Hybrid polyhipe materials : PhD thesis

(UL)

Hybrid polyhipe materials : PhD thesis

Kovačič, Sebastijan

Predmet mojega doktorskega dela je priprava novih poliHIPE materialov iz emulzij z visokimi deležem notranje faze, pričemer bodo monomerji prisotni v obeh fazah emulzije. Pridobljeni poliHIPE ... materiali, hibridni poliHIPE materiali, bodo sestavljeni iz hidrofobnega skeleta (poli stirena zamreženega z DVB oz. diciklopentadien) pri čemer bo celična struktura materiala napolnjena s hidrofilnim polimernim gelom (poli akrilna kislina ali poli NIPAM zamrežena z MBA). Tako pripravljene hibridne poliHIPE materiale z dvofazno morfologijo bomo testirali v pretočnih sistemih kot polimerne ventile. Dvofazno morfologijo hibridnih poliHIPE materialov bomo izkoristili za kontroliranje pretoka raztopine skozi monolitni polimeri. Notranja polimerna domena (t.i. polimerni gel) bo ob spremembi pH ali temperature črpane raztopine nabreknila ali se skrčila in s tem omogočila ali onemogočila pretok skozi material. Za pripravo poliHIPE materialov smo uporabili dve polimerizacijski tehniki, termično inicirano radikalsko polimerizacijo in polimerizacija pri kateri polimeriziramo ciklične monomerje (diciklopentadien ali norbornen) z odpiranjem obroča (ROMP). PoliHIPE materiali polimerizirani s ROMP mehanizmom so se izkazali z izjemnimi mehanskimi lastnostmi, saj so meritve mehanske jakosti pokazale sto krat višje vrednosti v primerjavi s poliHIPE materiali polimeriziranimi z navadno radikalsko polimerizacijo.

Type of material - dissertation ; adult, serious

Publication and manufacture - [Maribor : S. Kovačič], 2011

Language - english

COBISS.SI-ID - 14931734

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Digital Library of the University of Maribor – DLUM
Digitalna knjižnica Slovenije - dLib.si

Dostop z namenskih računalnikov v prostorih NUK

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Krajnc, Peter, 1970- | Slugovc, Christian

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Library	Call number – location, accession no. ...	Copy status
National and University Library, Ljubljana	GS II 711136 glavno skladišče	available - reading room

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Year	Impact factor		Edition		Category		Classification
Year	JCR	SNIP	JCR	SNIP	JCR	SNIP	JCR	SNIP

Links to authors' personal bibliographies	Links to information on researchers in the SICRIS system
Kovačič, Sebastijan	28412
Krajnc, Peter, 1970-	15501
Slugovc, Christian

Source: Personal bibliographies and: SICRIS

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