E-resources
Peer reviewed
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Tran, Hai Nguyen; Chao, Huan-Ping
Environmental science and pollution research international, 05/2018, Volume: 25, Issue: 13Journal Article
Six lignocellulosic waste-derived biosorbents cantaloupe peel (CAN), pine cone (PC), litchi fruit peel (LP), annona squamosal (AS), bamboo shoot (BS), and sugarcane bagasse (SB) were selected as low-cost and renewable materials to prepare chemically modified biosorbent. The modified biosorbent was prepared through a newer carboxyl groups-grafting process onto the biosorbent’s surface using acrylic acid. The results showed that the cation exchange capacity (CEC) of biosorbents increased by approximately 66.3–104% after modified. The modified biosorbent exhibited significantly higher adsorption capacity of Pb 2+ , Cu 2+ , and Cd 2+ ions than the pristine biosorbent. The maximum Langmuir adsorption capacity ( Q o max ) of both pristine and modified biosorbents toward three metal ions (Pb 2+ , Cu 2+ , and Cd 2+ ) followed the decreasing order: CAN > PC > LP > AS > BS > SB. The preference ranking of three metal ions on the pristine and modified biosorbents (mmol/kg) was generally in the order: Pb 2+ > Cu 2+ > Cd 2+ . Among these biosorbents, cantaloupe peel exhibited an excellent adsorption affinity to metal cations compared to the five others. The Q o max values of modified and pristine cantaloupe peels were ordered as follows: 143.2 and 81.1 mg/g for Pb 2+ adsorption, > 45.4 and 30.4 mg/g for Cd 2+ adsorption, > 33.1 and 23.5 mg/g for Cu 2+ adsorption. After five adsorption–desorption cycles, the removal efficiency of Pb 2+ by modified CAN was maintained at around 70%. The ion exchange played a determining role in adsorption mechanism. It can be concluded that modified cantaloupe peel can serve as a newer and promising biosorbent with a high adsorption capacity to various potentially toxic metals.
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