Alkaline-Earth Metal Catalyzed Dehydrative Allylic Alkylation

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Alkaline-Earth Metal Catalyzed Dehydrative Allylic Alkylation

Xie, Peizhong; Li, Shuangshuang; Liu, Yanan; Cai, Xinying; Wang, Jinyu; Yang, Xiaobo; Loh, Teck-Peng

Organic letters, 01/2020, Volume: 22, Issue: 1

Journal Article

An alkaline-earth metal catalytic system for environmentally benign allylic alkylation was developed. Allylic alcohols can be utilized directly at room temperature in this transition-metal-free process, producing water as the only byproduct. A variety of allylic compounds, including the ones containing all-carbonyl quaternary centers, can be obtained with high yields.

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