E-resources
Peer reviewed
-
Shahid, Omair; Yadav, Sweta; Manna, Kaustuv; Thakur, Gohil S; Prakash, Jai
Dalton transactions : an international journal of inorganic chemistry, 2024-Apr-02, 2024-04-02, Volume: 53, Issue: 14Journal Article
The design of new complex mixed metal tellurides (containing low toxicity cations) with intrinsic ultralow thermal conductivity is of paramount importance in the field of thermoelectrics. Herein, we report the synthesis and characterization of polycrystalline and single crystals of a new mixed-metal quaternary telluride Mn In Si Te . The structural aspects and chemical formula of this phase at room temperature have been established using single crystal X-ray diffraction and EDX studies. The trigonal centrosymmetric (space group: 3̄1 ) structure of the title phase has cell constants of = = 7.0483(7) Å and = 7.1277(8) Å. The structure has three independent cationic sites, one mixed (In1/Mn1), one partially filled Mn2, and one Si1, which are bonded with Te1 atoms. Each metal atom (In and Mn) in the structure is octahedrally coordinated with six neighboring Te1 atoms. The structure also features dimers of Si atoms, and each Si atom is bonded to three Te1 atoms to form ethane-like Si Te units. The optical absorption study of a polycrystalline Mn In Si Te sample shows a narrow optical bandgap of 0.6(2) eV. Temperature-dependent resistivity and Seebeck coefficient studies confirmed the -type semiconducting nature of the sample with high values of (301 μV K to 444 μV K ). The total thermal conductivity ( ) study of the polycrystalline sample shows a decreasing trend on heating with an extremely low value of 0.28 W m K at 773 K. Magnetic measurements indicate a glassy magnetic behavior for the sample below 8 K.
![loading ... loading ...](themes/default/img/ajax-loading.gif)
Shelf entry
Permalink
- URL:
Impact factor
Access to the JCR database is permitted only to users from Slovenia. Your current IP address is not on the list of IP addresses with access permission, and authentication with the relevant AAI accout is required.
Year | Impact factor | Edition | Category | Classification | ||||
---|---|---|---|---|---|---|---|---|
JCR | SNIP | JCR | SNIP | JCR | SNIP | JCR | SNIP |
Select the library membership card:
If the library membership card is not in the list,
add a new one.
DRS, in which the journal is indexed
Database name | Field | Year |
---|
Links to authors' personal bibliographies | Links to information on researchers in the SICRIS system |
---|
Source: Personal bibliographies
and: SICRIS
The material is available in full text. If you wish to order the material anyway, click the Continue button.