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Olatunde, Abiola O; Bond, Christopher J; Dorazio, Sarina J; Cox, Jordan M; Benedict, Jason B; Daddario, Michael D; Spernyak, Joseph A; Morrow, Janet R
Chemistry : a European journal, 2015-Dec-07, 20151207, Volume: 21, Issue: 50Journal Article
Fe(II) , Co(II) and Ni(II) complexes of two tetraazamacrocycles (1,4,8,11-tetrakis(carbamoylmethyl)-1,4,8,11-tetraazacyclotetradecane (L1) and 1,4,7,10-tetrakis(carbamoylmethyl)-1,4,7,10-tetraazacyclododecane (L2) show promise as paraCEST agents for registration of temperature (paraCEST=paramagnetic chemical exchange saturation transfer). The Fe(II) , Co(II) and Ni(II) complexes of L1 show up to four CEST peaks shifted ≤112 ppm, whereas analogous complexes of L2 show only a single CEST peak at ≤69 ppm. Comparison of the temperature coefficients (CT ) of the CEST peaks of Co(L2)(2+) , Fe(L2)(2+) , Ni(L1)(2+) and Co(L1)(2+) showed that a CEST peak of Co(L1)(2+) gave the largest CT (-0.66 ppm (o) C(-1) at 4.7 T). NMR spectral and CEST properties of these complexes correspond to coordination complex symmetry as shown by structural data. The Ni(L1)(2+) and Co(L1)(2+) complexes have a six-coordinate metal ion bound to the 1-, 4-amide oxygen atoms and four nitrogen atoms of the tetraazamacrocycle. The Fe(L2)(2+) complex has an unusual eight-coordinate Fe(II) bound to four amide oxygen atoms and four macrocyclic nitrogen atoms. For Co(L2)(2+) , one structure has seven-coordinate Co(II) with three bound amide pendents and a second structure has a six-coordinate Co(II) with two bound amide pendents.
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