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Peng, Huabei; Wen, Yuhua; Du, Yangyang; Yu, Qinxu; Yang, Qin
Metallurgical and materials transactions. B, Process metallurgy and materials processing science, 10/2013, Volume: 44, Issue: 5Journal Article
We investigated microstructures and solidification modes of cast Fe-(13-27)Mn-5.5Si-8.5Cr-5Ni shape memory alloys to clarify whether Mn was an austenite former during solidification. Furthermore, we examined whether the Cr eq /Ni eq equations (Delong, Hull, Hammer and WRC-1992 equations) and Thermo-Calc software ® together with database TCFE6 were valid to predict the solidification modes of cast Fe-(13-27)Mn-5.5Si-8.5Cr-5Ni shape memory alloys. The results have shown that the solidification modes of Fe-(13-27)Mn-5.5Si-8.5Cr-5Ni alloys changed from the F mode to the FA mode with increasing the Mn concentration. Mn is an austenite former during the solidification for the cast Fe-Mn-Si-Cr-Ni shape memory alloys. The Delong, Hull, Hammer, and WRC-1992 equations as well as Thermo-Calc software ® together with database TCFE6 are invalid to predict the solidification modes of cast Fe-(13-27)Mn-5.5Si-8.5Cr-5Ni SMAs. To predict the solidification modes of cast Fe-Mn-Si-Cr-Ni alloys, a new Cr eq /Ni eq equation should be developed or the thermodynamic database of Thermo-Calc software ® should be corrected.
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