In Situ Observation of Gas Adsorption onto ZIF‑8 Using Terahertz Waves

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In Situ Observation of Gas Adsorption onto ZIF‑8 Using Terahertz Waves

Tanno, Takenori; Watanabe, Yutaro; Umeno, Kyoko; Matsuoka, Atsushi; Matsumura, Hirotoshi; Odaka, Masafumi; Ogawa, Nobuaki

Journal of physical chemistry. C, 08/2017, Volume: 121, Issue: 33

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The adsorption behavior of energy-related gases onto ZIF-8 was investigated using terahertz waves. Comparison of the terahertz transmission spectra of ZIF-8 before and after exposure to the gases revealed that the 2 THz vibrational mode was involved in the gate-opening motion of organic linker molecules. The adsorption properties of each gas were detailed by monitoring the intensities of the 2 THz absorption peak.

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