applications in different fields and have been achieved commonly by increasing nanoscale roughness and lowering surface tension. Limited by the ...availability of either ideal nano-structural templates or simple fabrication procedures, the search of superhydrophobic coatings that are easy to manufacture and are robust in real-life applications remains challenging for both academia and industry. Herein, we report an unconventional protocol based on a single-step, stoichiometrically controlled reaction of long-chain organosilanes with water, which creates micro- to nano-scale hierarchical siloxane aggregates dispersible in industrial solvents (as the coating mixture). Excellent superhydrophobicity (ultrahigh water contact angle >170° and ultralow sliding angle <1°) has been attained on solid materials of various compositions and dimensions, by simply dipping into or spraying with the coating mixture. It has been demonstrated that these complete waterproof coatings hold excellent properties in terms of cost, scalability, robustness, and particularly the capability of encapsulating other functional materials (e.g. luminescent dyes).
Flexible barriers undergo large deformation to extend the impact duration, and thereby reduce the impact load of geophysical flows. The performance of flexible barriers remains a crucial challenge ...because there currently lacks a comprehensive criterion for estimating impact load. In this study, a series of centrifuge tests were carried out to investigate different geophysical flow types impacting an instrumented flexible barrier. The geophysical flows modelled include covered in this study include flood, hyperconcentrated flow, debris flow, and dry debris avalanche. Results reveal that the relationship between the Froude number,
Fr
, and the pressure coefficient
α
strongly depends on the formation of static deposits called dead zones which induce static loads and whether a run-up or pile-up impact mechanism develops. Test results demonstrate that flexible barriers can attenuate peak impact loads of flood, hyperconcentrated flow, and debris flow by up to 50% compared to rigid barriers. Furthermore, flexible barriers attenuate the impact load of dry debris avalanche by enabling the dry debris to reach an active failure state through large deformation. Examination of the state of static debris deposits behind the barriers indicates that hyperconcentrated and debris flows are strongly influenced by whether excessive pore water pressures regulate the depositional process of particles during the impact process. This results in significant particle rearrangement and similar state of static debris behind rigid barrier and the deformed full-retention flexible barrier, and thus the static loads on both barriers converge.
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