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Yadav, Nisha; Saquib, Mohammad; Arya, Krishan Kumar; Hussain, Mohd Kamil
Polycyclic aromatic compounds, 07/2023, Volume: 43, Issue: 6Journal Article
The development of versatile new routes to bridgehead nitrogen-bearing polycyclic aromatic systems having privileged scaffolds is a synthetic challenge for organic chemists. An efficient synthesis of benzo4,5imidazo1,2-aquinazoline derivatives bearing bridgehead nitrogen by the reaction of benzodimidazol-2-amines, aldehydes, and ortho-silyl aryltriflate via 1,4-dipolar cycloaddition is reported under the optimized reaction conditions. The methodology provides easy access to fused benzimidazolo-quinazolines by sequential C-N and C-C bond formation through a one-pot reaction.
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