Review: Direct ethanol fuel cells Kamarudin, M.Z.F.; Kamarudin, S.K.; Masdar, M.S. ...
International journal of hydrogen energy,
07/2013, Volume:
38, Issue:
22
Journal Article, Conference Proceeding
Peer reviewed
Direct ethanol fuel cells have attracted much attention recently in the search for alternative energy resources. As an emerging technology, direct ethanol fuel cells have many challenges that need to ...be addressed. Many improvements have been made to increase the performance of direct ethanol fuel cells, and there are great expectations for their potential. However, many improvements need to be made in order to enhance the potential of direct ethanol fuel cells in the future. This paper addresses the challenges and the developments of direct ethanol fuel cells at present. It also presents the applications of DEFC.
► Direct ethanol fuel cells have attracted much attention recently. ► As an emerging technology, direct ethanol fuel cells have many challenges and improvements. ► This paper addresses the challenges and the developments of direct ethanol fuel cells at present. ► It also presents the application of DEFC.
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GEOZS, IJS, IMTLJ, KILJ, KISLJ, NUK, OILJ, PNG, SAZU, SBCE, SBJE, UL, UM, UPCLJ, UPUK
The increasing energy demand, surging oil prices, depleting oil reserves and environmental pollution problems associated with the use of fossil fuels have sparked renewed interest to find out clean ...alternative fuels. Alcohols such as methanol, ethanol and butanol are competitive alternative fuels due to their liquid nature, high oxygen contents, high octane number and their production from renewable biomass. In this review, the fuel properties of these alcohols are compared with conventional gasoline and diesel fuel. The comparison of fuel properties represents that butanol has the potential to overcome the problems associated with the use of methanol and ethanol. Progresses of their production from different sources are also introduced. Further, several techniques such as alcohol–diesel fuel blends and alcohol–diesel fuel emulsions are discussed, especially for lower alcohols, in order to use them in diesel engines. The effects of diesel–alcohol blends on the combustion, performance and emissions of diesel engines are also analyzed. It is examined that blending of alcohols, along with some CN improver, to diesel fuels can reduce diesel engine emissions without adverse impacts on the performance of diesel engines. These studies also reveal that butanol is a better alternative for diesel fuel due to its superior fuel properties and miscibility with diesel fuel than those of methanol and ethanol. Finally, some critical conclusions and future research directions are highlighted.
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GEOZS, IJS, IMTLJ, KILJ, KISLJ, NUK, OILJ, PNG, SAZU, SBCE, SBJE, UL, UM, UPCLJ, UPUK
Enhancing energy and environmental systems through sustainable development, in particular integrating concepts of circular economy and cleaner production are important for the emerging needs of ...humankind. In recent years, the developments in alternative sources of renewable energy counterparts has been prompted to substitute the nonrenewable fossil fuel consumptions towards clearner environment. However, environmental problems arising currently must be carefully addressed and to be solved to conserve the energy, water and other environmental resources for the future. This article highlights the recent developments on alternative energy sources that mainly focus on energy and environmental sustainability, that has been discussed on “The 4th International Conference on Alternative Fuels & Energy (ICAFE–2019)”, which was held at Taichung City, Taiwan on October 18–21, 2019. Additionally, it provides useful insights from some of the papers published on a virtual special issue (VSI) of the Bioresourse Technology Journal. The highlighted research works in this review can be used as route-map towards sustainable development and energy efficiency.
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GEOZS, IJS, IMTLJ, KILJ, KISLJ, NLZOH, NUK, OILJ, PNG, SAZU, SBCE, SBJE, UILJ, UL, UM, UPCLJ, UPUK, ZAGLJ, ZRSKP
•Certification issues severely limit decarbonisation routes for aviation.•Hydrogen and ammonia are most suitable for future shipping.•Barriers to electrification are lower for haulage.•Optimal ...solution for haulage is highly region specific.•Biofuels are most suited to retrofits and existing infrastructure.
The high environmental impacts of transport mean that there is an increasing interest in utilising low-carbon alternative energy carriers and powertrains within the sector. While electricity has been mooted as the energy carrier of choice for passenger vehicles, as the mass and range of the vehicle increases, electrification becomes more difficult. This paper reviews the shipping, aviation and haulage sectors, and a range of low-carbon energy carriers (electricity, biofuels, hydrogen, and electrofuels) that can be used to decarbonise them. Energy carriers were assessed based on their energy density, specific energy, cost, lifecycle greenhouse gas emissions, and land-use. In terms of haulage, current battery electric vehicles may be technically feasible, however the specific energy of current battery technology reduces the payload capacity and range when compared to diesel. To alleviate these issues, biomethane represents a mature technology with potential co-benefits, while hydrogen is close to competitiveness but requires significant infrastructure. Energy density issues preclude the use of batteries in shipping which requires energy dense liquids or compressed gaseous fuels that allow for retrofits/current hull designs, with methanol being particularly appropriate here. Future shipping may be achieved with ammonia or hydrogen, but hull design will need to be changed significantly. Regulations and aircraft design mean that commercial aviation is dependant on drop-in jet fuels for the foreseeable future, with power-to-liquid fuels being deemed the most suitable option due to the scales required. Fuel costs and a lack of refuelling infrastructure were identified as key barriers facing the uptake of alternatives, with policy and financial incentives required to encourage the uptake of low-carbon fuels.
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GEOZS, IJS, IMTLJ, KILJ, KISLJ, NLZOH, NUK, OILJ, PNG, SAZU, SBCE, SBJE, UILJ, UL, UM, UPCLJ, UPUK, ZAGLJ, ZRSKP
A new family of thiometalate-based composite molecular materials is synthesized and characterized. 1.6 and 1.9 nm-sized clusters are observed in the gas phase utilizing high-resolution ESI-MS. The ...diversity of the selenite anions as an inorganic ligand is demonstrated by the isolation of the highest nuclearity selenium-based oxothiometalate materials reported so far. The observed proton conductivity of the selenite based oxothiometalate species renders them as promising alternative materials for fuel-cell applications.
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BFBNIB, FZAB, GIS, IJS, KILJ, NLZOH, NUK, OILJ, SBCE, SBMB, UL, UM, UPUK
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•Liquid fuel was produced from plastic waste through catalytic pyrolysis.•Pyrolysis of polystyrene plastic produced highest liquid oil yield of 54% using natural zeolite.•Pyrolysis ...liquid oil mainly consisted of aromatic hydrocarbons with a few aliphatic compounds.•Primary compounds in liquid oil were styrene, ethylbenzene, benzene, azulene, and naphthalene.•Liquid oil had high heating values (HHV) of 40.2–45MJ/kg.
This study aims to examine the catalytic pyrolysis of various plastic wastes in the presence of natural and synthetic zeolite catalysts. A small pilot scale reactor was commissioned to carry out the catalytic pyrolysis of polystyrene (PS), polypropylene (PP), polyethylene (PE) and their mixtures in different ratios at 450°C and 75min. PS plastic waste resulted in the highest liquid oil yield of 54% using natural zeolite and 50% using synthetic zeolite catalysts. Mixing of PS with other plastic wastes lowered the liquid oil yield whereas all mixtures of PP and PE resulted in higher liquid oil yield than the individual plastic feedstocks using both catalysts. The GC–MS analysis revealed that the pyrolysis liquid oils from all samples mainly consisted of aromatic hydrocarbons with a few aliphatic hydrocarbon compounds. The types and amounts of different compounds present in liquid oils vary with some common compounds such as styrene, ethylbenzene, benzene, azulene, naphthalene, and toluene. The FT-IR data also confirmed that liquid oil contained mostly aromatic compounds with some alkanes, alkenes and small amounts of phenol group. The produced liquid oils have high heating values (HHV) of 40.2–45MJ/kg, which are similar to conventional diesel. The liquid oil has potential to be used as an alternative source of energy or fuel production.
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GEOZS, IJS, IMTLJ, KILJ, KISLJ, NUK, OILJ, PNG, SAZU, SBCE, SBJE, UL, UM, UPCLJ, UPUK, ZRSKP
17.
The future of oil supply Miller, Richard G.; Sorrell, Steven R.
Philosophical transactions of the Royal Society of London. Series A: Mathematical, physical, and engineering sciences,
01/2014, Volume:
372, Issue:
2006
Journal Article
Peer reviewed
Open access
Abundant supplies of oil form the foundation of modern industrial economies, but the capacity to maintain and grow global supply is attracting increasing concern. Some commentators forecast a peak in ...the near future and a subsequent terminal decline in global oil production, while others highlight the recent growth in 'tight oil' production and the scope for developing unconventional resources. There are disagreements over the size, cost and recoverability of different resources, the technical and economic potential of different technologies, the contribution of different factors to market trends and the economic implications of reduced supply. Few debates are more important, more contentious, more wide-ranging or more confused. This paper summarizes the main concepts, terms, issues and evidence that are necessary to understand the 'peak oil' debate. These include: the origin, nature and classification of oil resources; the trends in oil production and discoveries; the typical production profiles of oil fields, basins and producing regions; the mechanisms underlying those profiles; the extent of depletion of conventional oil; the risk of an approaching peak in global production; and the potential of various mitigation options. The aim is to introduce the subject to non-specialist readers and provide a basis for the subsequent papers in this Theme Issue.
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BFBNIB, NMLJ, NUK, PNG, SAZU, UL, UM, UPUK
► Various method for the production of biodiesel from vegetable oil were reviewed. ► Such as direct use and blending, microemulsion, pyrolysis and transesterification. ► The advantages and ...disadvantages of the different biodiesel-production methods are also discussed. ► Finally, the economics of biodiesel production was discussed using Malaysia as a case study.
The finite nature of fossil fuels necessitates consideration of alternative fuels from renewable sources. The term biofuel refers to liquid, gas and solid fuels predominantly produced from biomass. Biofuels include bioethanol, biomethanol, biodiesel and biohydrogen. Biodiesel, defined as the monoalkyl esters of vegetable oils or animal fats, is an attractive alternative fuel because it is environmentally friendly and can be synthesized from edible and non-edible oils. Here, we review the various methods for the production of biodiesel from vegetable oil, such as direct use and blending, microemulsion, pyrolysis and transesterification. The advantages and disadvantages of the different biodiesel-production methods are also discussed. Finally, we analyze the economics of biodiesel production using Malaysia as a case study.
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GEOZS, IJS, IMTLJ, KILJ, KISLJ, NUK, OILJ, PNG, SAZU, SBCE, SBJE, UL, UM, UPUK
This study is based on detailed data from 11 sea voyages over three years to determine the impact of liquefied natural gas (LNG) use on the decarbonization pathway in maritime transportation. The ...research detailed the vessel's daily fuel consumption, CO2 emission inventories, and Carbon Intensity Indicator (CII). The decision tree method used to evaluate this complex dataset highlights the possible contributions of LNG to maritime energy efficiency and sustainability. While the findings show that LNG reduces CO2 emissions by around 30 %, it is insufficient to meet the International Maritime Organization's (IMO) 2050 targets. The study concludes that LNG should be an important transition fuel until the mid-2030s. However, the maritime sector needs multi-pronged strategies such as technological innovations, stringent regulations and sectoral collaborations to achieve a decarbonized future. This research provides a comprehensive analysis assessing the potential of LNG to achieve the IMO 2050 targets in the context of maritime decarbonization strategies.
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•The decarbonization potential of LNG is analysed over 3-year voyages.•The decision tree methodology provides insight on the compatibility of LNG with IMO 2050 targets.•CII calculations underline a significant transition towards sustainable maritime energy.•The using of LNG provides a significant 30 % reduction in CO2 emissions.•The future of shipping depends on a variety of strategies covering multiple alternative fuels.
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GEOZS, IJS, IMTLJ, KILJ, KISLJ, NLZOH, NUK, OILJ, PNG, SAZU, SBCE, SBJE, UILJ, UL, UM, UPCLJ, UPUK, ZAGLJ, ZRSKP
Cement will remain the key material to satisfy global housing and modern infrastructure needs. As a consequence, the cement industry worldwide is facing growing challenges in conserving material and ...energy resources, as well as reducing its CO
2 emissions. According to the International Energy Agency, the main levers for cement producers are the increase in energy efficiency and the use of alternative materials, be it as fuel or raw materials. Accordingly, the use of alternative fuels has already increased significantly in recent years, but potential for further increases still exists. In cement, the reduction of the clinker factor remains a key priority: tremendous progress has already been made. Nevertheless, appropriate materials are limited in their regional availability. New materials might be able to play a role as cement constituents in the future. It remains to be seen to what extent they could substitute Portland cement clinker to a significant degree.
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GEOZS, IJS, IMTLJ, KILJ, KISLJ, NUK, OILJ, PNG, SAZU, SBCE, SBJE, UL, UM, UPCLJ, UPUK
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