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  • Visualizing screening in no...
    Sinha-Roy, Rajarshi; García-González, Pablo; López-Lozano, Xóchitl; Weissker, Hans-Christian

    Physical chemistry chemical physics : PCCP, 01/2023, Volume: 25, Issue: 3
    Journal Article

    The localized surface-plasmon resonance of metal nanoparticles and clusters corresponds to a collective charge oscillation of the quasi-free metal electrons. The polarization of the more localized d electrons opposes the overall polarization of the electron cloud and thus screens the surface plasmon. By contrast, a static electric external field is well screened, as even very small noble-metal clusters are highly metallic: the field inside is practically zero except for the effect of the Friedel-oscillation-like modulations which lead to small values of the polarization of the d electrons. In the present article, we present and compare representations of the induced densities (i) connected to the surface-plasmon resonance and (ii) resulting from an external static electric field. The two cases allow for an intuitive understanding of the differences between the dynamic and the static screening.