Developing high‐efficiency and affordable electrocatalysts for the sluggish oxygen evolution reaction (OER) remains a crucial bottleneck on the way to the practical applications of rechargeable ...energy storage technologies and water splitting for producing clean fuel (H2). In recent years, NiFe‐based materials have proven to be excellent electrocatalysts for OER. Understanding the characteristics that affect OER activity and determining the OER mechanism are of vital importance for the development of OER electrocatalysts. Therefore, in situ characterization techniques performed under OER conditions are urgently needed to monitor the key intermediates together with identifying the OER active centers and phases. In this Minireview, recent advances regarding in situ techniques for the characterization of NiFe‐based electrocatalysts are thoroughly summarized, including Raman spectroscopy, X‐ray absorption spectroscopy, ambient pressure X‐ray photoelectron spectroscopy, Mössbauer spectroscopy, Ultraviolet–visible spectroscopy, differential electrochemical mass spectrometry, and surface interrogation scanning electrochemical microscopy. The results from these in situ measurements not only reveal the structural transformation and the progressive oxidation of the catalytic species under OER conditions, but also disclose the crucial role of Ni and Fe during the OER. Finally, the need for developing new in situ techniques and theoretical investigations is discussed to better understand the OER mechanism and design promising OER electrocatalysts.
What happens to the catalyst? NiFe‐based electrocatalysts undergo a structural transformation and progressive oxidation during the oxygen evolution reaction (OER). Recent advances regarding in situ techniques for the characterization of NiFe‐based electrocatalysts are summarized in this Minireview.
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BFBNIB, FZAB, GIS, IJS, KILJ, NLZOH, NUK, OILJ, SBCE, SBMB, UL, UM, UPUK
We investigate the topological skin effect in a ring resonator array which can be mapped into the square root of a Su-Schrieffer-Heeger (SSH) model with non-Hermitian asymmetric coupling. The ...asymmetric coupling is realized by integrating the same amount of gain and loss into the two half perimeters of linking rings that effectively couple two adjacent site rings. Such a square-root topological insulator inherits the properties from its parent Hamiltonian, which has the same phase transition points and exhibits non-Bloch features as well. We show the band closing points for open chain are different from that of periodic chain as a result of the skin effect. Moreover, the square-root insulator supports multiple topological edge modes as the number of band gaps is doubled compared to the original Hamiltonian. The full-wave simulations agree well with the theoretical analyses based on a tight-binding model. The study provides a promising approach to investigate the skin effect by utilizing ring resonators and may find potential applications in light trapping, lasers, and filters.
We introduce here the concept of acoustic parity-time (PT ) symmetry and demonstrate the extraordinary scattering characteristics of the acoustic PT medium. On the basis of exact calculations, we ...show how an acoustic PT -symmetric medium can become unidirectionally transparent at given frequencies. Combining such a PT -symmetric medium with transformation acoustics, we design two-dimensional symmetric acoustic cloaks that are unidirectionally invisible in a prescribed direction. Our results open new possibilities for designing functional acoustic devices with directional responses.
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CMK, CTK, FMFMET, IJS, NUK, PNG, UL, UM, UPUK
The ability to slow down wave propagation in materials has attracted significant research interest. A successful solution will give rise to manageable enhanced wave-matter interaction, freewheeling ...phase engineering and spatial compression of wave signals. The existing methods are typically associated with constructing dispersive materials or structures with local resonators, thus resulting in unavoidable distortion of waveforms. Here we show that, with helical-structured acoustic metamaterials, it is now possible to implement dispersion-free sound deceleration. The helical-structured metamaterials present a non-dispersive high effective refractive index that is tunable through adjusting the helicity of structures, while the wavefront revolution plays a dominant role in reducing the group velocity. Finally, we numerically and experimentally demonstrate that the helical-structured metamaterials with designed inhomogeneous unit cells can turn a normally incident plane wave into a self-accelerating beam on the prescribed parabolic trajectory. The helical-structured metamaterials will have profound impact to applications in explorations of slow wave physics.
Fabricating microscale helical structures from small molecules remains challenging due to the disfavoured torsion energy of twisted architectures and elusory chirality control at different ...hierarchical levels of assemblies. Here we report a combined solution-interface-directed assembly strategy for the formation of hierarchically self-assembled helical microtoroids with micrometre-scale lengths. A drop-evaporation assembly protocol on a solid substrate from pre-assembled intermediate colloids of enantiomeric binaphthalene bisurea compounds leads to microtoroids with preferred helicity, which depends on the molecular chirality of the starting enantiomers. Collective variable-temperature spectroscopic analyses, electron microscopy characterizations and theoretical simulations reveal a mechanism that simultaneously induces aggregation and cyclization to impart a favourable handedness to the final microtoroidal structures. We then use monodispersed luminescent helical toroids as chiral light-harvesting antenna and show excellent Förster resonance energy transfer ability to a co-hosted chiral acceptor dye, leading to unique circularly polarized luminescence. Our results shed light on the potential of the combined solution-interface-directed self-assembly approach in directing hierarchical chirality control and may advance the prospect of chiral superstructures at a higher length scale.
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EMUNI, FIS, FZAB, GEOZS, GIS, IJS, IMTLJ, KILJ, KISLJ, MFDPS, NLZOH, NUK, OILJ, PNG, SAZU, SBCE, SBJE, SBMB, SBNM, UKNU, UL, UM, UPUK, VKSCE, ZAGLJ
The fine manipulation of sound fields is critical in acoustics yet is restricted by the coupled amplitude and phase modulations in existing wave-steering metamaterials. Commonly, unavoidable losses ...make it difficult to control coupling, thereby limiting device performance. Here we show the possibility of tailoring the loss in metamaterials to realize fine control of sound in three-dimensional (3D) space. Quantitative studies on the parameter dependence of reflection amplitude and phase identify quasi-decoupled points in the structural parameter space, allowing arbitrary amplitude-phase combinations for reflected sound. We further demonstrate the significance of our approach for sound manipulation by producing self-bending beams, multifocal focusing, and a single-plane two-dimensional hologram, as well as a multi-plane 3D hologram with quality better than the previous phase-controlled approach. Our work provides a route for harnessing sound via engineering the loss, enabling promising device applications in acoustics and related fields.
Zero index materials where sound propagates without phase variation, holds a great potential for wavefront and dispersion engineering. Recently explored electromagnetic double zero index ...metamaterials consist of periodic scatterers whose refractive index is significantly larger than that of the surrounding medium. This requirement is fundamentally challenging for airborne acoustics because the sound speed (inversely proportional to the refractive index) in air is among the slowest. Here, we report the first experimental realization of an impedance matched acoustic double zero refractive index metamaterial induced by a Dirac-like cone at the Brillouin zone centre. This is achieved in a two-dimensional waveguide with periodically varying air channel that modulates the effective phase velocity of a high-order waveguide mode. Using such a zero-index medium, we demonstrated acoustic wave collimation emitted from a point source. For the first time, we experimentally confirm the existence of the Dirac-like cone at the Brillouin zone centre.
Three dimensional (3D) topology optimization problems always involve huge numbers of Degrees of Freedom (DOFs) in finite element analysis (FEA) and design variables in numerical optimization, ...respectively. This will inevitably lead to large computational efforts in the solution process. In the present paper, an efficient and explicit topology optimization approach which can reduce not only the number of design variables but also the number of degrees of freedom in FEA is proposed based on the Moving Morphable Voids (MMVs) solution framework. This is achieved by introducing a set of geometry parameters (e.g., control points of B-spline surfaces) to describe the boundary of a structure explicitly and removing the unnecessary DOFs from the FE model at every step of numerical optimization. Numerical examples demonstrate that the proposed approach does can overcome the bottleneck problems associated with a 3D topology optimization problem in a straightforward way and enhance the solution efficiency significantly.
•A new approach for topology optimization of 3D structures is proposed.•Both the numbers of degrees of freedom and design variables can be reduced substantially.•The bottleneck problems of 3D topology optimization have been well resolved by the proposed method.
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GEOZS, IJS, IMTLJ, KILJ, KISLJ, NUK, OILJ, PNG, SAZU, SBCE, SBJE, UL, UM, UPCLJ, UPUK, ZRSKP
Topological elastic metamaterials offer insight into classic motion law and open up opportunities in quantum and classic information processing. Theoretical modeling and numerical simulation of ...elastic topological states have been reported, whereas the experimental observation remains relatively unexplored. Here we present an experimental observation and numerical simulation of tunable topological states in soft elastic metamaterials. The on-demand reversible switch in topological phase has been achieved by changing filling ratio, tension, and/or compression of the elastic metamaterials. By combining two elastic metamaterials with distinct topological invariants, we further demonstrate the formation and dynamic tunability of topological interface states by mechanical deformation, and the manipulation of elastic wave propagation. Moreover, we provide a topological phase diagram of elastic metamaterials under deformation. Our approach to dynamically control interface states in soft materials paves the way to various phononic systems involving thermal management and soft robotics requiring better use of energy.
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