Temperature measurement in welding constitutes relevant information for process understanding and simulation, as it can be used to validate and predict microstructure. Monitoring can be performed at specific points through transducers. The typical one is the thermocouple. In laser welding processes, due to the high energy concentration of the beam, the acquisition with thermocouples should be performed closer to the bead when compared to electric arc welding processes. This measurement is critical because of overheating by spatters, which can result in damage. The present work covers developing a Capacitive Discharge Welding device for thermocouple fixing and assessing possible temperature acquisition positions in keyhole laser welding. The study performed all tests with a fiber laser of 9 kW power and 3 m/min scanning speed. When placed at 2 mm from the weld centerline, the results showed a high probability of spattering due to the 71° range of incidence angle. Therefore, the thermocouple should be placed far from the weld centerline to minimize the spattering. However, it must be close enough to acquire temperatures above 727 °C. This temperature corresponds to the envisaged austenitization microstructure correlation. The study found the maximum distance at 3.5 mm based on an interpolation map, where the incidence spatters angle reduced to 59°. At a 2 mm distance from the weld centerline, the weld cross section temperatures reached more than 727 °C. However, the microstructural changes did not occur due to insufficient austenitization time. The Heat Affected Zone boundary was at 1.64 mm from the weld centerline. Therefore, to correlate microstructure with thermal cycles, it is necessary to place thermocouples at a distance below this value. However, spatter can be a problem since the range of incidence angle is about 75°. Therefore, this work recommends using more than one thermocouple for each position (redundancy) to increase valuable data. Graphic abstract