E-resources
Peer reviewed
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Chi, Yang; Jiang, Teng-Fei; Xue, Huai-Guo; Guo, Sheng-Ping
Inorganic chemistry, 03/2019, Volume: 58, Issue: 6Journal Article
Novel Eu8In17.33S34 (1) is obtained by a solid state reaction and its structure features three parallel slabs of In9.33S18∞, Eu8∞, and In8S16∞, together with defects in specific lattice sites. It is the first monoclinic ternary M 8‑m In18‑n Q 34 (M = Pb, Sn, Eu; Q = S, Se) phase member, and the modulation from the ultralong In–S bond and lattice site with strong antibonding effect results in the unique structure feature. Its single crystals show anisotropic conductivity and photoconductivity.
