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Zheng, Huidong; Huang, Yangjie; Weng, Zhiqiang
Tetrahedron letters, 03/2016, Volume: 57, Issue: 13Journal Article
Display omitted •Recent advances in nucleophilic trifluoromethylthiolation are discussed.•These include transition-metal-mediated trifluoromethylthiolation reaction.•Some novel nucleophilic trifluoromethylthiolating reagents are highlighted. With regard to the high lipophilicity of the trifluoromethylthio group (CF3S–), there is a growing interest in the development of efficient methods for the incorporation of CF3S moiety onto organic molecules. In this review, recent advances in trifluoromethylthiolation using nucleophilic trifluoromethylthiolating reagents are discussed, highlighting some of the most intriguing examples of the synthesis of trifluoromethylthio-containing compounds using novel reagents.
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